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公开(公告)号:US5106803A
公开(公告)日:1992-04-21
申请号:US352399
申请日:1989-05-15
IPC分类号: B01J29/62 , B01J29/72 , C10G35/095
CPC分类号: C10G35/095 , B01J29/62 , B01J2229/26 , B01J2229/42
摘要: Reforming to produce aromatics from aliphatics, using a bond zeolite catalyst containing a Group VIII metal such as platinum, has been found to be extremely sensitive to water, even at water concentrations as low as 3 ppm in the feed, unless certain catalysts having a low water sensitivity index are used. The water sensitivity index (WSI) is described and methods for making catalysts with a low WSI are described. The sulfur content of the feed to the reforming/aromatics production process is preferably below 50 parts per billion. The catalysts used in the reforming process is preferably a high crush strength catalyst and is preferably prepared by steps including treating L zeolite with a binding enhancement agent prior to binding with a binder such as silica, silica/alumina or alumina.
摘要翻译: 已经发现使用含有VIII族金属如铂的键沸石催化剂从脂肪族产生芳族化合物,甚至在进料中的低至3ppm的水浓度下,对水是非常敏感的,除非某些催化剂具有低 使用水敏感指数。 描述了水敏感指数(WSI),并描述了制备低WSI催化剂的方法。 重整/芳烃生产过程的进料的硫含量优选低于50ppm。 在重整过程中使用的催化剂优选是高抗压强度催化剂,并且优选通过以下步骤制备,包括在与粘合剂例如二氧化硅,二氧化硅/氧化铝或氧化铝结合之前用结合增强剂处理L沸石。
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公开(公告)号:US4830732A
公开(公告)日:1989-05-16
申请号:US141657
申请日:1988-01-07
IPC分类号: B01J29/60 , B01J29/50 , B01J29/62 , C10G35/06 , C10G35/085 , C10G35/095
CPC分类号: C10G35/095 , B01J29/62 , B01J2229/26 , B01J2229/42
摘要: Reforming to produce aromatics from aliphatics, using a bound zeolite catalyst containing a Group VIII metal such as platinum, has been found to be extremely sensitive to water, even at water concentrations as low as 3 ppm in the feed, unless certain catalysts having a low water sensitivity index are used. The water sensitivity index (WSI) is described and methods for making catalysts with a low WSI are described. The sulfur content of the feed to the reforming/aromatics production process is preferably below 50 parts per billion. The catalyst used in the reforming process is preferably a high crush strength catalyst and is preferably prepared by steps including treating L zeolite with a binding enhancement agent prior to binding with a binder such as silica, silica/alumina or alumina.
摘要翻译: 已经发现使用含有VIII族金属如铂的结合的沸石催化剂从脂肪族产生芳族化合物,即使在进料中的低至3ppm的水浓度下,对水也非常敏感,除非某些催化剂具有低的 使用水敏感指数。 描述了水敏感指数(WSI),并描述了制备低WSI催化剂的方法。 重整/芳烃生产过程的进料的硫含量优选低于50ppm。 在重整过程中使用的催化剂优选是高抗压强度催化剂,并且优选通过以下步骤制备,所述步骤包括在与粘合剂如二氧化硅,二氧化硅/氧化铝或氧化铝结合之前用结合增强剂处理L沸石。
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公开(公告)号:US4853355A
公开(公告)日:1989-08-01
申请号:US141712
申请日:1988-01-07
CPC分类号: B01J29/06 , B01J20/186
摘要: A method for enhancing the binding of certain negatively surface charged molecular sieves to a silica binder is disclosed. As modified, molecular sieves having enhanced binding characteristics are also taught.
摘要翻译: 公开了一种用于增强某些负表面带电分子筛与二氧化硅粘合剂的结合的方法。 通过改进,还教导了具有增强的结合特性的分子筛。
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公开(公告)号:US5925284A
公开(公告)日:1999-07-20
申请号:US806006
申请日:1997-02-24
CPC分类号: B01J20/10 , B01J20/02 , B01J20/06 , B01J20/12 , B01J20/3007 , B01J20/3078 , B01J39/085
摘要: Applicants have developed a unique process for preparing a shaped article comprising an ion exchange composition and a hydroxy oxide binder. The ion exchange compositions include metallotitanates, metallogermanates, pillared clays and metal phosphonates. The process involves combining the ion exchange composition with a binder precursor and water, forming the mixture into a shaped article and heating the article at a temperature of about 85.degree. C. to about 120.degree. C. These shaped articles are useful for removing metal ions such as cesium from feed streams.
摘要翻译: 申请人已经开发了用于制备包含离子交换组合物和羟基氧化物粘合剂的成形制品的独特方法。 离子交换组合物包括金属钛酸盐,金属矿物,柱状粘土和金属膦酸盐。 该方法包括将离子交换组合物与粘合剂前体和水混合,将混合物形成成型制品并在约85℃至约120℃的温度下加热制品。这些成型制品可用于除去金属离子 例如来自进料流的铯。
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公开(公告)号:US5260243A
公开(公告)日:1993-11-09
申请号:US895975
申请日:1992-06-09
申请人: Stephen R. Dunne , Albert S. Behan
发明人: Stephen R. Dunne , Albert S. Behan
CPC分类号: B01J20/3204 , B01J20/08 , B01J20/183 , B01J20/3042 , B01J20/3223 , B01J20/3236 , B01J20/3238 , B01J20/3291
摘要: Layered adsorbent-substrate tubes are prepared by a method comprising heating the surface of an aluminum substrate, contacting the surface of the substrate with a slurry containing the adsorbent and a binder, and heating the coatings to form hardened surfaces which can have excellent adsorption and mechanical properties in devices for cooling or heating by adsorption of refrigerating fluid on a solid adsorbent.
摘要翻译: 通过包括加热铝基材的表面,使基材表面与含有吸附剂和粘合剂的浆料接触并且加热涂层以形成硬化表面的方法来制备分层的吸附剂 - 基材管,该表面可以具有优异的吸附和机械 通过在固体吸附剂上吸附冷冻液来冷却或加热的装置中的性质。
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公开(公告)号:US5518977A
公开(公告)日:1996-05-21
申请号:US462394
申请日:1995-06-05
申请人: Stephen R. Dunne , Albert S. Behan
发明人: Stephen R. Dunne , Albert S. Behan
CPC分类号: B01J20/3238 , B01J20/08 , B01J20/183 , B01J20/3042 , B01J20/3204 , B01J20/3223 , B01J20/3291 , F24F3/1423 , F24F2203/1036 , F24F2203/1056 , F24F2203/1068 , F24F2203/1076 , F24F2203/1084
摘要: A desiccant cooling apparatus and process using a solid adsorbent and refrigerant wherein the solid adsorbent is selected from the group consisting of zeolite Y-85, a low cerium rare earth exchanged Y-84 and a rare earth exchanged LZ-210, and the adsorbent is bonded directly to the heat exchange tubes within the device by a novel slip coating process resulted in significant improvements in thermal efficiency and overall performance.
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公开(公告)号:US5477014A
公开(公告)日:1995-12-19
申请号:US79575
申请日:1993-06-22
CPC分类号: B01J20/183 , B01J20/0248 , B01J20/2803 , B01J20/3042 , B01J20/3078 , B01J20/3204 , B01J20/3238 , B01J20/3297 , B01J2220/42 , B01J2220/64
摘要: Layered adsorbent-substrate composites are prepared by methods comprising heating the surface of an aluminum substrate, contacting the surface of the substrate with a slurry containing the adsorbent and a binder, and heating the coatings to form hardened surfaces which can have excellent adsorption and mechanical properties and have a variety of uses such as adsorbents in automobile mufflers.
摘要翻译: 通过以下方法制备分层的吸附剂 - 基材复合材料,方法包括加热铝基材的表面,使基材的表面与含有吸附剂和粘合剂的浆料接触,并加热涂层以形成硬化表面,其具有优异的吸附和机械性能 并具有各种用途,例如汽车消音器中的吸附剂。
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公开(公告)号:US5120694A
公开(公告)日:1992-06-09
申请号:US386319
申请日:1989-07-28
CPC分类号: B01J20/183 , B01J20/0248 , B01J20/28004 , B01J20/2803 , B01J20/3042 , B01J20/3078 , B01J20/3204 , B01J20/3238 , B01J20/3297 , B01J2220/42 , B01J2220/64
摘要: Layered adsorbent-substrate composites are prepared by methods comprising heating the surface of an aluminum substrate, contacting the surface of the substrate with a slurry containing the adsorbent and a binder, and heating the coatings to form hardened surfaces which can have excellent adsorption and mechanical properties and have a variety of uses such as adsorbents in automobile mufflers and as desiccants in multiple pane windows.
摘要翻译: 通过以下方法制备分层的吸附剂 - 基材复合材料,方法包括加热铝基材的表面,使基材的表面与含有吸附剂和粘合剂的浆料接触,并加热涂层以形成硬化表面,其具有优异的吸附和机械性能 并具有各种用途,例如汽车消声器中的吸附剂和多个窗格窗中的干燥剂。
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公开(公告)号:US5325916A
公开(公告)日:1994-07-05
申请号:US124830
申请日:1993-09-21
申请人: Stephen R. Dunne , Albert S. Behan
发明人: Stephen R. Dunne , Albert S. Behan
CPC分类号: B01J20/183 , B01J20/0248 , B01J20/2803 , B01J20/3042 , B01J20/3078 , B01J20/3204 , B01J20/3238 , F28F13/18 , B01J2220/64
摘要: Layered adsorbent-substrate tubes are prepared by a method comprising heating the surface of an aluminum substrate, contacting the surface of the substrate with a slurry containing the adsorbent and a binder, and heating the coatings to form hardened surfaces which can have excellent adsorption and mechanical properties in devices for cooling or heating by adsorption of refrigerating fluid on a solid adsorbent.
摘要翻译: 通过包括加热铝基材的表面,使基材表面与含有吸附剂和粘合剂的浆料接触并且加热涂层以形成硬化表面的方法来制备分层的吸附剂 - 基材管,该表面可以具有优异的吸附和机械 通过在固体吸附剂上吸附冷冻液来冷却或加热的装置中的性质。
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10.
公开(公告)号:US5456093A
公开(公告)日:1995-10-10
申请号:US124740
申请日:1993-09-21
申请人: Stephen R. Dunne , Albert S. Behan
发明人: Stephen R. Dunne , Albert S. Behan
CPC分类号: B01J20/3238 , B01J20/08 , B01J20/183 , B01J20/3042 , B01J20/3204 , B01J20/3223 , B01J20/3291 , F24F3/1423 , F24F2203/1036 , F24F2203/1056 , F24F2203/1068 , F24F2203/1076 , F24F2203/1084
摘要: A desiccant cooling apparatus and process using a solid adsorbent and refrigerant wherein the solid adsorbent is selected from the group consisting of zeolite Y-85, a low cerium rare earth exchanged Y-84 and a rare earth exchanged LZ-210, and the adsorbent is bonded directly to the heat exchange tubes within the device by a novel slip coating process resulted in significant improvements in thermal efficiency and overall performance.
摘要翻译: 一种使用固体吸附剂和制冷剂的干燥剂冷却装置和方法,其中固体吸附剂选自沸石Y-85,低铈稀土交换的Y-84和稀土交换的LZ-210,吸附剂为 通过新颖的滑移涂覆工艺直接粘合到装置内的热交换管,导致热效率和总体性能的显着改善。
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