公开(公告)号：US06803426B2

公开(公告)日：2004-10-12

申请号：US10357580

申请日：2003-02-04

申请人： Edward R. Coleridge ,  Edward R. Millero, Jr. ,  Robert T. Pogue ,  Truman F. Wilt ,  Carole A. Conley ,  Shawn A. DeSaw ,  Robert A. Montague

发明人： Edward R. Coleridge ,  Edward R. Millero, Jr. ,  Robert T. Pogue ,  Truman F. Wilt ,  Carole A. Conley ,  Shawn A. DeSaw ,  Robert A. Montague

IPC分类号： C08F830

CPC分类号： B05D7/57 ,  B05D1/007 ,  B05D3/0209 ,  B05D3/067 ,  B05D7/53 ,  C08F8/00 ,  C08F210/10 ,  C08F220/10 ,  C08F290/046 ,  C08G18/6229 ,  C08G18/792 ,  C08G18/798 ,  C08G18/8025 ,  C08G18/807 ,  C08G18/8074 ,  C08G2150/20 ,  C08L33/068 ,  C09D123/22 ,  C09D133/062 ,  C09D133/08 ,  Y10T428/31504 ,  Y10T428/31511 ,  C08F220/00 ,  C08F220/12 ,  C08F210/00 ,  C08L2666/28 ,  C08L2666/02 ,  C08F214/18 ,  C08F2500/03 ,  C08F2500/02 ,  C08F212/00 ,  C08F222/00 ,  C08F2500/26 ,  C08L2666/04

摘要： A composition that includes a fluorine-containing copolymer containing at least 30 mol % of residues having the following alternating structural unit: —[DM—AM]— where DM represents a residue from a donor monomer having the following structure (I): where R1 is linear or branched C1 to C4 alkyl; R2 is selected from methyl, linear, cyclic or branched C1 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl; and AM represents an acceptor monomer. The copolymer contains at least 5 wt. % fluorine. The composition may include co-reactive functional groups and may be a thermosetting composition, which can be used to coat a substrate. The thermosetting composition may be part of a multi-component composite coating composition that includes a base coat deposited from a pigmented film-forming composition and a substantially pigment free top coat applied over at least a portion of the base coat.

摘要翻译： 包含含有至少30mol％具有以下交替结构单元的残基的含氟共聚物的组合物：其中DM表示具有以下结构（I）的供体单体的残基：其中R 1是直链或支链 C1至C4烷基; R 2选自甲基，直链，环状或支链C 1至C 20烷基，烯基，芳基，烷芳基和芳烷基; AM表示受体单体。 共聚物含有至少5wt。 ％氟。 组合物可以包括共反应性官能团，并且可以是热固性组合物，其可以用于涂覆底物。 热固性组合物可以是多组分复合涂料组合物的一部分，其包括由着色成膜组合物沉积的底涂层和施加在底涂层的至少一部分上的基本上无颜料的顶涂层。

公开(公告)号：US06387519B1

公开(公告)日：2002-05-14

申请号：US09629423

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Anthony M. Chasser ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Robert A. Montague ,  Masayuki Nakajima ,  Kurt G. Olson ,  Jamel S. Richardson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Anthony M. Chasser ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Robert A. Montague ,  Masayuki Nakajima ,  Kurt G. Olson ,  Jamel S. Richardson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： B32B516

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/62 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/31 ,  Y10T428/31551 ,  Y10T428/31663 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Cured coatings having particles at a surface region of the cured coating are provided. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了在固化涂层的表面区域具有颗粒的固化涂层。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供了耐刮擦后能够保持耐划伤性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06657001B1

公开(公告)日：2003-12-02

申请号：US09629444

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04

摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种固化剂，其包含与聚硅氧烷（a）的任何反应性官能团反应的至少一个官能团。 另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。 还提供了制备涂料组合物的方法。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US07053149B2

公开(公告)日：2006-05-30

申请号：US10795216

申请日：2004-03-09

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04

摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种包含至少一种与聚硅氧烷（a）的任何反应性官能团反应的官能团的固化剂。 另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。 还提供了制备涂料组合物的方法。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06794055B2

公开(公告)日：2004-09-21

申请号：US10357091

申请日：2003-02-03

申请人： Roy E. Dean ,  Truman F. Wilt ,  Shawn A. DeSaw ,  M. Lisa Perrine ,  Michael J. Ziegler

发明人： Roy E. Dean ,  Truman F. Wilt ,  Shawn A. DeSaw ,  M. Lisa Perrine ,  Michael J. Ziegler

IPC分类号： B32B2104

CPC分类号： C09D15/00 ,  C08K3/013 ,  C08K5/0041 ,  C09D167/08 ,  Y10T428/3188 ,  Y10T428/31935 ,  Y10T428/31946 ,  Y10T428/31989

摘要： Stains comprising a polymer, an initiator, a colorant and a solvent are disclosed. The polymer comprises an alkyd portion and a free radical curable portion that is pendant from the alkyd portion; the alkyd portion includes one or more fatty acid moieties that can be derived from one or more drying, semi-drying or nondrying oils. When drying or semi-drying oils are used, the molecules of the present invention exhibit a dual cure, both oxidative and free radical. The compositions are particularly suitable for staining substrates comprising wood. Methods for using the present compositions are also disclosed.

摘要翻译： 公开了包含聚合物，引发剂，着色剂和溶剂的污渍。 聚合物包含醇酸部分和从醇酸部分悬挂的自由基可固化部分; 醇酸部分包括可以衍生自一种或多种干燥，半干燥或不干燥的油的一种或多种脂肪酸部分。 当使用干燥或半干性油时，本发明的分子表现出双重固化，包括氧化和自由基。 该组合物特别适用于染色包含木材的底物。 还公开了使用本发明组合物的方法。

公开(公告)号：US06803408B2

公开(公告)日：2004-10-12

申请号：US10456854

申请日：2003-06-09

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04

摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种固化剂，其包含与聚硅氧烷（a）的任何反应性官能团反应的至少一个官能团。 另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。 还提供了制备涂料组合物的方法。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06759478B2

公开(公告)日：2004-07-06

申请号：US10456552

申请日：2003-06-09

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06593417B1

公开(公告)日：2003-07-15

申请号：US09629443

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US07005472B2

公开(公告)日：2006-02-28

申请号：US10784830

申请日：2004-02-24

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarje L. Koster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarje L. Koster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

公开(公告)号：US08507050B2

公开(公告)日：2013-08-13

申请号：US12269290

申请日：2008-11-12

申请人： Dennis L. Faler ,  Shawn A. DeSaw

发明人： Dennis L. Faler ,  Shawn A. DeSaw

IPC分类号： C08J7/18

CPC分类号： C03C17/007 ,  B82Y30/00 ,  C03C2217/445 ,  C03C2217/485 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/348 ,  C08G18/4238 ,  C08G18/6659 ,  C08G18/672 ,  C08G18/755 ,  C08K5/0025 ,  C08K5/0041 ,  C09D175/16 ,  C08G18/3228 ,  C08G18/2875

摘要： Disclosed are methods for depositing an ultra thin coating that exhibits both low haze (high transparency) and strong color (high optical density at a given film thickness). Also disclosed are methods for making radiation curable coating compositions comprising polymer-enclosed particles that are suitable for producing ultra thin coatings.

摘要翻译： 公开了沉积低雾度（高透明度）和强色（在给定膜厚度下的高光密度）的超薄涂层的方法。 还公开了制备包含适合于生产超薄涂层的聚合物封闭颗粒的可辐射固化涂料组合物的方法。