公开(公告)号：US10351647B2

公开(公告)日：2019-07-16

申请号：US15558067

申请日：2016-04-15

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Matthew W. Holtcamp ,  Gregory S. Day ,  Laughlin G. McCullough ,  David F. Sanders

IPC: C08F4/76 ,  C08F210/16 ,  C08F4/64 ,  C08F4/60 ,  C08F4/659 ,  C08L23/06 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/06 ,  C08F210/14

Abstract: This invention relates to a process to polymerize olefins by contacting one or more olefins with a catalyst system comprising an organoaluminum treated layered silicate support, and a bridged metallocene compound and obtaining a polyolefin having a g′vis of 0.90 or more and an MIR of 30 or less.

公开(公告)号：US20180162973A1

公开(公告)日：2018-06-14

申请号：US15893922

申请日：2018-02-12

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Matthew W. Holtcamp ,  Matthew S. Bedoya ,  Xuan Ye ,  David F. Sanders ,  Gregory S. Day ,  Sarah J. Mattler

IPC: C08F210/16

Abstract: This invention relates to a process to polymerize olefins, particularly to produce ethylene polymers with internal unsaturation structures.

公开(公告)号：US09926396B2

公开(公告)日：2018-03-27

申请号：US15249021

申请日：2016-08-26

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Matthew W. Holtcamp ,  Matthew S. Bedoya ,  Xuan Ye ,  David F. Sanders ,  Gregory S. Day ,  Sarah J. Mattler

IPC: C08F4/6592 ,  C08F210/16 ,  C07F7/08 ,  C08F210/02

CPC classification number: C08F210/16 ,  C07F7/0803 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/02 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2800/20 ,  C08F210/14 ,  C08F2500/03

Abstract: This invention relates to a process to polymerize olefins, particularly to produce ethylene polymers with internal unsaturation structures.

公开(公告)号：US20180072823A1

公开(公告)日：2018-03-15

申请号：US15565624

申请日：2016-03-10

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Xuan Ye ,  Matthew W. Holtcamp ,  Laughlin G. McCullough ,  Jo Ann M. Canich ,  David F. Sanders ,  Gregory S. Day ,  Michelle E. Titone

IPC: C08F4/6592 ,  C08F4/02 ,  C08F210/16 ,  C08F210/14 ,  B01J31/22

Abstract: This invention relates to a catalyst system including fluorided silica, alkylalumoxane activator and a bridged monocyclopentadienyl group 4 transition metal compound, where the fluorided support has not been calcined at a temperature of 400° C. or more, and is preferably, produced using a wet mix method, particularly an aqueous method.

公开(公告)号：US09725537B2

公开(公告)日：2017-08-08

申请号：US15142084

申请日：2016-04-29

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Lubin Luo ,  Gregory S. Day

IPC: C08F4/02 ,  C08F4/6592 ,  C08F210/06 ,  C08F110/06 ,  C08F4/659

CPC classification number: C08F110/06 ,  C08F4/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/06 ,  C08F10/00 ,  C08F10/06 ,  C08F4/025 ,  C08F2500/15 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/17 ,  C08F210/16 ,  C08F2500/05 ,  C08F2/001 ,  C08F2500/24

Abstract: This invention relates to single site catalyst supportation methods involving high temperature treatment (≧40° C., e.g., 100-130° C.) to improve catalyst activity for olefin polymerization, e.g., propylene polymerization, and to the supported catalyst systems obtained by the methods, e.g., single site catalyst systems supported on a support having high average particle size (PS≧30 μm), high surface area (SA≧200 m2/g), low pore volume (PV≦2 mL/g), and a mean pore diameter range of 1≦PD≦20 nm.

公开(公告)号：US09644047B2

公开(公告)日：2017-05-09

申请号：US14324408

申请日：2014-07-07

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Jian Yang ,  Matthew W. Holtcamp ,  Garth R. Giesbrecht ,  Gregory S. Day ,  Jo Ann M. Canich ,  Lian Xiongdong

IPC: C07F17/00 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F4/659

CPC classification number: C08F10/06 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/06 ,  C08F2500/03 ,  C08F210/06 ,  C08F210/02 ,  C08F210/16

Abstract: This invention relates to a novel group 2, 3 or 4 transition metal metallocene catalyst compound having two indenyl ligands with identical substitution including, for example, cyclopropyl groups and substituted phenyl groups at the 2 and 4 positions of the catalyst, respectively, where the substituents are at the 3′ and 5′ positions of the phenyl groups.

公开(公告)号：US20170096510A1

公开(公告)日：2017-04-06

申请号：US15242357

申请日：2016-08-19

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Xuan Ye ,  Crisita Carmen H. Atienza ,  Matthew W. Holtcamp ,  David F. Sanders ,  Gregory S. Day ,  Michelle E. Titone ,  David A. Cano ,  Matthew S. Bedoya

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F4/60189 ,  C08F4/64 ,  C08F4/64189 ,  C08F4/65912 ,  C08F210/14 ,  C08F2500/03 ,  C08F4/65916 ,  C08F4/64186

Abstract: A catalyst system including the reaction product of a fluorided support, an activator, and at least a first transition metal catalyst compound; methods of making such catalyst systems, polymerization processes using such catalyst systems, and polymers made therefrom.

公开(公告)号：US20170096509A1

公开(公告)日：2017-04-06

申请号：US15242337

申请日：2016-08-19

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Crisita Carmen H. Atienza ,  Matthew W. Holtcamp ,  Xuan Ye ,  Gregory S. Day ,  David A. Cano ,  Michelle E. Titone ,  Machteld M. W. Mertens ,  Gerardo J. Majano Sanchez

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F4/60189 ,  C08F4/64 ,  C08F4/64189 ,  C08F4/65912 ,  C08F4/65916 ,  C08F110/02 ,  C08F210/14 ,  C08F2500/03 ,  C08F4/025 ,  C08F4/659

Abstract: This invention relates to a process to polymerize olefins comprising: i) contacting one or more olefins with a catalyst system comprising: 1) a support comprising an organoaluminum treated layered silicate and an inorganic oxide; and 2) a bisphenolate compound; and ii) obtaining olefin polymer having high molecular weight and layered silicate dispersed therein. Preferably the support is in the form of spheroidal particles.

公开(公告)号：US20170096506A1

公开(公告)日：2017-04-06

申请号：US15242179

申请日：2016-08-19

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Xuan Ye ,  Matthew W. Holtcamp ,  Gregory S. Day ,  Matthew S. Bedoya ,  David F. Sanders ,  Laughlin G. McCullough

IPC: C08F210/02 ,  C08J5/18

CPC classification number: C08J5/18 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F210/16 ,  C08J2323/08 ,  C08F4/64148 ,  C08F4/65904 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/01 ,  C08F2500/03

Abstract: A catalyst system including the reaction product of a fluorided support (such as a fluorided silica support) that preferably has not been calcined at a temperature of 400° C. or more, an activator and at least a first transition metal catalyst compound; methods of making such catalyst systems, polymerization processes using such catalyst systems and polymers made therefrom.

公开(公告)号：US20170015686A1

公开(公告)日：2017-01-19

申请号：US15160821

申请日：2016-05-20

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Jian Yang ,  Matthew W. Holtcamp ,  Gregory S. Day ,  Xiongdong Lian ,  Xuan Ye

IPC: C07F7/08 ,  C08F10/02

CPC classification number: C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/10 ,  C08F10/00

Abstract: This invention relates to novel bridged bis indenyl metallocene catalyst compounds where the bridge is —((R15*)2Si—Si(R15)2)— wherein, each R15 and R15* is identical or different and is a substituted or unsubstituted, branched or unbranched C1-C20 alkyl group, preferably each R15 together do not form a ring, and/or each R15* together do not form a ring, and/or R15 and R15* together do not form a ring. This invention also relates to polymerization processes to produce polymer and to polymer compositions produced by the methods described.

Abstract translation: 本发明涉及桥接为 - （（R 15 *）2 Si-Si（R 15）2） - 的桥连双茚基金属茂催化剂化合物，其中每个R 15和R 15 *相同或不同，并且是取代或未取代的支链或 未分支的C 1 -C 20烷基，优选每个R 15一起不形成环，和/或每个R 15 *不一起形成环，和/或R 15和R 15 *不一起形成环。 本发明还涉及通过所述方法制备聚合物和聚合物组合物的聚合方法。