Coated enzyme-containing granule
    1.
    发明授权
    Coated enzyme-containing granule 失效
    包被的含酶颗粒

    公开(公告)号:US5879920A

    公开(公告)日:1999-03-09

    申请号:US577894

    申请日:1995-12-22

    摘要: A granular enzyme composition is produced having reduced tendency to form dust and leave a residue, and improved stability and delayed release characteristics. The composition has a core, optionally coated with a vinyl polymer, a layer containing an enzyme and a vinyl polymer and optionally a plasticizer or anti-agglomeration agent, and an outer coating containing a polymer and optionally a low residue pigment and/or lubricant. Preferably, the core is a salt or sugar nonpareil, the vinyl polymer coating the core is polyvinyl alcohol and most preferably partially hydrolyzed polyvinyl alcohol, the vinyl polymer in the enzyme layer is polyvinyl pyrrolidone, and the polymer of the outer coating is polyvinyl pyrrolidone, polyvinyl alcohol which may be partially hydrolyzed, polyethylene glycol or mixtures thereof such as a mixture of polyvinyl pyrrolidone and polyvinyl alcohol or a mixture of polyvinyl pyrrolidone and polyethylene glycol. Preferably, the pigment is titanium dioxide and the lubricant is a nonionic or anionic surfactant such as a linear primary alcohol of a 9-15 carbon atom chain length alkane or alkene or an ethoxylate or ethoxysulfate derivative thereof. The enzyme can be a protease, amylase, lipase, cellulase, xylanase, oxidase, peroxidase or mixtures thereof. The composition may be produced by spray coating in a fluidized bed a solution of the enzyme and vinyl polymer onto the core to form the enzyme layer, and then spray coating in a fluidized bed a solution of polymer on the enzyme layer to form the outer coating.

    摘要翻译: 产生颗粒状酶组合物,其具有降低形成粉尘并留下残留物的倾向,以及改进的稳定性和延迟释放特性。 该组合物具有核心,任选地涂覆有乙烯基聚合物,含有酶和乙烯基聚合物的层以及任选的增塑剂或抗附聚剂,以及含有聚合物和任选的低残留颜料和/或润滑剂的外涂层。 优选地,核心是盐或糖不分散体,涂覆核心的乙烯基聚合物是聚乙烯醇,最优选部分水解的聚乙烯醇,酶层中的乙烯基聚合物是聚乙烯吡咯烷酮,外涂层的聚合物是聚乙烯吡咯烷酮, 可以部分水解的聚乙烯醇,聚乙二醇或其混合物,例如聚乙烯吡咯烷酮和聚乙烯醇的混合物,或聚乙烯吡咯烷酮和聚乙二醇的混合物。 优选地,颜料是二氧化钛,润滑剂是非离子或阴离子表面活性剂,例如9-15碳原子的链烷烃或链烯烃的直链伯醇或其乙氧基化物或乙氧基硫酸盐衍生物。 酶可以是蛋白酶,淀粉酶,脂肪酶,纤维素酶,木聚糖酶,氧化酶,过氧化物酶或其混合物。 组合物可以通过在流化床中将酶和乙烯基聚合物的溶液喷雾到芯上以形成酶层,然后在流化床中将聚合物溶液在酶层上喷涂以形成外涂层 。

    Fluidized bed low density granule
    7.
    发明授权
    Fluidized bed low density granule 有权
    流化床低密度颗粒

    公开(公告)号:US06635611B2

    公开(公告)日:2003-10-21

    申请号:US09866210

    申请日:2001-05-25

    申请人: Douglas A. Dale

    发明人: Douglas A. Dale

    IPC分类号: C11D3386

    摘要: Low-density enzyme-carrying granules are low dusting and/or storage-stable, and especially suitable for use in liquid detergents and cleaners, such as non-aqueous liquid laundry detergents. Preferred granules of the invention include a relatively high content of one or more low-density fillers, such as perlite or starch, to provide a desired product density. In one embodiment, the granules have a true density within a range of from about 1 to about 1.4 g/cm3. The granules can be economically produced in commercial quantities using fluidized bed technology.

    摘要翻译: 低密度酶载体颗粒具有低的粉尘和/或储存稳定性,并且特别适用于液体洗涤剂和清洁剂,例如非水性液体衣物洗涤剂。 本发明优选的颗粒包括相对高含量的一种或多种低密度填料,例如珍珠岩或淀粉,以提供所需的产品密度。 在一个实施方案中,颗粒的真密度在约1至约1.4g / cm 3的范围内。 颗粒可以使用流化床技术以商业量经济地生产。

    Fluidized bed low density granule
    9.
    发明授权
    Fluidized bed low density granule 有权
    流化床低密度颗粒

    公开(公告)号:US06310027B1

    公开(公告)日:2001-10-30

    申请号:US09462431

    申请日:2000-01-07

    申请人: Douglas A. Dale

    发明人: Douglas A. Dale

    IPC分类号: C11D3386

    摘要: A multi-layer enzyme granule for use in liquid detergents and cleaners is produced, comprising a seed or carrier particle; an outer coating; and, between the particle and the coating layer, a low-density filler and an enzyme, wherein the granule has a density of less than 1.4 g/cm3. Also disclosed are methods for making such enzyme-containing granules including using fluidized bed technology.

    摘要翻译: 制备用于液体洗涤剂和清洁剂的多层酶颗粒,其包含种子或载体颗粒; 外涂层; 并且在颗粒和涂层之间,是低密度填料和酶,其中颗粒的密度小于1.4g / cm 3。 还公开了制备这种含酶颗粒的方法,包括使用流化床技术。