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公开(公告)号：US06936566B2
公开(公告)日：2005-08-30
申请号：US10395421
申请日：2003-03-24
申请人： Filip Mees , Etienne Vansant , Kun Wang , Richard B. Hall , Marcel Johannes Janssen , Luc Roger Marc Martens , An Verberckmoes , Guang Cao
发明人： Filip Mees , Etienne Vansant , Kun Wang , Richard B. Hall , Marcel Johannes Janssen , Luc Roger Marc Martens , An Verberckmoes , Guang Cao
CPC分类号： B01J37/0209 , B01J29/84 , B01J29/85 , B01J2229/14 , B01J2229/30 , C07C1/20 , C07C2531/14 , C10G3/49 , C10G3/62 , C10G2300/4081 , C10G2300/708 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/04 , C07C11/06
摘要： The invention is directed to a method for modifying a microporous metalloaluminophosphate molecular sieve, the method comprising the steps of a) introducing a compound containing at least one M-X group within the cages of said microporous molecular sieve; and b) reacting said compound containing at least one M-X group with the acid groups located in the cages of the molecular sieve, wherein the compound containing at least one M-X group is selected from the group consisting of compounds of formula MX3, compounds of formula M2X6, and mixtures thereof, M being a metal belonging to Group 13 of the Periodic Table, and each X independently being a hydrogen or halogen atom. Preferably, X is a hydrogen atom. The present invention also relates to modified metalloaluminophosphate molecular sieves, preferably modified silicoaluminophosphate molecular sieves, as well as to the use of these modified molecular sieves in catalytic processes, such as processes for the conversion of oxygenated hydrocarbon feedstocks.
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公开(公告)号：US06906233B2
公开(公告)日：2005-06-14
申请号：US10317425
申请日：2002-12-12
申请人： Filip Mees , Etienne Vansant , Kun Wang , Richard B. Hall , Marcel Johannes Janssen , Luc Roger Marc Martens , An Amandine Verberckmoes , Guang Cao
发明人： Filip Mees , Etienne Vansant , Kun Wang , Richard B. Hall , Marcel Johannes Janssen , Luc Roger Marc Martens , An Amandine Verberckmoes , Guang Cao
CPC分类号： B01J37/0209 , B01J29/84 , B01J29/85 , B01J2229/14 , B01J2229/30 , C07C1/20 , C07C2531/14 , C10G3/49 , C10G3/62 , C10G2300/4081 , C10G2300/708 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/04 , C07C11/06
摘要： The invention is directed to a method for modifying a microporous metalloaluminophosphate molecular sieve, the method comprising the steps of a) introducing a compound containing at least one M-X group within the cages of said microporous molecular sieve; and b) reacting said compound containing at least one M-X group with the acid groups located in the cages of the molecular sieve, wherein the compound containing at least one M-X group is selected from the group consisting of compounds of formula MX3, compounds of formula M2X6, and mixtures thereof, M being a metal belonging to Group 13 of the Periodic Table, and each X independently being a hydrogen or halogen atom. Preferably, X is a hydrogen atom. The present invention also relates to modified metalloaluminophosphate molecular sieves, preferably modified silicoaluminophosphate molecular sieves, as well as to the use of these modified molecular sieves in catalytic processes, such as processes for the conversion of oxygenated hydrocarbon feedstocks.
摘要翻译： 本发明涉及一种改性微孔金属铝磷酸盐分子筛的方法，该方法包括以下步骤：a）将含有至少一个M-X基团的化合物引入所述微孔分子筛的笼中; 和b）使含有至少一个MX基团的化合物与位于分子筛网笼中的酸基反应，其中含有至少一个MX基团的化合物选自式MX 3化合物， / SUB，式M 2 X 6的化合物及其混合物，M是属于周期表第13族的金属，并且每个X独立地为氢 或卤素原子。 优选地，X是氢原子。 本发明还涉及改性的金属铝磷酸盐分子筛，优选改性的硅铝磷酸盐分子筛，以及这些改性分子筛在催化方法中的用途，例如转化含氧烃原料的方法。
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公开(公告)号：US06897180B2
公开(公告)日：2005-05-24
申请号：US10295994
申请日：2002-11-15
CPC分类号： B01J29/85 , B01J2229/24 , B01J2229/30 , B01J2229/38 , B01J2229/42 , C07C1/20 , Y02P30/42 , C07C11/02
摘要： The invention is directed to a method of stabilizing metalloaluminophosphate molecular sieves and catalysts derived therefrom. In particular, the invention is directed to a method of treating such molecular sieves with chemisorbed ammonia, which may be easily desorbed before or during use and after storage. The invention is also directed to formulating the molecular sieve into a catalyst useful in a process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
摘要翻译： 本发明涉及一种稳定金属铝磷酸盐分子筛和由其衍生的催化剂的方法。 特别地，本发明涉及用化学吸附的氨处理这种分子筛的方法，其可以在使用之前或之后在储存之前或之后容易地解吸。 本发明还涉及将分子筛配制成可用于从原料，优选含氧化合物原料生产烯烃，优选乙烯和/或丙烯的方法中的催化剂。
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公开(公告)号：US07193122B2
公开(公告)日：2007-03-20
申请号：US11072796
申请日：2005-03-04
IPC分类号： C07C1/00 , C07C209/00
CPC分类号： B01J29/85 , B01J2229/24 , B01J2229/30 , B01J2229/38 , B01J2229/42 , C07C1/20 , Y02P30/42 , C07C11/02
摘要： The invention is directed to a method of stabilizing metalloaluminophosphate molecular sieves and catalysts derived therefrom. In particular, the invention is directed to a method of treating such molecular sieves with chemisorbed ammonia, which may be easily desorbed before or during use and after storage. The invention is also directed to formulating the molecular sieve into a catalyst useful in a process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
摘要翻译： 本发明涉及一种稳定金属铝磷酸盐分子筛和由其衍生的催化剂的方法。 特别地，本发明涉及用化学吸附的氨处理这种分子筛的方法，其可以在使用之前或之后在储存之前或之后容易地解吸。 本发明还涉及将分子筛配制成可用于从原料，优选含氧化合物原料生产烯烃，优选乙烯和/或丙烯的方法中的催化剂。
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5.发明授权公开(公告)号：US07309806B2
公开(公告)日：2007-12-18
申请号：US11285699
申请日：2005-11-22
申请人： Peter N. Loezos , Shun Chong Fung , Stephen Neil Vaughn , Kenneth Ray Clem , James H. Beech , Nicolas P. Coute , Marcel Johannes Janssen , Luc Roger Marc Martens , Karl G. Strohmaier
发明人： Peter N. Loezos , Shun Chong Fung , Stephen Neil Vaughn , Kenneth Ray Clem , James H. Beech , Nicolas P. Coute , Marcel Johannes Janssen , Luc Roger Marc Martens , Karl G. Strohmaier
CPC分类号： B01J29/85 , B01J29/84 , B01J37/10 , B01J2229/24 , B01J2229/36 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2300/807 , C10G2400/20 , Y02P30/20 , Y02P30/42 , Y10S585/906 , Y10S585/951 , C07C11/02
摘要： The invention is directed to methods for protecting metalloaluminophosphate molecular sieves, particularly silicoaluminophosphate (SAPO) molecular sieves, from loss of catalytic activity due to contact with a gas containing water. The methods of the invention provide procedures that enable activated sieve to contact water vapor, within a certain range of time, temperature, and water partial pressure conditions, before the sieve becomes substantially deactivated.
摘要翻译： 本发明涉及用于保护金属铝磷酸盐分子筛，特别是硅铝磷酸盐（SAPO）分子筛的方法，这是由于与含有气体的气体接触导致的催化活性丧失。 本发明的方法提供了在筛子基本上失活之前，在一定时间，温度和水分压条件下使活化筛接触水蒸汽的方法。
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公开(公告)号：US07259287B2
公开(公告)日：2007-08-21
申请号：US10641718
申请日：2003-08-15
申请人： James H. Beech , Richard E. Walter , Shun Chong Fung , Peter N. Loezos , Marcel Johannes Janssen , Luc Roger Marc Martens , Kenneth Ray Clem , Stephen Neil Vaughn
发明人： James H. Beech , Richard E. Walter , Shun Chong Fung , Peter N. Loezos , Marcel Johannes Janssen , Luc Roger Marc Martens , Kenneth Ray Clem , Stephen Neil Vaughn
IPC分类号： C07C1/00
CPC分类号： C10G3/62 , C10G3/49 , C10G11/00 , C10G49/24 , C10G50/00 , C10G2300/1037 , C10G2300/4006 , C10G2300/4031 , C10G2400/02 , C10G2400/10 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y02P30/20 , Y10S585/951
摘要： The invention is directed to methods of starting up reaction systems. The reaction systems are those that use catalysts that comprise molecular sieves, particularly metalloaluminophosphate molecular sieves, especially metalloaluminophosphate molecular sieves which are susceptible to loss of catalytic activity due to contact with water molecules. The methods provide appropriate mechanisms of heating and loading the activated molecular sieves to protect against loss of catalytic activity that can occur due to contact with water molecules.
摘要翻译： 本发明涉及启动反应体系的方法。 反应体系是使用包含分子筛的催化剂，特别是金属铝磷酸盐分子筛，特别是金属铝磷酸盐分子筛，它们由于与水分子接触而易于损失催化活性。 该方法提供适当的加热和加载活化分子筛的机制，以防止由于与水分子接触而可能发生的催化活性的损失。
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7.发明授权公开(公告)号：US07015174B2
公开(公告)日：2006-03-21
申请号：US10600123
申请日：2003-06-20
申请人： Peter N. Loezos , Shun Chong Fung , Stephen Neil Vaughn , Kenneth Ray Clem , James H. Beech , Nicolas P. Coute , Marcel Johannes Janssen , Luc Roger Marc Martens , Karl G. Strohmaier
发明人： Peter N. Loezos , Shun Chong Fung , Stephen Neil Vaughn , Kenneth Ray Clem , James H. Beech , Nicolas P. Coute , Marcel Johannes Janssen , Luc Roger Marc Martens , Karl G. Strohmaier
IPC分类号： B01J29/02 , B01J27/18 , B01J27/182
CPC分类号： B01J29/85 , B01J29/84 , B01J37/10 , B01J2229/24 , B01J2229/36 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2300/807 , C10G2400/20 , Y02P30/20 , Y02P30/42 , Y10S585/906 , Y10S585/951 , C07C11/02
摘要： The invention is directed to methods for protecting metalloaluminophosphate molecular sieves, particularly silicoaluminophosphate (SAPO) molecular sieves, from loss of catalytic activity due to contact with a gas containing water. The methods of the invention provide procedures that enable activated sieve to contact water vapor, within a certain range of time, temperature, and water partial pressure conditions, before the sieve becomes substantially deactivated.
摘要翻译： 本发明涉及用于保护金属铝磷酸盐分子筛，特别是硅铝磷酸盐（SAPO）分子筛的方法，这是由于与含有气体的气体接触导致的催化活性丧失。 本发明的方法提供了在筛子基本上失活之前，在一定时间，温度和水分压条件下使活化筛接触水蒸汽的方法。
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公开(公告)号：US07495142B2
公开(公告)日：2009-02-24
申请号：US11818496
申请日：2007-06-14
IPC分类号： C07C1/00
CPC分类号： C10G3/49 , B01J29/84 , B01J29/85 , B01J2229/24 , C07C1/20 , C07C209/16 , C07C2529/85 , C10G3/48 , C10G2300/802 , C10G2300/805 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/06 , C07C211/04
摘要： Metalloaluminophosphate molecular sieves and metalloaluminophosphate molecular sieve catalyst particles are protecting from degradation by water by maintaining said molecular sieves or catalysts in contact with a liquid mixture of alcohol and water, the mixture of alcohol and water containing from 45 wt % to 99.8 wt % alcohol. The metalloaluminophosphate molecular sieves and metalloaluminophosphate molecular sieve catalyst particles which have been protected in such fashion catalyze the conversion of feedstocks to hydrocarbons.
摘要翻译： 金属铝磷酸盐分子筛和金属铝磷酸盐分子筛催化剂颗粒通过保持所述分子筛或催化剂与醇和水的液体混合物（含有45重量％至99.8重量％的醇的水和水的混合物）接触来防止水分降解。 以这种方式被保护的金属铝磷酸盐分子筛和金属铝磷酸盐分子筛催化剂颗粒催化原料转化为烃。
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公开(公告)号：US07241716B2
公开(公告)日：2007-07-10
申请号：US10704741
申请日：2003-11-10
IPC分类号： B01J27/182 , B01J27/00
CPC分类号： C10G3/49 , B01J29/84 , B01J29/85 , B01J2229/24 , C07C1/20 , C07C209/16 , C07C2529/85 , C10G3/48 , C10G2300/802 , C10G2300/805 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/06 , C07C211/04
摘要： Metalloaluminophosphate molecular sieves and metalloaluminophosphate molecular sieve catalyst particles are protecting from degradation by water by maintaining said molecular sieves or catalysts in contact with a liquid mixture of alcohol and water, the mixture of alcohol and water containing from 45 wt % to 99.8 wt % alcohol. The metalloaluminophosphate molecular sieves and metalloaluminophosphate molecular sieve catalyst particles which have been protected in such fashion catalyze the conversion of feedstocks to hydrocarbons.
摘要翻译： 金属铝磷酸盐分子筛和金属铝磷酸盐分子筛催化剂颗粒通过保持所述分子筛或催化剂与醇和水的液体混合物（含有45重量％至99.8重量％的醇的水和水的混合物）接触来防止水分降解。 以这种方式被保护的金属铝磷酸盐分子筛和金属铝磷酸盐分子筛催化剂颗粒催化原料转化为烃。
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10.发明授权公开(公告)号：US06897179B2
公开(公告)日：2005-05-24
申请号：US10461621
申请日：2003-06-13
申请人： Shun Chong Fung , Stephen Neil Vaughn , Marcel Johannes Janssen , Luc Roger Marc Martens , Kenneth Ray Clem
发明人： Shun Chong Fung , Stephen Neil Vaughn , Marcel Johannes Janssen , Luc Roger Marc Martens , Kenneth Ray Clem
IPC分类号： B01J29/83 , B01J29/85 , B01J37/00 , B01J27/18 , B01J27/182
CPC分类号： B01J29/83 , B01J29/85 , B01J37/0045 , Y02P30/20
摘要： Disclosed is a method of protecting the loss of catalytic activity of metalloaluminophosphate molecular sieve, particularly a SAPO molecular sieve, from contact with moisture. The method involves heating the metalloaluminophosphate molecular sieve so as to remove template, and provide a molecular sieve in sufficiently dry form for storage.
摘要翻译： 公开了一种保护金属铝磷酸盐分子筛，特别是SAPO分子筛的催化活性丧失与水分接触的方法。 该方法包括加热金属铝磷酸盐分子筛以除去模板，并提供足够干燥形式的分子筛用于储存。
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