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    Thermoplastic moulding compositions
    2.
    发明授权
    Thermoplastic moulding compositions 失效
    热塑性成型组合物

    公开(公告)号：US4205140A

    公开(公告)日：1980-05-27

    申请号：US852628

    申请日：1977-11-18

    申请人： Lothar Liebig ,  Frank Wingler ,  Dieter Margotte ,  Werner Nouvertne

    发明人： Lothar Liebig ,  Frank Wingler ,  Dieter Margotte ,  Werner Nouvertne

    IPC分类号： C08L25/12 ,  C08L33/12 ,  C08L51/00 ,  C08L51/04 ,  C08L55/00 ,  C08L55/02 ,  C08L69/00 ,  C08L67/06

    CPC分类号： C08L51/04 ,  C08L25/12 ,  C08L33/12 ,  C08L55/02 ,  C08L69/00

    摘要： A thermoplastic moulding composition comprising:(1.) 80 to 20 parts by wt. of a thermoplastic polycarbonate based on a dihydroxy diaryl alkane,(2.) 20 to 80 parts by wt. of a graft polymer of2.2. a monomer mixture, polymerized onto2.1. a diene rubber with a glass transition temperature below -30.degree. C., of2.2.1. 95 to 50% by wt. of styrene, methyl methacrylate or a mixture thereof; and2.2.2. 50 to 5% by wt. of acrylonitrile, methacrylonitrile or a mixture thereof, the ratio by wt. of rubber (2.1) to monomer mixture (2.2.) being in the range of from 80:20 and 10:90, and the moulding composition containing from 5 to 35% by wt. of the rubber (2.1.), and(3.) 5 to 75 parts by wt. of a copolymer which is chemically uniform in structure and which comprises:(3.1.) 93 to 50 parts by wt. of styrene, methyl methacrylate or a mixture thereof;(3.2.) 40 to 5 parts by weight of acrylonitrile, methacrylonitrile or a mixture thereof; and(3.3.) 2 to 30 parts by wt. of maleic acid anhydride.

    摘要翻译： 一种热塑性模塑组合物，其包含：（1）80〜20重量份 的基于二羟基二芳基烷烃的热塑性聚碳酸酯，（2.）20至80重量份。 的2.2的接枝聚合物。 单体混合物，聚合到2.1上。 二烯橡胶，玻璃化转变温度低于-30℃，为2.2.1。 95〜50重量％ 的苯乙烯，甲基丙烯酸甲酯或其混合物; 和2.2.2。 50〜5重量％ 丙烯腈，甲基丙烯腈或其混合物，重量比。 的橡胶（2.1）与单体混合物（2.2。）的摩尔比为80:20和10:90，模塑组合物含有5-35重量％ 的橡胶（2.1。）和（3.）5〜75重量份。 的共聚物，其结构化学均匀，并且包括：（3.1。）93至50重量份。 的苯乙烯，甲基丙烯酸甲酯或其混合物; （3.2。）40-5份（重量）丙烯腈，甲基丙烯腈或其混合物; 和（3.3。）2〜30重量份。 的马来酸酐。

    Process for the production of thermoplastic molding materials based on vinyl polymers
    3.
    发明授权
    Process for the production of thermoplastic molding materials based on vinyl polymers 失效
    用于生产基于乙烯基聚合物的热塑性成型材料的方法

    公开(公告)号：US4181788A

    公开(公告)日：1980-01-01

    申请号：US908763

    申请日：1978-05-23

    申请人： Frank Wingler ,  Lothar Liebig ,  Gerd Wassmuth ,  Martin Ullrich ,  Manfred Hederich

    发明人： Frank Wingler ,  Lothar Liebig ,  Gerd Wassmuth ,  Martin Ullrich ,  Manfred Hederich

    IPC分类号： B01J19/24 ,  C08F2/00 ,  C08F2/02 ,  C08F6/00 ,  C08F6/28 ,  C08F6/10

    CPC分类号： B01J19/243 ,  C08F6/28 ,  B01J2219/00094

    摘要： A process for the production of thermoplastically processible moulding materials based on vinyl polymers of high chemical and molecular uniformity and having residual monomer contents of less than 0.1 mol % which comprises the steps of:(i) mass homogeneous phase polymerization of at least one vinyl monomer in a stirred continuously charged tank reactor to a conversion of from 25 to 60 mol %;(ii) directly concentrating the syrup consisting of residual monomers and vinyl polymer dissolved therein obtained from step (i) in a spiral tube evaporator at a temperature of from 60.degree. to 250.degree. C. and at a pressure of 100 m bar to 35 bar to obtain a solid content of vinyl polymer of from 40 to 90 mol %;(iii) directly charging the concentrate obtained from step (ii) to the inlet zone of a screw evaporator which consists of at least two sequential zones in order to effect further concentration, in which a first zone at a pressure of from 10 to 300 m bar and at a temperature of from 100.degree. to 250.degree. C. concentrates the vinyl polymer to a solid content of from 80 to 99 mol-%, and each subsequent zone at a pressure of 1 to 200 m bar and at a temperature of 150.degree. to 250.degree. C. concentrates the vinyl polymer to a solid content of at least 99.9 %; and(iv) recycling the residual monomers from step (ii) and the residual monomers from said first zone of the screw evaporator to the stirred and charged tank reactor without intermediate cleaning.

    摘要翻译： 一种生产基于乙烯基聚合物的热塑性可加工成型材料的方法，其具有高的化学和分子均匀性并且具有小于0.1摩尔％的残余单体含量，其包括以下步骤：（i）至少一种乙烯基单体的均匀相聚合 在搅拌的连续加入的釜式反应器中以25至60mol％的转化率; （ii）将由步骤（i）获得的残留单体和乙烯基聚合物组成的糖浆直接浓缩在螺旋管式蒸发器中，温度为60-250℃，压力为100巴，至35巴 以获得40至90mol％的乙烯基聚合物的固体含量; （iii）将由步骤（ii）获得的浓缩物直接装入由至少两个顺序区组成的螺杆蒸发器的入口区域，以便进一步浓缩，其中第一区域的压力为10-300μm 并且在100至250℃的温度下将乙烯基聚合物浓缩至固体含量为80至99mol％，并且每个后续区域在1至200mbar的压力和150℃的温度下 DEG至250℃，将乙烯基聚合物浓缩至至少99的固体含量。

    Thermoplastic moulding compositions
    5.
    发明授权
    Thermoplastic moulding compositions 失效
    热塑性成型组合物

    公开(公告)号：US4205141A

    公开(公告)日：1980-05-27

    申请号：US852630

    申请日：1977-11-18

    申请人： Lothar Liebig ,  Frank Wingler ,  Gert Humme ,  Richard Prinz

    发明人： Lothar Liebig ,  Frank Wingler ,  Gert Humme ,  Richard Prinz

    IPC分类号： C08L23/00 ,  C08L25/00 ,  C08L25/12 ,  C08L33/00 ,  C08L33/02 ,  C08L33/12 ,  C08L33/18 ,  C08L35/06 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08L51/06 ,  C08L55/02 ,  C08L69/00 ,  C08L101/00 ,  C08L67/06

    CPC分类号： C08L51/04 ,  C08L25/12 ,  C08L33/12 ,  C08L55/02 ,  C08L69/00

    摘要： A thermoplastic moulding composition comprising:(1) 80 to 20 parts by weight of a thermoplastic polycarbonate based on a dihydroxy diarylalkane,(2) 0 to 60 parts by weight of a graft copolymer of a(2.2) monomer mixture of(2.2.1) 95 to 50% by weight of styrene, methyl methacrylate or a mixture thereof; and(2.2.2) 50 to 5% by weight of acrylonitrile, methacrylonitrile or a mixture thereof,polymerized onto(2.1) a rubber which has a glass temperature below -20.degree. C., and which contains less than 30 C.dbd.C-double bonds per 1,000 carbon atoms, the moulding composition containing from 0 to 35% by weight of the rubber (2.1), and(3) 5 to 75 parts by weight of a copolymer which is chemically uniform in structure and comprises:(3.1) 95 to 50% by weight of styrene, methyl methacrylate or a mixture thereof;(3.2) 40 to 5% by weight of acrylonitrile, methacrylonitrile or a mixture thereof; and(3.3) 2 to 30% by weight of maleic acid anhydride, the sum of 3.1, 3.2 and 3.3 being equal to 100% by weight.

    摘要翻译： 一种热塑性模塑组合物，其包含：（1）基于二羟基二芳基烷烃的80至20重量份的热塑性聚碳酸酯，（2）0至60重量份的（2.2）（2.2.1）单体混合物的接枝共聚物 ）95〜50重量％的苯乙烯，甲基丙烯酸甲酯或其混合物; 和（2.2.2）50-5重量％的丙烯腈，甲基丙烯腈或其混合物，聚合到（2.1）玻璃温度低于-20℃的橡胶上，并且其含有小于30℃= C- 每1000个碳原子的双键，所述模塑组合物含有0至35重量％的橡胶（2。

    Thermoplastic molding compositions
    7.
    发明授权
    Thermoplastic molding compositions 失效
    热塑性成型组合物

    公开(公告)号：US4163032A

    公开(公告)日：1979-07-31

    申请号：US953000

    申请日：1978-10-20

    申请人： Lothar Liebig ,  Frank Wingler ,  Karl-Heinz Ott ,  Gert Humme ,  Alfred Pischtschan

    发明人： Lothar Liebig ,  Frank Wingler ,  Karl-Heinz Ott ,  Gert Humme ,  Alfred Pischtschan

    IPC分类号： C08L51/00 ,  C08L23/00 ,  C08L25/00 ,  C08L25/12 ,  C08L51/02 ,  C08L51/04 ,  C08L51/06 ,  C08L101/00

    CPC分类号： C08L25/12 ,  C08L51/04 ,  C08L51/06

    摘要： A thermoplastic molding composition having improved flow, toughness. and heat distortion comprising a polymer mixture of (A) 25 to 95% by weight of a graft polymer of 70 to 30% by weight of a mixture of styrene (95 to 50% by weight) and acrylonitrile (5 to 50% by weight) on 30 to 70% by weight of an EPDM-rubber, and (B) 50 to 75% by weight of a terpolymer of acrylonitrile, maleic acid anhydride and styrene, the terpolymer containing 10 to 30 parts by weight of acrylonitrile, 7.5 to 15 parts by weight of maleic acid anhydride, and 82.5 to 55 parts by weight of styrene in copolymerised form.

    摘要翻译： 具有改善的流动性，韧性的热塑性模塑组合物。 和热变形，其包含（A）25至95重量％的70至30重量％的苯乙烯（95至50重量％）和丙烯腈（5至50重量％）的混合物的接枝聚合物的聚合物混合物 ），30〜70重量％的EPDM-橡胶，（B）50〜75重量％的丙烯腈，马来酸酐和苯乙烯的三元共聚物，三元共聚物含有10〜30重量份的丙烯腈，7.5〜 15重量份马来酸酐和82.5至55重量份共聚形式的苯乙烯。

    Continuous bulk polymerization process
    8.
    发明授权
    Continuous bulk polymerization process 失效
    连续本体聚合工艺

    公开(公告)号：US4141934A

    公开(公告)日：1979-02-27

    申请号：US668984

    申请日：1976-03-22

    申请人： Frank Wingler ,  Adolf Schmidt ,  Lothar Liebig ,  Gerd Wassmuth

    发明人： Frank Wingler ,  Adolf Schmidt ,  Lothar Liebig ,  Gerd Wassmuth

    IPC分类号： C08F2/00 ,  C08F2/02 ,  C08F212/10 ,  C08F220/00 ,  C08F220/42 ,  C08F257/02

    CPC分类号： C08F212/10

    摘要： Copolymers ofA 22 to 96 mol-% of styrene and/or .alpha.-methyl styrene,B 0 to 78 mol-% of at least one monoolefinically unsaturated monomer containing nitrile groups, andC 0 to 50 mol-% of at least one monoolefinically unsaturated monomer different from A or B are obtained by continuous bulk polymerization in a homogeneous liquid phase, in several process stages, in one or more different temperature ranges and in the presence of one or more initiators with different dissociation times in each temperature range and under pressures of from 1 to 20 bars.In first stage the monomers are copolymerized with backmixing up to a conversion of from 10 - 60 mol-% in an ideally mixed tank reactor and then after optionally additional addition of further parts of monomers copolymerization is continued with backmixing in a completely flooded, self-cleaning polymerization kneader up to a residual monomer content of from 10-50 mol-%.Residual monomers are continuously removed from the copolymer up to a content of less than 0.5% by weight based on the copolymer.The process according to the invention provides uniform, compatible, homogeneous products which are free from gel-like particles and which combine improved transparency with greater dimensional stability under heat and better mechanical properties together with improved processibility.

    摘要翻译： A 22至96摩尔％的苯乙烯和/或α-甲基苯乙烯的共聚物，B 0至78摩尔％的至少一种含有腈基的单烯属不饱和单体和C 0至50摩尔％的至少一种单烯烃 不同于A或B的不饱和单体通过在均相液相中，在几个工艺阶段中，在一个或多个不同温度范围内并且在一个或多个在每个温度范围和下面具有不同解离时间的引发剂的存在下连续本体聚合获得 压力为1至20巴。

    Rubber dispersions II
    9.
    发明授权
    Rubber dispersions II 失效
    橡胶分散体II

    公开(公告)号：US4454305A

    公开(公告)日：1984-06-12

    申请号：US399712

    申请日：1982-07-19

    申请人： Christian Lindner ,  Lothar Liebig ,  Karl-Heinz Ott

    发明人： Christian Lindner ,  Lothar Liebig ,  Karl-Heinz Ott

    IPC分类号： C08L33/00 ,  C08C1/00 ,  C08F279/02 ,  C08J3/02 ,  C08J3/09 ,  C08L7/00 ,  C08L9/00 ,  C08L21/00 ,  C08L25/00 ,  C08L33/02 ,  C08L33/04 ,  C08L51/00 ,  C08L51/02 ,  C08L67/00 ,  C08F279/04

    CPC分类号： C08J3/091 ,  C08F279/02 ,  C08J2321/00

    摘要： Stable, free-flowing dispersions in organic liquids of rubbers in the form of discrete particles having an average diameter of from 100 to 3000 nm which contains:A--as rubber, from 1 to 20% by weight, based on the total dispersion, of a crosslinked diene rubber; B--from 0 to 20% by weight, based on the total dispersion, of water in the form of a water-in-oil emulsion; C--as the continuous organic phase, from 99 to 66% by weight, based on the total dispersion, of (a) C.sub.1 -C.sub.10 alkyl acrylates or alkyl methacrylates, methyl methacrylate, ethyl acrylate or n-hexyl acrylate; or (b) a mixture of from 85 to 50% by weight of styrene or .alpha.-methyl styrene and from 15 to 50% by weight of acrylonitrile, methacrylonitrile or C.sub.1 -C.sub.6 alkyl acrylates or alkyl methacrylates, methyl methacrylate, ethyl acrylate, n-hexyl acrylate; or (c) a mixture of from 85 to 50% by weight of a C.sub.1 -C.sub.10 alkyl acrylate or alkyl methacrylate and from 15 to 50% by weight of acrylonitrile, methacrylonitrile or styrene; up to 60% by weight of a liquid hydrocarbon can be added to and mixed with (a), (b) and (c),and a process for producing said dispersions.

    摘要翻译： 平均直径为100至3000nm的离散颗粒形式的橡胶有机液体中的稳定的自由流动的分散体，其包含：A-橡胶，基于总分散体积的1至20重量％ 交联二烯橡胶; B为0至20重量％，基于总分散体积为油包水乳液形式的水; （a）丙烯酸C1-C10烷基酯或甲基丙烯酸烷基酯，甲基丙烯酸甲酯，丙烯酸乙酯或丙烯酸正己酯的总分散体的99至66重量％ 或（b）85至50重量％的苯乙烯或α-甲基苯乙烯和15至50重量％的丙烯腈，甲基丙烯腈或丙烯酸C 1 -C 6烷基酯或甲基丙烯酸烷基酯的混合物，甲基丙烯酸甲酯，丙烯酸乙酯， 丙烯酸己酯 或（c）85至50重量％的丙烯酸C1-C10烷基酯或甲基丙烯酸烷基酯和15至50重量％的丙烯腈，甲基丙烯腈或苯乙烯的混合物; 可以向（a），（b）和（c）中加入高达60重量％的液体烃，并与（a），（b）和（c）混合，以及制备所述分散体的方法。

    Rubber dispersions
    10.
    发明授权
    Rubber dispersions 失效
    橡胶分散体

    公开(公告)号：US4360620A

    公开(公告)日：1982-11-23

    申请号：US283930

    申请日：1981-07-17

    申请人： Christian Lindner ,  Lothar Liebig ,  Karl-Heinz Ott

    发明人： Christian Lindner ,  Lothar Liebig ,  Karl-Heinz Ott

    IPC分类号： C08L33/00 ,  C08C1/00 ,  C08J3/02 ,  C08J3/09 ,  C08L7/00 ,  C08L9/00 ,  C08L21/00 ,  C08L23/00 ,  C08L25/00 ,  C08L33/02 ,  C08L33/04 ,  C08L51/00 ,  C08L51/02 ,  C08L67/00 ,  C08L101/00 ,  C08K5/20 ,  C08K5/32

    CPC分类号： C08J3/091 ,  C08J2321/00 ,  C08J2333/06

    摘要： Stable, free-flowing dispersions in organic liquids of rubbers in the form of discrete particles having an average diameter of from 100 to 3,000 nm which contain: A--as rubber, from 1 to 20% by weight, based on the total dispersion, of a crosslinked diene rubber or a crosslinked, rubber-like acrylate polymer; B--from 0 to 15% by weight, based on the total dispersion, of water in the form of a water-in-oil emulsion; C--as the continuous organic phase, from 99 to 45% by weight, based on the total dispersion, of a mixture of from 95 to 60% by weight of a liquid aliphatic hydrocarbon having up to 20 carbon atoms; or C.sub.6 -C.sub.12 aromatic hydrocarbon or a halogen derivative thereof and from 5 to 40% by weight of a C.sub.1 -C.sub.12 alkanol, a ketone containing up to 8 carbon atoms, a formamide or a nitrile containing up to 6 carbon atoms, and a process for their manufacture.

    摘要翻译： 稳定的，自由流动的分散体在平均直径为100至3000nm的离散颗粒形式的橡胶的有机液体中，其含有：基于总分散体的1至20重量％的A-橡胶， 交联二烯橡胶或交联橡胶状丙烯酸酯聚合物; B为0至15重量％，基于总分散体积为油包水乳液形式的水; 作为连续有机相的99至45重量％的基于总分散体的95至60重量％的具有至多20个碳原子的液体脂族烃的混合物; 或C 6 -C 12芳族烃或其卤素衍生物和5至40重量％的C 1 -C 12链烷醇，含有至多8个碳原子的酮，甲酰胺或含有至多6个碳原子的腈，以及方法 为他们的制造。