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    Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide hydrogen ethylene and acetylene-(LAW072)
    1.
    发明授权
    Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide hydrogen ethylene and acetylene-(LAW072) 失效
    含有一氧化碳氢乙烯和乙炔的多组分合成气的直接加氢甲酰化（LAW072）

    公开(公告)号：US5600017A

    公开(公告)日：1997-02-04

    申请号：US563838

    申请日：1995-11-28

    申请人： Gabor Kiss ,  Michael G. Matturro ,  Harry W. Deckman ,  Istvan T. Horvath ,  Anthony M. Dean ,  Frank Hershkowitz ,  Raymond A. Cook

    发明人： Gabor Kiss ,  Michael G. Matturro ,  Harry W. Deckman ,  Istvan T. Horvath ,  Anthony M. Dean ,  Frank Hershkowitz ,  Raymond A. Cook

    IPC分类号： C07C45/50

    CPC分类号： C07C45/50 ,  Y02P20/582

    摘要： The invention is a process for hydroformylating multicomponent syngas feed streams containing CO, H.sub.2, C.sub.2 to C.sub.5 olefins and mixtures thereof and C.sub.2 to C.sub.5 alkynes and mixtures thereof by contacting the multicomponent syngas feed stream with a solution of an oil soluble rhodium complex catalyst produced by complexing in solution a low valence Rh and an oil soluble triorganophoshorous compound wherein the catalyst has a P/Rh ratio of at least 30, a concentration of Rh in solution from about 1 to about 1000 ppm by weight, a total concentration of coordinatively active P of at least about 0.01 mol/l, and a ratio of [P]/p.sub.co of at least 0.1 mmol/l/kPa, wherein [P] is the total concentration of coordinatively active phosphorous in the solution, and p.sub.co is the partial pressure of CO, to produce the corresponding C.sub.3 to C.sub.6 aldehydes. The process has utility for the hydroformylation of streams that contain olefins and alkynes.

    摘要翻译： 本发明是一种通过使多组分合成气进料流与油溶性铑配合物催化剂溶液接触而将含有CO，H 2，C 2至C 5烯烃及其混合物和C 2 -C 5炔烃及其混合物的多组分合成气原料流加氢甲酰化的方法， 在低价Rh和油溶性三有机磷化合物溶液中络合，其中催化剂的P / Rh比为至少30，溶液中Rh的浓度为约1至约1000重量ppm，配位活性P 至少约0.01mol / l，[P] / pco为至少0.1mmol / l / kPa的比例，其中[P]是溶液中配位活性磷的总浓度，pco是分压 的CO，以产生相应的C3至C6醛。 该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。

    Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
    2.
    发明授权
    Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene 失效
    含有一氧化碳，氢气，乙烯和乙炔的多组分合成气的直接加氢甲酰化

    公开(公告)号：US5675041A

    公开(公告)日：1997-10-07

    申请号：US573052

    申请日：1995-12-15

    申请人： Gabor Kiss ,  Frank Hershkowitz ,  Harry W. Deckman ,  Michael Gerard Matturro ,  Istvan T. Horvath ,  Anthony M. Dean ,  Raymond A. Cook

    发明人： Gabor Kiss ,  Frank Hershkowitz ,  Harry W. Deckman ,  Michael Gerard Matturro ,  Istvan T. Horvath ,  Anthony M. Dean ,  Raymond A. Cook

    IPC分类号： C07C45/50

    CPC分类号： C07C45/50 ,  Y02P20/582

    摘要： The invention is a process for production of C.sub.3 to C.sub.6 aldehydes by hydroformylating a mixture containing: (a) C.sub.2 to C.sub.5 olefins and mixtures thereof, and (b) (i) C.sub.2 to C.sub.5 alkynes and mixtures thereof or (ii) C.sub.3 to C.sub.5 cumulated dienes and mixtures thereof or (iii) mixtures of (i) and (ii), with CO, H.sub.2 and a solution of a rhodium complex catalyst produced by complexing Rh and an organophosphorus compound at a concentration of Rh in solution from 1 to 1000 ppm by weight. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio of at least 30. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio greater than the value R.sub.L defined by the formula: ##EQU1## in which R.sub.B is the P/Rh ratio sufficient for a catalytically active Rh complex, pKa.sub.TPP is the pKa value for triphenylphosphine, pKa.sub.L is the pKa value for the triorganophosphorus compound, R is the gas constant, and .DELTA.S.sub.B is 35(N-1) cal/mole/.degree.K., N is the number of P-Rh attachments per ligand molecule. The process has utility for the hydroformylation of streams that contain olefins and alkynes.

    摘要翻译： 本发明是通过加氢甲酰化含有：（a）C 2〜C 5烯烃及其混合物的混合物，和（b）（ⅰ）C2〜C5炔烃及其混合物或（ⅱ）C3〜C5 累积的二烯及其混合物，或（iii）（ⅰ）和（ⅱ）的混合物与CO，H 2和铑络合物催化剂的溶液形成，所述铑配合物催化剂是通过使Rh和溶液中Rh浓度为1〜1000的有机磷化合物 重量ppm。 或者，铑络合物催化剂的溶液的P / Rh原子比可以至少为30.另外，铑络合物催化剂的溶液可以具有大于由下式定义的值RL的P / Rh原子比： 其中RB是催化活性Rh配合物的P / Rh比，pKaTPP是三苯基膦的pKa值，pKaL是三有机磷化合物的pKa值，R是气体常数，DELTA SB是35（N-1 ）cal / mole / DEGK，N是每个配体分子的P-Rh附着物的数目。 该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。

    Low temperature halogenation of alkanes
    3.
    发明授权
    Low temperature halogenation of alkanes 失效
    低温卤化烷烃

    公开(公告)号：US5276226A

    公开(公告)日：1994-01-04

    申请号：US956706

    申请日：1992-10-05

    申请人： Istvan T. Horvath ,  Raymond A. Cook ,  Gabor Kiss

    发明人： Istvan T. Horvath ,  Raymond A. Cook ,  Gabor Kiss

    IPC分类号： C07C17/10 ,  C07C17/00 ,  C07C19/00

    CPC分类号： C07C17/10

    摘要： The invention relates to a process for selectively producing alkyl halides from alkanes, such as methane and ethane at relatively mild temperatures and pressures in an organic liquid phase in the presence of halogen and transition metal complex. The alkane may be neat if in a liquid form, or may be solubilized with a suitable organic solvent, if the alkane not a liquid at reaction conditions. The reaction is for a time, under conditions of temperature and pressure and in effective amounts that will permit the formation of alkyl halides. Optional hydrolysis to the corresponding alcohols may follow. The alkyl halides have utility as precursors for alternative fuels, such as methanol.

    摘要翻译： 本发明涉及在卤素和过渡金属络合物存在下，在有机液相中相对温和的温度和压力下从烷烃如甲烷和乙烷中选择性地制备烷基卤的方法。 如果在反应条件下烷烃不是液体，则烷烃可以是纯的，如果是液体形式，或者可以用合适的有机溶剂溶解。 在温度和压力的条件下反应一段时间，并且有效量可以形成烷基卤。 可以按照相应的醇进行任选的水解。 烷基卤化物可用作替代燃料（例如甲醇）的前体。

    Polymer production at supercritical conditions
    7.
    发明申请
    Polymer production at supercritical conditions 审中-公开
    聚合物在超临界条件下的生产

    公开(公告)号：US20080153997A1

    公开(公告)日：2008-06-26

    申请号：US11714546

    申请日：2007-03-06

    申请人： Gary L. Casty ,  Raymond A. Cook ,  Gabor Kiss ,  Patrick Brant

    发明人： Gary L. Casty ,  Raymond A. Cook ,  Gabor Kiss ,  Patrick Brant

    IPC分类号： C08F4/42 ,  C08F2/00 ,  C08F4/46

    CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/544 ,  C08F4/64144 ,  C08F2/06 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/09 ,  C08F2500/03

    摘要： This invention relates to a process to polymerize olefins comprising contacting, at a temperature of 60° C. or more and a pressure of at least 15 MPa, one or more olefin monomers having three or more carbon atoms, with: 1) a catalyst system comprising one or more activators and one or more nonmetallocene metal-centered, heteroaryl ligand catalyst compounds, where the metal is chosen from the Group 4, 5, 6, the lanthanide series, or the actinide series of the Periodic Table of the Elements, 2) optionally one or more comonomers, 3) optionally diluent or solvent, and 40 optionally solvent, wherein: a) the olefin monomers and any comonomers are present in the polymerization system at 40 weight % or more, b) the monomer having three or more carbon atoms is present at 80 wt % or more based upon the weight of all monomers and comonomers present in the feed, c) the polymerization occurs at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, in the event the solid-fluid phase transition temperature of the polymerization system cannot be determined then the polymerization occurs at a temperature above the fluid fluid phase transition temperature.

    摘要翻译： 本发明涉及一种聚合烯烃的方法，包括在60℃或更高的温度和至少15MPa的压力下使一种或多种具有三个或更多个碳原子的烯烃单体与以下物质接触：1）催化剂体系 包含一种或多种活化剂和一种或多种非金属茂金属中心的杂芳基配位体催化剂化合物，其中金属选自第4,5,6族，镧系元素或元素周期表的锕系元素，2 ）任选的一种或多种共聚单体，3）任选的稀释剂或溶剂，以及40任选溶剂，其中：a）烯烃单体和任何共聚单体在40重量％或更多的重量％存在于聚合体系中，b）具有三个或更多个的单体 基于进料中存在的所有单体和共聚单体的重量，碳原子存在于80重量％以上，c）聚合在高于聚合体系的固体 - 流体相转变温度的温度下进行， 肯定不低于聚合体系的浊点压力10MPa以下，并且小于1500MPa，在聚合体系的固体流体相转变温度不能确定的情况下，聚合在高于流体流体相的温度下发生 转变温度。

    Super-solution homogeneous propylene polymerization
    8.
    发明授权
    Super-solution homogeneous propylene polymerization 有权
    超溶液均相丙烯聚合

    公开(公告)号：US08058371B2

    公开(公告)日：2011-11-15

    申请号：US12098907

    申请日：2008-04-07

    申请人： Patrick Brant ,  Gary L. Casty ,  Gabor Kiss ,  Raymond A. Cook ,  James R. Lattner

    发明人： Patrick Brant ,  Gary L. Casty ,  Gabor Kiss ,  Raymond A. Cook ,  James R. Lattner

    IPC分类号： C08F4/6592 ,  C08F2/06 ,  C08F110/06 ,  C08F210/06

    CPC分类号： C08F10/06 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  C08L21/00 ,  C08F4/65908 ,  C08F2/06 ,  C08F2/14 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/20

    摘要： Processes for polymerizing propylene. About 40 wt % to about 80 wt % propylene monomer, based on total weight of propylene monomer and diluent, and about 20 wt % to about 60 wt % diluent, based on total weight of propylene monomer and diluent, can be fed into a reactor. The propylene monomer can be polymerized in the presence of a metallocene catalyst and an activator within the reactor at a temperature of about 80° C. or more and a pressure of about 13 MPa or more to produce a polymer product in a homogenous system. About 20 wt % to about 76 wt % (preferably About 28 wt % to about 76 wt %) propylene monomer, based on total weight of the propylene monomer, diluent, and polymer product, can be present at the reactor exit at steady state conditions.

    摘要翻译： 丙烯聚合方法 基于丙烯单体和稀释剂的总重量计，约40重量％至约80重量％的丙烯单体和约20重量％至约60重量％的稀释剂（基于丙烯单体和稀释剂的总重量）可以进料到反应器 。 丙烯单体可在茂金属催化剂和活化剂存在下在约80℃以上的温度和约13MPa或更高的压力下在反应器内聚合，以在均匀体系中生产聚合物产物。 基于丙烯单体，稀释剂和聚合物产物的总重量，约20重量％至约76重量％（优选约28重量％至约76重量％）的丙烯单体可以在稳态条件下在反应器出口处存在 。

    Linear alpha olefins from natural gas-derived synthesis gas over a nonshifting cobalt catalyst
    9.
    发明授权
    Linear alpha olefins from natural gas-derived synthesis gas over a nonshifting cobalt catalyst 有权
    来自天然气衍生合成气的线性α-烯烃在非脱钴钴催化剂上

    公开(公告)号：US06787576B2

    公开(公告)日：2004-09-07

    申请号：US10330860

    申请日：2002-12-27

    申请人： Gabor Kiss ,  Rocco Anthony Fiato ,  Frank Hershkowitz ,  David Chester Long

    发明人： Gabor Kiss ,  Rocco Anthony Fiato ,  Frank Hershkowitz ,  David Chester Long

    IPC分类号： C07C2700

    CPC分类号： C07C11/02 ,  C07C1/0435 ,  C07C1/046 ,  C07C1/0485 ,  C07C2523/75

    摘要： Linear alpha olefins having from four to twenty carbon atoms and low amounts of oxygenates are synthesized, by producing a synthesis gas containing H2 and CO from natural gas and passing it over a non-shifting cobalt catalyst at reaction conditions of temperature, % CO conversion, and gas feed H2:CO mole ratio land water vapor pressure, effective for the mathematical expression 200−0.6T+0.03PH2O−0.6XCO−8(H2:CO) to have a numerical value greater than or equal to 50. This process can be integrated into a conventional Fischer-Tropsch hydrocarbon synthesis process producing fuels and lubricant oils.

    摘要翻译： 通过在天然气中含有H 2和CO的合成气，并在温度，CO转化率的反应条件下将其转移到非转移钴催化剂上，合成具有4-20个碳原子和少量含氧化合物的直链α-烯烃， 和气体进料H2：CO摩尔比陆地水蒸汽压力，对于数学表达式200-0.6T + 0.03PH2O-0.6XCO-8（H2：CO）有效数值大于或等于50.该过程可以 被整合到生产燃料和润滑油的常规费 - 托烃合成方法中。

    Unsaturates recovery and recycle process
    10.
    发明授权
    Unsaturates recovery and recycle process 失效
    不饱和的回收和回收过程

    公开(公告)号：US5516965A

    公开(公告)日：1996-05-14

    申请号：US375432

    申请日：1995-01-18

    申请人： Frank Hershkowitz ,  Gabor Kiss

    发明人： Frank Hershkowitz ,  Gabor Kiss

    IPC分类号： C07C7/11 ,  C07C45/50 ,  C07C45/78 ,  C07C7/00

    CPC分类号： C07C45/783 ,  C07C45/50 ,  C07C7/11 ,  Y02P20/582

    摘要： The invention relates to a process for recovering unreacted unsaturated hydrocarbons from an effluent stream of a process for synthesizing oxygenated hydrocarbons from unsaturated hydrocarbons, said stream containing unreacted unsaturated hydrocarbons, oxygenated reaction products, and low-boiling gaseous components selected from the group including CO, H.sub.2, CO.sub.2, H.sub.2 O, C.sub.1 -C.sub.5 alkanes, nitrogen, helium, and argon by absorbing the unreacted unsaturated hydrocarbons and the oxygenated hydrocarbons of the synthesis process effluent stream in a solvent wherein said solvent is an unsaturates-depleted stream of the oxygenated product of said synthesis process, and stripping the unsaturated hydrocarbons from the solvent to produce a first stream concentrated in unsaturates and a second stream of oxygenated product depleted in unsaturates, wherein said unsaturates-depleted stream is the absorption solvent and the synthesis process product.

    摘要翻译： 本发明涉及从不饱和烃合成含氧烃的方法的流出物流中回收未反应的不饱和烃的方法，所述物流含有未反应的不饱和烃，含氧反应产物和选自CO， H 2，CO 2，H 2 O，C 1 -C 5烷烃，氮，氦和氩，通过在溶剂中吸收合成过程流出物流中的未反应的不饱和烃和氧化烃，其中所述溶剂是贫氧产物的不饱和物流 所述合成方法，以及从所述溶剂中除去不饱和烃以产生浓缩在不饱和化合物中的第一物流和贫化的不饱和化合物的第二氧化产物流，其中所述不饱和物流是吸收溶剂和合成过程产物。