摘要:
A non-aqueous electrolyte secondary battery is provided that uses as a positive electrode active material a low-cost lithium-containing transition metal composite oxide containing Ni and Mn as its main components, to improve the output power characteristics so that it can be used suitably for an electric power source for, for example, hybrid electric vehicles. A non-aqueous electrolyte secondary battery has a positive electrode (11) containing a positive electrode active material, a negative electrode (12) containing a negative electrode active material, and a non-aqueous electrolyte solution (14) in which a solute is dissolved in a non-aqueous solvent. In the positive electrode active material, Nb2O5 in which the amount of niobium is 0.5 mol % with respect to the total amount of the transition metals and TiO2 in which the amount of titanium is 0.5 mol % with respect to the total amount of the transition metals are disposed on a surface of Li1.06Ni10.56Mn10.38O2.
摘要翻译:提供一种非水电解质二次电池,其使用含有Ni和Mn作为其主要成分的低成本含锂过渡金属复合氧化物作为正极活性物质,以提高输出功率特性,使其可以适当地使用 用于例如混合动力电动车辆的电力源。 非水电解质二次电池具有含有正极活性物质的正极(11),含有负极活性物质的负极(12)和溶解有溶质的非水电解液(14) 在非水溶剂中。 在正极活性物质中,相对于过渡金属的总量,钛的含量相对于过渡金属的总量为0.5摩尔%,其中铌的量为0.5摩尔%的Nb 2 O 5 设置在Li1.06Ni10.56Mn10.38O2的表面上。
摘要:
A positive electrode active material of a nonaqueous electrolyte secondary battery is improved by using an inexpensive lithium transition metal oxide containing nickel and manganese as main components. Output characteristics of the battery under various temperature conditions are thereby improved, and the battery is suitable as a power supply of a hybrid vehicle. The battery includes a positive electrode including a positive electrode active material, a negative electrode including a negative electrode active material, and a nonaqueous electrolyte prepared by dissolving a solute in a nonaqueous solvent. The positive electrode active material includes positive electrode active material particles composed of a lithium transition metal complex oxide having a layered structure containing nickel and manganese as main components, and at least one niobium-containing material selected from a Li—Nb—O compound and a Li—Ni—Nb—O compound, the at least one niobium-containing material being sintered onto surfaces of the positive electrode active material particles.
摘要:
A non-aqueous electrolyte secondary battery including a positive electrode having a positive electrode mixture layer containing a positive electrode active material, a binder, and a conductive agent, and a negative electrode having a negative electrode active material capable of intercalating and deintercalating lithium. The positive electrode active material includes a layered lithium-transition metal composite oxide represented by the compositional formula LiaNixM(1-x)O2 where 0
摘要:
A non-aqueous electrolyte secondary battery includes: a positive electrode containing a positive electrode active material, a negative electrode containing a negative electrode active material; and a non-aqueous electrolyte having lithium ion conductivity. The positive electrode includes a lithium-containing transition metal oxide having a layered structure and being represented by the general formula Li1+x(NiaMnbCoc)O2+α, where x+a+b+c=1, 0.7≦a+b, 0≦x≦0.1, 0≦c/(a+b)
摘要翻译:非水电解质二次电池包括:含有正极活性物质的正极,含有负极活性物质的负极; 和具有锂离子传导性的非水电解质。 正极包括层状结构的含锂过渡金属氧化物,由通式Li1 + x(NiaMnbCoc)O2 +α表示,其中x + a + b + c = 1,0.7 <= a + b, 0 <= x <= 0.1,0 <= c /(a + b)<0.35,0.7 <= a / b <= 2.0,-0.1 <=α<= 0.1。 非水电解质含有具有草酸络合物作为阴离子的锂盐。
摘要:
A non-aqueous electrolyte secondary battery having a positive electrode (11) containing a positive electrode active material, a negative electrode (12) containing a negative electrode active material, and a non-aqueous electrolyte solution (14) in which a solute is dissolved in a non-aqueous solvent. The positive electrode active material is obtained by sintering a titanium-containing oxide on a surface of a layered lithium-containing transition metal oxide represented by the general formula Li1+xNiaMnbCocO2+d, where x, a, b, c, and d satisfy the conditions x+a+b+c=1, 0.7≦a+b, 0
摘要翻译:具有含有正极活性物质的正极(11),含有负极活性物质的负极(12)和溶解有溶质的非水电解液(14)的非水电解质二次电池 在非水溶剂中。 正极活性物质是通过在通式Li1 + xNiaMnbCocO2 + d表示的层状含锂过渡金属氧化物的表面上烧结含钛氧化物而得到的,其中x,a,b,c和d满足 条件x + a + b + c = 1,0.7&nlE; a + b,0
摘要:
A non-aqueous electrolyte secondary battery using lithium-containing transition metal composite oxide which has a layer structure, contains a lot of Ni and Mn and is inexpensive as a positive electrode active material and attaining high output characteristics even under low temperature environment is provided.The non-aqueous electrolyte secondary battery includes a positive electrode 11 containing a positive electrode active material, a negative electrode 12 containing a negative electrode active material and a non-aqueous electrolyte 14 having lithium ion conductivity, wherein lithium-containing transition metal composite oxide having a layer structure and being represented by a general formula Li1+xNiaMnbCocO2+d wherein x, a, b, c and d satisfy x+a+b+c=1, 0.25≦a≦0.60, 0.25≦b≦0.60, 0≦c≦0.40, 0≦x≦0.10, 0.7≦a/b≦2.0 and −0.1≦d≦0.1 is used as the positive electrode active material of positive electrode, and the surface of positive electrode active material is covered with an amorphous carbon material and a conductive agent of amorphous carbon material is inserted between particles of the positive electrode active material.
摘要翻译:提供具有层状结构的含有锂的过渡金属复合氧化物的非水电解质二次电池,含有大量的Ni和Mn,并且作为正极活性物质便宜,并且即使在低温环境下也获得高的输出特性。 非水电解质二次电池包括含有正极活性物质的正极11,含有负极活性物质的负极12和具有锂离子传导性的非水电解质14,其中含有锂的过渡金属复合氧化物具有 其中x,a,b,c和d满足x + a + b + c = 1,0.25&nlE; a&nlE; 0.60,0.25&lt; 1; b&nlE; 0.60, 0&nlE; c&nlE; 0.40,0和nlE; x和nlE; 0.10,0.7&nlE; a / b&nlE; 2.0和-0.1&amp; nlE; d&nlE; 0.1用作正极正极活性物质,正极活性物质的表面被覆盖 将无定形碳材料和无定形碳材料的导电剂插入正极活性物质的颗粒之间。
摘要:
A non-aqueous electrolyte secondary battery has a positive electrode (11) containing a positive electrode active material, a negative electrode (12) containing a negative electrode active material, and a non-aqueous electrolyte solution (14) in which a solute is dissolved in a non-aqueous solvent. The positive electrode active material is obtained by sintering a titanium-containing oxide on a surface of a layered lithium-containing transition metal oxide represented by the general formula Li1+xNiaMnbCocO2+d, where x, a, b, c, and d satisfy the conditions x+a+b+c=1, 0.7≦a+b, 0≦x≦0.1, 0≦c/(a+b)
摘要翻译:非水电解质二次电池具有含有正极活性物质的正极(11),含有负极活性物质的负极(12)和溶解有溶质的非水电解液(14) 在非水溶剂中。 正极活性物质是通过在通式Li1 + xNiaMnbCocO2 + d表示的层状含锂过渡金属氧化物的表面上烧结含钛氧化物而得到的,其中x,a,b,c和d满足 条件x + a + b + c = 1,0.7 <= a + b,0 <= x <= 0.1,0 <= c /(a + b)<0.35,0.7 <= a / b <= 2.0, -0.1 <= d <= 0.1。
摘要:
A nonaqueous electrolyte secondary battery which has a positive electrode containing lithium cobalt oxide as a positive active material, a negative electrode containing a graphite material and a nonaqueous electrolyte solution containing ethylene carbonate as a solvent and which is charged with an end-of-charge voltage of at least 4.3 V. Characteristically, the battery uses, as the positive active material, lithium cobalt oxide obtained by firing a mixture of a lithium salt, tricobalt tetraoxide (Co3O4) and a zirconium compound and having particle surfaces onto which the zirconium compound adheres.
摘要翻译:具有含有作为正极活性物质的钴酸锂的正极的非水电解质二次电池,含有石墨材料的负极和含有碳酸亚乙酯作为溶剂的非水电解液,并充入充电电压 特别地,电池使用通过焙烧锂盐,四氧化四钴(Co 3 O 4)和锆化合物并具有锆化合物附着的颗粒表面的混合物而获得的钴酸锂作为正极活性材料 。
摘要:
The storage characteristics in a charged state are improved in a non-aqueous electrolyte secondary battery containing a lithium cobalt oxide as a positive electrode active material. The non-aqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material; a negative electrode containing a negative electrode active material other than metallic lithium; and a non-aqueous electrolyte. The positive electrode active material contains a lithium cobalt oxide as its main component. The non-aqueous electrolyte contains 0.1 to 10 volume % of a compound having an ether group. The positive electrode active material and the negative electrode active material are contained so that the charge capacity ratio of the negative electrode to the positive electrode is from 1.0 to 1.2 when the battery is charged until the potential of the positive electrode reaches 4.4 to 4.5 V (vs. Li/Li+)
摘要:
A non-aqueous electrolyte secondary battery including a positive electrode containing a positive active material, a negative electrode containing a negative active material and a non-aqueous electrolyte, characterized in that lithium transition metal complex oxide A formed by allowing LiCoO2 to contain at least both of Zr and Mg and lithium transition metal complex oxide B having a layered structure and containing at least both of Mn and Ni as transition metals are mixed and used as said positive active material, and vinylene carbonate and divinyl sulfone are contained in said non-aqueous electrolyte.