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公开(公告)号：US08720555B2
公开(公告)日：2014-05-13
申请号：US13252373
申请日：2011-10-04
申请人： Feng Liang , Bradley L. Todd , Rajesh K. Saini , Stanley J. Heath
发明人： Feng Liang , Bradley L. Todd , Rajesh K. Saini , Stanley J. Heath
IPC分类号： E21B43/25 , E21B43/267 , C09K8/80
摘要： A method for diverting fluids across a perforation tunnel in high-rate water pack operations may include providing a wellbore extending into a subterranean formation, wherein a perforation tunnel provides a fluid connection between the wellbore and the subterranean formation; providing a diverting particulate that comprises a degradable plasticized polymer coating on a particulate; placing the diverting particulate into the perforation tunnel, wherein the step of placing the diverting particulate forms a particulate pack within the subterranean formation and the perforation tunnel; allowing the degradable plasticized polymer coating to deform and fill the interstitial spaces within the particulate pack in the perforation tunnel such that the fluid conductivity between the wellbore and the subterranean formation is substantially blocked; and allowing the plasticized polymer coating to degrade over time thereby substantially restoring the fluid conductivity between the wellbore and the subterranean formation.
摘要翻译： 在高速水包装操作中将流体转移穿过穿孔隧道的方法可以包括提供延伸到地下地层中的井眼，其中穿孔在井筒和地下地层之间提供流体连接; 提供包含颗粒上的可降解塑化聚合物涂层的转向颗粒; 将转向颗粒放置到穿孔隧道中，其中放置转向颗粒的步骤在地层和穿孔隧道内形成颗粒状包装; 允许可降解塑化聚合物涂层变形并填充穿孔隧道内的颗粒包装内的间隙空间，使得井筒和地下地层之间的流体传导性基本上被阻挡; 并且允许塑化的聚合物涂层随着时间的推移而降解，从而基本上恢复井筒和地下地层之间的流体传导性。
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2.发明申请Degradable Fluid Sealing Compositions Having an Adjustable Degradation Rate and Methods for Use Thereof 审中-公开可降解流体密封组合物具有可调节的降解速率及其使用方法公开(公告)号：US20130233546A1
公开(公告)日：2013-09-12
申请号：US13414269
申请日：2012-03-07
申请人： Feng Liang , Rajesh K. Saini , Bradley L. Todd , Stanley J. Heath
发明人： Feng Liang , Rajesh K. Saini , Bradley L. Todd , Stanley J. Heath
IPC分类号： E21B33/00
摘要： When performing subterranean treatment operations, it can be desirable to temporarily divert or block fluid flow by forming a degradable fluid seal. Methods for forming a degradable fluid seal can comprise: providing a sealing composition comprising: a degradable polymer, and a water-soluble material comprising a first portion and a second portion of rigid particulates, each portion having a sealing time and a particulate size distribution associated therewith, the particulate size distributions of the first portion and the second portion differing from one another; determining an amount of the first portion relative to the second portion needed to produce a degradable fluid seal having a desired sealing time that is different than that of the sealing time of either the first portion or the second portion; introducing the sealing composition into a subterranean formation; and allowing the sealing composition to form a degradable fluid seal in the subterranean formation.
摘要翻译： 当进行地下处理操作时，可以期望通过形成可降解流体密封来临时转移或阻止流体流动。 用于形成可降解流体密封件的方法可以包括：提供密封组合物，其包含：可降解聚合物和包含刚性颗粒的第一部分和第二部分的水溶性材料，每个部分具有密封时间和相关的颗粒尺寸分布 由此，第一部分和第二部分的颗粒尺寸分布彼此不同; 确定产生具有与第一部分或第二部分的密封时间不同的期望密封时间的可降解流体密封件所需的相对于第二部分的第一部分的量; 将密封组合物引入地层; 并且允许密封组合物在地层中形成可降解的流体密封。
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3.发明授权Methods of fluid loss control, diversion, and sealing using deformable particulates 有权使用可变形颗粒的流体损失控制，引流和密封方法公开(公告)号：US08936086B2
公开(公告)日：2015-01-20
申请号：US13252349
申请日：2011-10-04
申请人： Feng Liang , Bradley L. Todd , Thomas D. Welton , Rajesh K. Saini
发明人： Feng Liang , Bradley L. Todd , Thomas D. Welton , Rajesh K. Saini
摘要： Method including the steps of providing a treatment fluid that comprises a base fluid and polymeric particulates and introducing the treatment fluid into a subterranean formation having a temperature above about 65° C. The polymeric particulates comprise a degradable polymer and a plasticizer and exhibit a Tg above about −15° C. When the polymeric particulates are placed into a subterranean formation having a temperature above about 65° C. they transform from rigid form to malleable form and are able to provide fluid loss, seal the rock surfaces for fluid diversion, or plug an area along the annulus of a well bore. The malleable particulates then degrade over time in the subterranean formation.
摘要翻译： 方法包括提供包括基础流体和聚合物颗粒的处理流体并将处理流体引入温度高于约65℃的地下地层的步骤。聚合物颗粒包含可降解聚合物和增塑剂并且显示Tg高于 约-15℃。当将聚合物颗粒置于温度高于约65℃的地下地层中时，它们从刚性形式转变为可延展形式并且能够提供流体损失，密封岩石表面用于流体分流，或 沿着井眼的环带堵塞一个区域。 然后随着时间的推移，可延展的颗粒在地层中降解。
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4.发明申请Methods of Fluid Loss Control, Diversion, and Sealing Using Deformable Particulates 有权使用可变形颗粒的流体损失控制，引流和密封方法公开(公告)号：US20130081813A1
公开(公告)日：2013-04-04
申请号：US13252349
申请日：2011-10-04
申请人： Feng Liang , Bradley L. Todd , Thomas D. Welton , Rajesh K. Saini
发明人： Feng Liang , Bradley L. Todd , Thomas D. Welton , Rajesh K. Saini
IPC分类号： E21B43/22
摘要： Method including the steps of providing a treatment fluid that comprises a base fluid and polymeric particulates wherein the polymeric particulates comprise a degradable polymer and a plasticizer and exhibit a Tg above about −15° C.; introducing the treatment fluid into a subterranean formation having a temperature above about 65° C. such that the particulates transform from rigid to malleable form and are able to provide fluid loss, seal the rock surfaces for fluid diversion, or plug an area along the annulus of a well bore; and, degrading the malleable particulates over time in the subterranean formation.
摘要翻译： 方法包括提供包含基础流体和聚合物颗粒的处理流体的步骤，其中聚合物颗粒包含可降解聚合物和增塑剂，并且具有高于约-15℃的Tg。 将处理流体引入具有高于约65℃的温度的地下地层，使得颗粒从刚性变形为可延展形式并且能够提供流体损失，密封岩石表面用于流体分流，或者沿着环形空间 的井眼; 并且在地下地层中随着时间的推移降解可延展的颗粒物。
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公开(公告)号：US20120024526A1
公开(公告)日：2012-02-02
申请号：US13252373
申请日：2011-10-04
申请人： Feng Liang , Bradley L. Todd , Rajesh K. Saini
发明人： Feng Liang , Bradley L. Todd , Rajesh K. Saini
IPC分类号： E21B43/04
摘要： A method for diverting fluids across a perforation tunnel in high-rate water pack operations may include providing a wellbore extending into a subterranean formation, wherein a perforation tunnel provides a fluid connection between the wellbore and the subterranean formation; providing a diverting particulate that comprises a degradable plasticized polymer coating on a particulate; placing the diverting particulate into the perforation tunnel, wherein the step of placing the diverting particulate forms a particulate pack within the subterranean formation and the perforation tunnel; allowing the degradable plasticized polymer coating to deform and fill the interstitial spaces within the particulate pack in the perforation tunnel such that the fluid conductivity between the wellbore and the subterranean formation is substantially blocked; and allowing the plasticized polymer coating to degrade over time thereby substantially restoring the fluid conductivity between the wellbore and the subterranean formation.
摘要翻译： 在高速水包装操作中将流体转移穿过穿孔隧道的方法可以包括提供延伸到地下地层中的井眼，其中穿孔在井筒和地下地层之间提供流体连接; 提供包含颗粒上的可降解塑化聚合物涂层的转向颗粒; 将转向颗粒放置到穿孔隧道中，其中放置转向颗粒的步骤在地层和穿孔隧道内形成颗粒状包装; 允许可降解塑化聚合物涂层变形并填充穿孔隧道内的颗粒包装内的间隙空间，使得井筒和地下地层之间的流体传导性基本上被阻挡; 并且允许塑化的聚合物涂层随着时间的推移而降解，从而基本上恢复井筒和地下地层之间的流体传导性。
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6.发明申请公开(公告)号：US20130081821A1
公开(公告)日：2013-04-04
申请号：US13252327
申请日：2011-10-04
申请人： Feng Liang , Rajesh K. Saini , Bradley L. Todd
发明人： Feng Liang , Rajesh K. Saini , Bradley L. Todd
IPC分类号： E21B37/00 , C08L67/04 , C09D167/04 , B82Y99/00 , B82Y30/00
CPC分类号： C09K8/03 , C08J3/201 , C08J2367/04 , C08L101/16 , C09D167/04 , C09K8/50 , C09K8/516
摘要： The present invention relates to the use of composite material in downhole applications, and more particularly, relates to methods of making composite material comprising reinforced amorphous polylactic acid and methods of use related thereto. Some methods comprise providing an amorphous polylactic acid and a solid reinforcing material; forming a composite material by melting the amorphous polylactic acid and mixing it with the solid reinforcing material; and, using the composite material in a downhole application.
摘要翻译： 本发明涉及复合材料在井下应用中的应用，更具体地涉及制备包含增强的无定形聚乳酸的复合材料的方法及其相关使用方法。 一些方法包括提供无定形聚乳酸和固体增强材料; 通过熔化无定形聚乳酸并将其与固体增强材料混合而形成复合材料; 并且在井下应用中使用复合材料。
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公开(公告)号：US20130081801A1
公开(公告)日：2013-04-04
申请号：US13252403
申请日：2011-10-04
申请人： Feng Liang , Bradley L. Todd , Thomas D. Welton , Rajesh K. Saini
发明人： Feng Liang , Bradley L. Todd , Thomas D. Welton , Rajesh K. Saini
摘要： The present invention relates to the use of degradable coatings suitable for use on downhole tools. In particular, the present invention relates to pliable coatings for use on downhole tools that have been designed to be able to resist flaking or breaking off of the tool in response to a physical shock. Some embodiments of the present invention provide methods of reacting lactic acid, glycolic acid, or a combination thereof in a polymerization reaction to form a degradable polymer; combining the degradable polymer and a plasticizer to form a coating composition; applying the coating composition to a downhole tool; placing the coated downhole tool into a portion of a subterranean formation; and, hydrolyzing the degradable polymer of the coating composition to release an acid and degrade the coating.
摘要翻译： 本发明涉及适用于井下工具的可降解涂料的应用。 特别地，本发明涉及用于井下工具的柔性涂层，其被设计成能够抵抗物理冲击而抵抗工具的剥落或破裂。 本发明的一些实施方案提供了在聚合反应中使乳酸，乙醇酸或其组合反应形成可降解聚合物的方法; 组合可降解聚合物和增塑剂以形成涂料组合物; 将涂料组合物施加到井下工具; 将涂覆的井下工具放置在地层的一部分中; 并且水解涂料组合物的可降解聚合物以释放酸并降解涂层。
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公开(公告)号：US08887816B2
公开(公告)日：2014-11-18
申请号：US13193844
申请日：2011-07-29
申请人： Feng Liang , Stanley J. Heath , Bradley L. Todd
发明人： Feng Liang , Stanley J. Heath , Bradley L. Todd
CPC分类号： E21B41/00
摘要： A downhole tool or a component thereof may comprise a plasticized polymer composition that comprises a polymer and a water-soluble plasticizer, wherein the plasticized polymer composition has a first deflection test value. The tool may be exposed to an aqueous-based medium where the water-soluble plasticizer may leach out of the tool such that the plasticized polymer composition has a second deflection test value after exposure to the aqueous-based medium that is less than about 10% of the first deflection test value.
摘要翻译： 井下工具或其组分可以包含包含聚合物和水溶性增塑剂的增塑聚合物组合物，其中增塑聚合物组合物具有第一挠曲测试值。 该工具可以暴露于水性介质中，其中水溶性增塑剂可以从工具中浸出，使得增塑的聚合物组合物在暴露于含水介质后具有小于约10％的第二挠曲测试值， 的第一个挠度测试值。
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公开(公告)号：US20130025859A1
公开(公告)日：2013-01-31
申请号：US13193844
申请日：2011-07-29
申请人： Feng Liang , Stanley J. Heath , Bradley L. Todd
发明人： Feng Liang , Stanley J. Heath , Bradley L. Todd
CPC分类号： E21B41/00
摘要： Methods including providing a downhole tool or a component thereof comprising a plasticized polymer composition that comprises a polymer and a water-soluble plasticizer, wherein the plasticized polymer composition has a first deflection test value; exposing the downhole tool or the component thereof to an aqueous-based medium; allowing the water-soluble plasticizer to leach out of the downhole tool or the component thereof, wherein the plasticized polymer composition has a second deflection test value after exposure to the aqueous-based medium, and wherein the second deflection test value is less than about 10% of the first deflection test value; and placing the downhole tool or the component thereof in a subterranean formation.
摘要翻译： 包括提供井下工具或其组分的方法包括包含聚合物和水溶性增塑剂的增塑聚合物组合物，其中所述增塑聚合物组合物具有第一偏转测试值; 将井下工具或其组分暴露于水基介质; 允许水溶性增塑剂从井下工具或其组分中浸出，其中增塑聚合物组合物在暴露于含水介质之后具有第二挠曲测试值，并且其中第二偏转测试值小于约10 ％的第一偏转测试值; 并将井下工具或其组件放置在地层中。
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公开(公告)号：US20110214859A1
公开(公告)日：2011-09-08
申请号：US12718382
申请日：2010-03-05
IPC分类号： E21B43/16
摘要： Treatment fluids comprising an aqueous base fluid, a compliant cellulosic viscosifying agent, a crosslinking agent, and a protective ligand are provided. The present invention provides methods of using the treatment fluids in subterranean formations. One example of a suitable method includes providing a fracturing fluid comprising an aqueous base fluid, a compliant cellulosic viscosifying agent, a crosslinking agent, and a protective ligand and introducing the fracturing fluid into at least a portion of a subterranean formation at a rate and pressure sufficient to create or enhance at least one or more fractures in the subterranean formation.
摘要翻译： 提供了包含基础水溶液，柔顺纤维素增粘剂，交联剂和保护配体的处理流体。 本发明提供了在地下地层中使用处理流体的方法。 合适方法的一个实例包括提供包含含水基础流体，顺应性纤维素增粘剂，交联剂和保护性配体的压裂流体，并将压裂流体以速率和压力引入至地下地层的至少一部分 足以产生或增强地下地层中的至少一个或多个裂缝。
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