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    Flow enhancer for petroleum middle distillates
    5.
    发明授权
    Flow enhancer for petroleum middle distillates 失效
    石油中间馏分的流动增强剂

    公开(公告)号：US06395852B1

    公开(公告)日：2002-05-28

    申请号：US09423116

    申请日：1999-11-02

    申请人： Dieter Faul ,  Bernd Wenderoth ,  Gabriele Dralle-Voss ,  Gunnar Schornick

    发明人： Dieter Faul ,  Bernd Wenderoth ,  Gabriele Dralle-Voss ,  Gunnar Schornick

    IPC分类号： C08F12400

    CPC分类号： C10L1/1966 ,  C08F222/00 ,  C08F224/00 ,  C10L1/146 ,  C10L1/1973 ,  C10L1/2364

    摘要： A copolymer of the monomers of the following components A to C and, if required, D, the total amount by weight of which is 100 mol %: a: from 20 to 80 mol % of at least one ethylenically unsaturated dicarboxylic acid or of an anhydride, ester and/or amide thereof as component A, b: from 1 to 79 mol % of at least one diketene of the general formula (I)  where R1 and R2 independently are each hydrogen or C1-C30-alkyl, as component B, c: from 1 to 79 mol % of at least one vinyl ester, alkyl (meth)acrylate, (meth)acrylonitrile or mixtures thereof as component C and d: from 0 to less than 0.5 mol % or, if at least 20 mol % of component C are present, from 0 to 20 mol % of at least one further olefinically unsaturated monomer as component D, is used as a flow improver in mineral oil middle distillates.

    摘要翻译： 以下组分A至C的单体和如果需要的话，其总重量为100摩尔％的共聚物：a：20至80摩尔％的至少一种烯键式不饱和二羧酸或 酸酐，酯和/或酰胺作为组分A，b：1至79mol％的至少一种通式（I）的二烯酮，其中R 1和R 2各自独立地为氢或C 1 -C 30 - 烷基，作为组分B ，c：1至79摩尔％的至少一种乙烯基酯，（甲基）丙烯酸烷基酯，（甲基）丙烯腈或其混合物作为组分C和d：0至小于0.5摩尔％，或如果至少20摩尔％ 的组分C，0至20摩尔％的至少一种作为组分D的烯属不饱和单体用作矿物油中间馏分中的流动改进剂。

    Reaction products of olefinically unsaturated carboxylic acids and polyetherols and their use as demulsifiers for crude oil emulsions
    8.
    发明授权
    Reaction products of olefinically unsaturated carboxylic acids and polyetherols and their use as demulsifiers for crude oil emulsions 失效

    公开(公告)号：US5661220A

    公开(公告)日：1997-08-26

    申请号：US592290

    申请日：1996-02-07

    申请人： Dieter Faul ,  Joachim Roser ,  Heinrich Hartmann ,  Hans-Henning Vogel ,  Wilhelmus Slotman ,  Gerd Konrad

    发明人： Dieter Faul ,  Joachim Roser ,  Heinrich Hartmann ,  Hans-Henning Vogel ,  Wilhelmus Slotman ,  Gerd Konrad

    IPC分类号： B01D17/04 ,  C08F220/26 ,  C08G63/676 ,  C08G65/332 ,  C09K8/36 ,  C10G33/04 ,  C08F8/00 ,  C08F8/14

    CPC分类号： B01D17/047 ,  C08F220/26 ,  C08G63/676 ,  C08G65/3322 ,  C09K8/36 ,  C10G33/04 ,  C08G2650/20 ,  C08L2312/00

    摘要： Reaction products which are suitable as demulsifiers for crude oil emulsions, comprise olefinically unsaturated carboxylic acids and polyetherols and are obtainable byA) condensation of one or more unsaturated C.sub.3 -C.sub.10 -carboxylic acids or their derivatives of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.4 -alkyl or carboxyl, R.sup.3 is hydrogen or methyl and R.sup.1 together with the carboxyl group may form a 5-membered or 6-membered anhydride ring, with a polyetherol of the general formula II ##STR2## where R.sup.4 is a radical of a monohydric or polyhydric alcohol or of a phenol or of an alkylphenol of 7 to 30 carbon atoms or a radical of an alkylphenol/formaldehyde or alkylphenol/acetaldehyde condensate, R.sup.5 is a branched or straight-chain C.sub.2 -C.sub.4 -alkylene group, where different units [R.sup.5 -O] may be present within a polyalkylene oxide chain, and X is an integer of from 5 to 120, in a molar ratio of compounds II to I of from 2:1 to 10:1 and in a weight ratio of from 25:1 to 1,000:1,B) polymerization of the resulting condensate with one or more unsaturated carboxylic acids I and, if required, further olefinically unsaturated monomers copolymerizable with the carboxylic acids I, the amount of the carboxylic acids I being from 50 to 100 mol %, based on the amount of the olefinically unsaturated monomers, and the molar ratio of the polyetherol II to the sum of the olefinically unsaturated monomers used in process steps A) and B) being from 1:5 to 1:200, and subsequentC) condensation of the resulting reaction mixture, with the proviso that not all hydroxyl groups are converted,and a process for their preparation, mixtures of the reaction products with organic solvents and the use of the reaction products and of the mixtures as demulsifiers for crude oil emulsions.

    Polymeric reaction products
    9.
    发明授权
    Polymeric reaction products 失效
    聚合反应产物

    公开(公告)号：US5336722A

    公开(公告)日：1994-08-09

    申请号：US979313

    申请日：1992-11-20

    申请人： Dieter Faul ,  Gerhard Hoffmann ,  Klaus Huemke ,  Ulrich Heimann ,  John A. Gilbert

    发明人： Dieter Faul ,  Gerhard Hoffmann ,  Klaus Huemke ,  Ulrich Heimann ,  John A. Gilbert

    IPC分类号： C08F8/00 ,  C08F36/00 ,  C08F36/04 ,  C08G59/14 ,  C08G81/02 ,  C08J3/24 ,  C08K5/14 ,  C08L63/00 ,  C08L71/02 ,  C09D5/02 ,  C09D5/44 ,  C09D163/00 ,  C08L63/10

    CPC分类号： C09D5/4492 ,  C08G81/025 ,  C08J3/246 ,  C08L63/00 ,  C08L71/02 ,  Y10T428/31529

    摘要： Polymeric reaction products are obtained by reactingI) prepolymers obtained fromA) polyoxyalkylenes which have an average molecular weight M.sub.n of from 140 to 10,000 and contain on average from 1.5 to 3.0a.sub.1) primary or secondary amino groups ora.sub.2) epoxy groups per molecule andB) polymers which are based on conjugated dienes, have an average molecular weight M.sub.n of from 250 to 50,000 and contain on average from 1.5 to 3.0b.sub.1) primary or secondary amino groups orb.sub.2) epoxy groups per molecule, the components (a.sub.1) and ( b.sub.2) or (a.sub.2) and (b.sub.1) being reacted with one another so that from at least an amino equivalent excess to 3 amino equivalents of component (a.sub.1) or (b.sub.1) are present per epoxide equivalent of component (a.sub.2) or (b.sub.2), withII) at least one compound which forms free radicals.

    摘要翻译： 聚合反应产物是通过使I）得自A）聚氧亚烷的平均分子量＆Upbar＆Mn为140〜10,000，平均含有1.5〜3.0个a1）伯或仲氨基或a2）环氧基的分子得到的预聚物 和B）基于共轭二烯的聚合物，其平均分子量＆gt;＆gt; Mn为250至50,000，并且平均含有1.5至3.0个b1）伯或仲氨基或每个分子的b2）环氧基，组分（a1 ）和（b2）或（a2）和（b1）彼此反应，使得由组分（a2）的每个环氧当量存在至少一个氨基当量过量至3个氨基当量的组分（a1）或（b1） 或（b2），II）至少一种形成自由基的化合物。