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公开(公告)号：US20120277512A1
公开(公告)日：2012-11-01
申请号：US13545539
申请日：2012-07-10
申请人： Edwin P. Boldingh
发明人： Edwin P. Boldingh
IPC分类号： C07C4/12
CPC分类号： C07C6/126 , B01J29/26 , B01J29/48 , B01J29/78 , B01J29/80 , B01J35/1019 , B01J35/1038 , B01J35/108 , B01J37/20 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C07C6/123 , C07C2529/78 , C07C2529/80 , Y02P20/52 , C07C15/04 , C07C15/08
摘要： A process for transalkylating aromatic hydrocarbon compounds, the process comprising introducing an aromatic hydrocarbon feed stream and a sulfur source to a transalkylation zone. The feed stream contacts a catalyst in the transalkylation zone in the presence of sulfur, and produces a reaction product stream comprising benzene and xylene. The invention includes methods to control the transalkylation process.
摘要翻译： 一种芳族烃化合物的烷基转移方法，该方法包括将芳烃进料流和硫源引入烷基转移区。 进料流在硫存在下与烷基转移区中的催化剂接触，并产生包含苯和二甲苯的反应产物流。 本发明包括控制烷基转移过程的方法。
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公开(公告)号：US07605295B1
公开(公告)日：2009-10-20
申请号：US12146865
申请日：2008-06-26
IPC分类号： C07C6/12
CPC分类号： C07C6/126 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/28 , C07C2523/30 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/18 , C07C2529/83 , Y02P20/125 , Y02P20/52 , C07C15/08
摘要： The subject invention comprises an aromatics complex to improve yields from a mixed aromatics feed. Through the use of a novel catalyst having higher activity and stability in a transalkylation unit in the complex, a higher xylene yield is obtained.
摘要翻译： 本发明包括芳族化合物以提高混合芳烃进料的产率。 通过使用在络合物中的烷基转移单元中具有较高活性和稳定性的新型催化剂，可获得更高的二甲苯产率。
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公开(公告)号：US07423190B2
公开(公告)日：2008-09-09
申请号：US11460652
申请日：2006-07-28
IPC分类号： C07C6/12
CPC分类号： C07C6/126 , B01J29/185 , B01J2229/20 , B01J2229/34 , B01J2229/42 , C07C2523/14 , C07C2523/36 , C07C2529/26
摘要： Transalkylation catalysts comprising acidic molecular sieve, rhenium, tin and germanium have good activities and attenuate aromatic ring saturation and lights co-production.
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4.发明授权Shaped catalysts for transalkylation of aromatics for enhanced xylenes production 有权用于芳族化合物烷基转移用于增强二甲苯生产的成型催化剂公开(公告)号：US07393989B2
公开(公告)日：2008-07-01
申请号：US11678857
申请日：2007-02-26
IPC分类号： C07C6/10
CPC分类号： C07C6/126 , B01J29/18 , B01J29/40 , B01J29/80 , B01J35/026 , B01J37/0009 , B01J2229/37 , B01J2229/42 , C07C2521/04 , C07C2521/12 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2529/78 , C07C2529/80 , Y02P20/52 , C07C15/08 , C07C15/067
摘要： A catalyst, a process for using the catalyst whereby the catalyst effectively transalkylates C7, C9, and C10 aromatics to C8 aromatics are disclosed. The catalyst comprises a support such as mordenite plus a metal component. The catalyst provides an enhanced life and activity for carrying out the transalkylation reactions at relatively low temperatures. This is achieved by reducing the maximum particle diameter of cylindrical pellets to 1/32 inch (0.08 cm) or a trilobe to 1/16 inch (0.16 cm).
摘要翻译： 催化剂，使用催化剂的方法，其中催化剂有效地使C 7，C 9和C 10芳烷烃基烷基化至C 1 -C 10烷基， 公开了8种芳族化合物。 催化剂包括支链如丝光沸石加金属组分。 催化剂提供了在较低温度下进行烷基转移反应的寿命和活性。 这是通过将圆柱形丸粒的最大粒径减小到1/32英寸（0.08cm）或三叶至1/16英寸（0.16cm）来实现的。
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5.发明授权Iridium and germanium-containing catalysis and alkylaromatic transalkylation processes using such catalysts 失效使用这种催化剂的铱和含锗催化和烷基芳基烷基转移方法公开(公告)号：US07381674B1
公开(公告)日：2008-06-03
申请号：US11460645
申请日：2006-07-28
IPC分类号： B01J29/06
CPC分类号： B01J29/068 , B01J29/22 , B01J2229/20 , B01J2229/42 , C07C6/126 , C07C2529/18
摘要： Transalkylation catalysts comprising acidic molecular sieve, iridium and germanium have good activities and attenuate aromatic ring saturation and lights co-production where high atomic ratios of germanium to iridium are present.
摘要翻译： 包含酸性分子筛，铱和锗的烷基转移催化剂具有良好的活性并减弱芳族环饱和度，并且存在锗原子与铱的高原子比之间的共同生成。
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公开(公告)号：US07220885B2
公开(公告)日：2007-05-22
申请号：US10855463
申请日：2004-05-27
CPC分类号： B01J37/18 , B01J21/12 , B01J23/36 , B01J29/061 , B01J29/076 , B01J29/26 , B01J29/48 , B01J29/7815 , B01J37/0009 , B01J37/0201 , B01J37/12 , B01J37/20 , B01J2229/42 , C07C5/2737 , C07C5/2775 , C10G45/64 , Y02P20/52 , C07C15/08
摘要： A process for preparing a transalkylation catalyst, the catalyst itself, and a transalkylation process for using the catalyst are herein disclosed. The catalyst comprises rhenium metal on a solid-acid support such as mordenite, which has been treated with a sulfur-based agent. Such treatment reduces the amount of methane produced by metal hydrogenolysis in a transalkylation process wherein heavy aromatics like A9+ are reacted with toluene to produce xylenes. Reduced methane production relative to total light ends gas production results in lower hydrogen consumption and lower reactor exotherms.
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7.发明授权Shaped catalysts for transalkylation of aromatics for enhanced xylenes production 失效用于芳族化合物烷基转移用于增强二甲苯生产的成型催化剂公开(公告)号：US06815570B1
公开(公告)日：2004-11-09
申请号：US10141294
申请日：2002-05-07
IPC分类号： C07C500
CPC分类号： C07C6/126 , B01J29/18 , B01J29/40 , B01J29/80 , B01J35/026 , B01J37/0009 , B01J2229/37 , B01J2229/42 , C07C2521/04 , C07C2521/12 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2529/78 , C07C2529/80 , Y02P20/52 , C07C15/08 , C07C15/067
摘要： A catalyst, a process for using the catalyst whereby the catalyst effectively transalkylates C7, C9, and C10 aromatics to C8 aromatics are disclosed. The catalyst comprises a support such as mordenite plus a metal component. The catalyst provides an enhanced life and activity for carrying out the transalkylation reactions at relatively low temperatures. This is achieved by reducing the maximum particle diameter of cylindrical pellets to {fraction (1/32)} inch (0.08 cm) or a trilobe to {fraction (1/16)} inch (0.16 cm).
摘要翻译： 一种催化剂，一种使用该催化剂的方法，其中该催化剂有效地将C7，C9和C10芳族化合物烷基化为C8芳族化合物。 催化剂包括支链如丝光沸石加金属组分。 催化剂提供了在较低温度下进行烷基转移反应的寿命和活性。 这通过将圆柱形丸粒的最大粒径减小到{部分（1/32英寸（0.08cm））或三叶形至{部分（1/16英寸（0.16cm））而实现。
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公开(公告)号：US6114592A
公开(公告)日：2000-09-05
申请号：US213957
申请日：1998-12-17
摘要： An improved process combination is disclosed for the selective disproportionation of toluene. The combination comprises selective hydrogenation of a toluene feedstock followed by disproportionation using a zeolitic catalyst which is oil-dropped in an aluminum phosphate binder to achieve a high yield of paraxylene. Optionally, the catalyst is selectively precoked prior to toluene disproportionation. The catalyst and process provide improved selectivity for the production of paraxylene.
摘要翻译： 公开了改进的方法组合用于甲苯的选择性歧化。 该组合包括甲苯原料的选择性氢化，然后使用沸石催化剂进行歧化，该沸石催化剂油滴在磷酸铝粘合剂中以实现高产率的对二甲苯。 任选地，在甲苯歧化之前选择性地预先催化剂。 催化剂和方法为对二甲苯的生产提供了改进的选择性。
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公开(公告)号：US08481795B2
公开(公告)日：2013-07-09
申请号：US13234673
申请日：2011-09-16
CPC分类号： C07C7/14833 , C07C6/126 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/26 , C07C2527/051 , C07C2529/18 , C07C2529/40 , Y02P20/52 , C07C15/06 , C07C15/073 , C07C15/08
摘要： A process for aromatic transalkylation and olefin reduction of a feed stream is disclosed. Transalkylation conditions produce xylenes and reduced olefins in the feed. The process may be used in a xylene production facility to minimize or avoid the necessity of feedstock pretreatment such as hydrotreating, hydrogenation, or treating with clay and/or molecular sieves.
摘要翻译： 公开了一种进料流的芳族烷基转移和烯烃还原方法。 烷基转移条件在进料中产生二甲苯和还原烯烃。 该方法可用于二甲苯生产设备中以最小化或避免原料预处理（如加氢处理，氢化或用粘土和/或分子筛处理）的必要性。
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公开(公告)号：US20110046427A1
公开(公告)日：2011-02-24
申请号：US12917045
申请日：2010-11-01
IPC分类号： C07C15/08
摘要： A process for aromatic transalkylation and olefin reduction of a feed stream is disclosed. Transalkylation conditions provide a product having increased xylene concentration and reduced olefin concentration relative to the feed. The process may be used in a xylene production facility to minimize or avoid the necessity of feedstock pretreatment such as hydrotreating, hydrogenation, or treating with clay and/or molecular sieves.
摘要翻译： 公开了一种进料流的芳族烷基转移和烯烃还原方法。 烷基转移条件提供了相对于进料的二甲苯浓度增加和烯烃浓度降低的产物。 该方法可用于二甲苯生产设备中以最小化或避免原料预处理（如加氢处理，氢化或用粘土和/或分子筛处理）的必要性。
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