公开(公告)号：US20170022308A1

公开(公告)日：2017-01-26

申请号：US15061015

申请日：2016-03-04

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Prasadarao Meka ,  Chon-Yie Lin ,  Todd S. Edwards ,  Christopher G. Bauch

IPC: C08F210/06 ,  C08L23/14 ,  C08K3/34

CPC classification number: C08F210/06 ,  C08F10/06 ,  C08F2500/04 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/24 ,  C08F2800/20 ,  C08K3/013 ,  C08K3/34 ,  C08L23/12 ,  C08L23/14 ,  C08L23/16 ,  C08L23/26 ,  C08L2205/03 ,  C08L2207/04

Abstract: A propylene-based impact copolymer (ICP) and composition including the ICP, the ICP comprising a polypropylene homopolymer and within the range of from 10 wt % to 45 wt % of propylene copolymer based on the weight of the ICP, wherein the copolymer comprises from 20 wt % to 44 wt % ethylene, 1-butene, 1-hexene and/or 1-octene derived units and from 80 to 60 wt % propylene-derived units based on the weight of the propylene copolymer, the propylene-based impact copolymer having a Melt Flow Rate (230° C./2.16 kg) within the range of from 10 g/10 mm to 50 g/10 mm and an Elongation at Break of greater than 70%.

Abstract translation: 基于丙烯的抗冲共聚物（ICP）和包含ICP的组合物，ICP包含聚丙烯均聚物，并且在基于ICP的重量的10重量％至45重量％的丙烯共聚物的范围内，其中共聚物包含 基于丙烯共聚物的重量，20重量％至44重量％的乙烯，1-丁烯，1-己烯和/或1-辛烯衍生的单元和80至60重量％的丙烯衍生的单元，丙烯类抗冲共聚物 熔体流动速率（230℃/ 2.16kg）在10g / 10mm至50g / 10mm的范围内，断裂伸长率大于70％。

公开(公告)号：US09309334B2

公开(公告)日：2016-04-12

申请号：US14567019

申请日：2014-12-11

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Prasadarao Meka ,  Chon-Yie Lin ,  Todd S. Edwards ,  Christopher G. Bauch

IPC: C08L23/12 ,  C08F10/06 ,  C08L23/26 ,  C08L23/16 ,  C08K3/00 ,  C08K3/34 ,  C08L23/14

CPC classification number: C08F210/06 ,  C08F10/06 ,  C08F2500/04 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/24 ,  C08F2800/20 ,  C08K3/013 ,  C08K3/34 ,  C08L23/12 ,  C08L23/14 ,  C08L23/16 ,  C08L23/26 ,  C08L2205/03 ,  C08L2207/04

Abstract: A propylene-based impact copolymer (ICP) and composition including the ICP, the ICP comprising a polypropylene homopolymer and within the range of from 10 wt % to 45 wt % of propylene copolymer based on the weight of the ICP, wherein the copolymer comprises from 20 wt % to 44 wt % ethylene, 1-butene, 1-hexene and/or 1-octene derived units and from 80 to 56 wt % propylene-derived units based on the weight of the propylene copolymer, the propylene-based impact copolymer having a Melt Flow Rate (230° C./2.16 kg) within the range of from 10 g/10 min to 50 g/10 min and an Elongation at Break of greater than 70%.

Abstract translation: 基于丙烯的抗冲共聚物（ICP）和包含ICP的组合物，ICP包含聚丙烯均聚物，并且在基于ICP的重量的10重量％至45重量％的丙烯共聚物的范围内，其中共聚物包含 基于丙烯共聚物的重量，20重量％至44重量％的乙烯，1-丁烯，1-己烯和/或1-辛烯衍生的单元和80至56重量％的丙烯衍生的单元，丙烯类抗冲共聚物 熔体流动速率（230℃/ 2.16kg）在10g / 10min至50g / 10min的范围内，断裂伸长率大于70％。

公开(公告)号：US20210179747A1

公开(公告)日：2021-06-17

申请号：US16759570

申请日：2018-08-13

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Todd S. Edwards ,  Christopher G. Bauch

IPC: C08F110/06 ,  C08F4/654 ,  B01J27/08 ,  B01J27/135 ,  B01J27/138

Abstract: A polypropylene comprising a xylene soluble fraction of 1.5 wt % by weight of the polymer and soluble fraction or less, wherein the polypropylene has a melt flow rate within a range from 50 g/10 min to 500 g/10 min and a flexural modulus within a range from 1780 MPa to 2200 MPa. The polypropylene is preferably made from contacting propylene with a solid magnesium/titanium catalyst component that has been washed at least once with a solvent having a desirable solubility parameter.

公开(公告)号：US09605096B2

公开(公告)日：2017-03-28

申请号：US14296616

申请日：2014-06-05

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Todd S. Edwards ,  Kevin W. Lawson

IPC: C08F210/06 ,  C08F2/00 ,  C08F10/00 ,  C08F110/06

CPC classification number: C08F210/06 ,  C08F2/00 ,  C08F10/00 ,  C08F110/06 ,  C08F2500/04 ,  C08F2500/12

Abstract: A method is provided for polymerizing an olefin monomer in a reactor with a highly active polyolefin polymerization catalyst system. The method includes introducing a catalyst system comprising a catalyst and a catalyst activator into the reactor containing the olefin monomer with less than 10 seconds or no pre-contacting time of the catalyst and the catalyst activator prior to introducing the catalyst and the catalyst activator into the reactor. The catalyst system may have a standard adjusted catalyst activity of greater than 10 gPgcat−1hr−1.

公开(公告)号：US10465025B2

公开(公告)日：2019-11-05

申请号：US15609835

申请日：2017-05-31

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Chon-Yie Lin ,  Todd S. Edwards ,  Christopher G. Bauch ,  Prasadarao Meka

IPC: C08L23/16 ,  C08L23/14 ,  C08F210/06 ,  C08F10/06 ,  C08L23/12 ,  C08K3/34 ,  C08L23/26 ,  C08K3/013

Abstract: A propylene-based impact copolymer having a high gloss and suitable for appliance components comprising a polypropylene homopolymer and within a range of from 6 wt % to 20 wt % of propylene copolymer based on the weight of the impact copolymer, wherein the copolymer comprises from 20 wt % to 44 wt % ethylene, and/or C4 to C10 α-olefin derived units and the remainder propylene-derived units based on the weight of the propylene copolymer, the impact copolymer having a melt flow rate (230° C./2.16 kg) within a range of from 10 g/10 min to 50 g/10 min.

公开(公告)号：US20150252127A1

公开(公告)日：2015-09-10

申请号：US14434825

申请日：2013-10-08

Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

Inventor： Prasadarao Meka ,  Saifudin M. Abubakar ,  Yumin Chen ,  Todd S. Edwards

IPC: C08F210/06 ,  C08L91/06 ,  C08K3/36 ,  C08L23/14 ,  H01B1/20 ,  C08K3/34

CPC classification number: C08F210/06 ,  C08F10/06 ,  C08F110/06 ,  C08K3/34 ,  C08K3/36 ,  C08L23/14 ,  C08L91/06 ,  H01B1/20 ,  C08F4/6465 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/17 ,  C08F2500/19 ,  C08F2500/04

Abstract: Polypropylene resin comprising at least 50 mol % propylene, an MWD (Mw/Mn) of greater than 5, a branching index (g′) of at least 0.95, and a melt strength of at least 20 cN determined using an extensional rheometer at 190° C. A catalyst system comprising a Ziegler-Natta catalyst comprising a non-aromatic internal electron donor, and first and second external electron donors comprising different organosilicon compounds, and a method to produce a polypropylene resin comprising contacting propylene monomers at propylene polymerization conditions with the catalyst system are also disclosed.

Abstract translation: 包含至少50mol％丙烯的聚丙烯树脂，MWD（Mw / Mn）大于5，支链指数（g'）至少为0.95，熔体强度为至少20cN，使用拉伸流变仪在190℃下测定 包含含有非芳族内电子给体的齐格勒 - 纳塔催化剂和包含不同有机硅化合物的第一和第二外部电子给体的催化剂体系，以及一种生产聚丙烯树脂的方法，包括使丙烯单体在丙烯聚合条件下与 还公开了催化剂体系。

公开(公告)号：US20150031842A1

公开(公告)日：2015-01-29

申请号：US14296616

申请日：2014-06-05

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Todd S. Edwards ,  Kevin W. Lawson

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F2/00 ,  C08F10/00 ,  C08F110/06 ,  C08F2500/04 ,  C08F2500/12

Abstract: A method is provided for polymerizing an olefin monomer in a reactor with a highly active polyolefin polymerization catalyst system. The method includes introducing a catalyst system comprising a catalyst and a catalyst activator into the reactor containing the olefin monomer with less than 10 seconds or no pre-contacting time of the catalyst and the catalyst activator prior to introducing the catalyst and the catalyst activator into the reactor. The catalyst system may have a standard adjusted catalyst activity of greater than 10 gPgcat−1hr−1.

Abstract translation: 提供了一种使反应器中的烯烃单体与高活性聚烯烃聚合催化剂体系聚合的方法。 该方法包括在将催化剂和催化剂活化剂引入到催化剂和催化剂活化剂之前，将包含催化剂和催化剂活化剂的催化剂体系引入到含有烯烃单体的反应器中，其中催化剂和催化剂活化剂在催化剂和催化剂活化剂中的时间少于10秒， 反应堆。 催化剂体系可具有大于10gPgcat-1hr-1的标准调节催化剂活性。

公开(公告)号：US11505685B2

公开(公告)日：2022-11-22

申请号：US16624630

申请日：2018-04-11

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Todd S. Edwards ,  Christopher G. Bauch

IPC: C08L23/16 ,  C08F210/16 ,  C08L23/12 ,  C08F2/01 ,  C08F4/02 ,  C08F4/659 ,  C08F299/00 ,  C08L23/14 ,  C08F2/00

Abstract: Disclosed is a polypropylene with an MFR of at least 20 g/10 min comprising a homopolypropylene and within a range from 2 wt % to 20 wt % of a propylene-α-olefin copolymer by weight of the polypropylene, where the homopolypropylene has a MFR within a range from 30 g/10 min to 200 g/10 min, where the propylene-α-olefin copolymer comprises within a range from 30 wt % to 50 wt % α-olefin derived units by weight of the propylene-α-olefin copolymer, and has an IV within a range from 4 to 9 dL/g. The polypropylene may be obtained by combining a Ziegler-Natta catalyst having two transition metals with propylene in reactors in series to produce the homopolypropylene followed by a gas phase reactor to produce a propylene-α-olefin copolymer blended with the homopolypropylene.

公开(公告)号：US20180237555A1

公开(公告)日：2018-08-23

申请号：US15749818

申请日：2016-07-25

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Christopher G. Bauch ,  Todd S. Edwards ,  Daniel L. Bilbao ,  Kevin W. Lawson ,  Blu E. Englehorn

IPC: C08F8/04 ,  C08F210/02 ,  C08F210/06 ,  C08F210/16 ,  C08F4/642 ,  C08F4/622 ,  C08F110/06 ,  C08F2/38

CPC classification number: C08F8/04 ,  C08F2/38 ,  C08F4/6226 ,  C08F4/642 ,  C08F110/06 ,  C08F210/02 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2800/10 ,  C08L23/12 ,  C08F2420/02 ,  C08F2/001 ,  C08L23/16

Abstract: Disclosed is a method of reducing and/or regulating the level of hydrogen in a polymerization reactor comprising contacting a first feed comprising a first amount of hydrogen with a hydrogenation catalyst prior to entering a polymerization reactor to form a second feed; then contacting the second feed having a second amount of hydrogen with monomers and a polymerization catalyst in a polymerization reactor to form a polymer. The first and second feeds may reside in a feed line from one reactor to another, a monomer feed line to the reactor, or in a recycle line to and from the same reactor.

公开(公告)号：US09453093B2

公开(公告)日：2016-09-27

申请号：US14434825

申请日：2013-10-08

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Prasadarao Meka ,  Saifudin M. Abubakar ,  Yumin Chen ,  Todd S. Edwards

IPC: C08F210/06 ,  C08L23/14 ,  C08F110/06 ,  C08F10/06 ,  C08K3/34 ,  C08K3/36 ,  C08L91/06 ,  H01B1/20

CPC classification number: C08F210/06 ,  C08F10/06 ,  C08F110/06 ,  C08K3/34 ,  C08K3/36 ,  C08L23/14 ,  C08L91/06 ,  H01B1/20 ,  C08F4/6465 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/17 ,  C08F2500/19 ,  C08F2500/04

Abstract: Polypropylene resin comprising at least 50 mol % propylene, an MWD (Mw/Mn) of greater than 5, a branching index (g′) of at least 0.95, and a melt strength of at least 20 cN determined using an extensional rheometer at 190° C. A catalyst system comprising a Ziegler-Natta catalyst comprising a non-aromatic internal electron donor, and first and second external electron donors comprising different organosilicon compounds, and a method to produce a polypropylene resin comprising contacting propylene monomers at propylene polymerization conditions with the catalyst system are also disclosed.

Abstract translation: 包含至少50mol％丙烯的聚丙烯树脂，MWD（Mw / Mn）大于5，支链指数（g'）至少为0.95，熔体强度为至少20cN，使用拉伸流变仪在190℃下测定 包含含有非芳族内电子给体的齐格勒 - 纳塔催化剂和包含不同有机硅化合物的第一和第二外部电子给体的催化剂体系，以及一种生产聚丙烯树脂的方法，包括使丙烯单体在丙烯聚合条件下与 还公开了催化剂体系。