公开(公告)号：US09722252B2

公开(公告)日：2017-08-01

申请号：US14790299

申请日：2015-07-02

申请人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng ,  Mingyan Wu

发明人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng ,  Mingyan Wu

IPC分类号： H01B1/00 ,  C07D221/00 ,  H01M4/62 ,  H01B1/12 ,  B82Y30/00 ,  C08J5/00 ,  C08G61/02 ,  C08K3/08 ,  H01M4/134 ,  H01M4/38 ,  C08L65/00 ,  H01M10/0525

CPC分类号： H01M4/622 ,  B82Y30/00 ,  C07D221/00 ,  C08G61/02 ,  C08G2261/1414 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/312 ,  C08G2261/3142 ,  C08G2261/516 ,  C08J5/005 ,  C08J2365/00 ,  C08K3/08 ,  C08L65/00 ,  H01B1/128 ,  H01M4/134 ,  H01M4/386 ,  H01M10/0525 ,  Y02E60/122

摘要： A family of carboxylic acid groups containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. Triethyleneoxide side chains provide improved adhesion to materials such as, graphite, silicon, silicon alloy, tin, tin alloy. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

公开(公告)号：US08852461B2

公开(公告)日：2014-10-07

申请号：US13294885

申请日：2011-11-11

申请人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng

发明人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng

IPC分类号： H01B1/12 ,  H01M4/04 ,  H01M4/134 ,  C08K3/08 ,  B82Y30/00 ,  H01M10/0525 ,  C08G61/02 ,  H01M4/1395 ,  C08J5/00 ,  H01M4/62

CPC分类号： H01M4/624 ,  B82Y30/00 ,  C08G61/02 ,  C08G61/10 ,  C08G2261/12 ,  C08G2261/3142 ,  C08G2261/516 ,  C08J5/005 ,  C08J2365/00 ,  C08K3/08 ,  H01B1/121 ,  H01M4/0409 ,  H01M4/0416 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/386 ,  H01M4/622 ,  H01M10/0525 ,  Y02E60/122 ,  C08L65/00

摘要： A family of carboxylic acid group containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

摘要翻译： 在制造用于锂离子电池的负极中，公开了含有芴/芴酮共聚物的羧酸基团作为硅颗粒的粘合剂。 这些粘合剂使得能够使用硅作为电极材料，因为它们通过防止电极劣化随时间而显着地提高硅的循环性能。 特别地，这些在第一次充电时导电的聚合物与电极的硅颗粒结合是柔性的，以便在充电/放电期间更好地适应电极的膨胀和收缩，并且导电促进流动电池电流。

公开(公告)号：US20130253163A1

公开(公告)日：2013-09-26

申请号：US13615402

申请日：2012-09-13

申请人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng ,  Mingyan Wu

发明人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng ,  Mingyan Wu

IPC分类号： H01M4/62

CPC分类号： H01M4/622 ,  B82Y30/00 ,  C07D221/00 ,  C08G61/02 ,  C08G2261/1414 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/312 ,  C08G2261/3142 ,  C08G2261/516 ,  C08J5/005 ,  C08J2365/00 ,  C08K3/08 ,  C08L65/00 ,  H01B1/128 ,  H01M4/134 ,  H01M4/386 ,  H01M10/0525 ,  Y02E60/122

摘要： A family of carboxylic acid groups containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. Triethyleneoxide side chains provide improved adhesion to materials such as, graphite, silicon, silicon alloy, tin, tin alloy. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

公开(公告)号：US20120119155A1

公开(公告)日：2012-05-17

申请号：US13294885

申请日：2011-11-11

申请人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng

发明人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng

IPC分类号： H01B1/04 ,  C08G61/10 ,  B05D5/12 ,  B82Y30/00

CPC分类号： H01M4/624 ,  B82Y30/00 ,  C08G61/02 ,  C08G61/10 ,  C08G2261/12 ,  C08G2261/3142 ,  C08G2261/516 ,  C08J5/005 ,  C08J2365/00 ,  C08K3/08 ,  H01B1/121 ,  H01M4/0409 ,  H01M4/0416 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/386 ,  H01M4/622 ,  H01M10/0525 ,  Y02E60/122 ,  C08L65/00

摘要： A family of carboxylic acid group containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

摘要翻译： 在制造用于锂离子电池的负极中，公开了含有芴/芴酮共聚物的羧酸基团作为硅颗粒的粘合剂。 这些粘合剂使得能够使用硅作为电极材料，因为它们通过防止电极劣化随时间而显着地提高硅的循环性能。 特别地，这些在第一次充电时导电的聚合物与电极的硅颗粒结合是柔性的，以便在充电/放电期间更好地适应电极的膨胀和收缩，并且导电促进流动电池电流。

公开(公告)号：US09653734B2

公开(公告)日：2017-05-16

申请号：US14458977

申请日：2014-08-13

申请人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng

发明人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng

IPC分类号： H01B1/00 ,  H01M4/00 ,  H01M4/62 ,  H01B1/12 ,  B82Y30/00 ,  C08G61/02 ,  C08J5/00 ,  C08K3/08 ,  H01M4/134 ,  H01M4/1395 ,  H01M10/0525 ,  C08G61/10 ,  H01M4/04 ,  H01M4/38

CPC分类号： H01M4/624 ,  B82Y30/00 ,  C08G61/02 ,  C08G61/10 ,  C08G2261/12 ,  C08G2261/3142 ,  C08G2261/516 ,  C08J5/005 ,  C08J2365/00 ,  C08K3/08 ,  H01B1/121 ,  H01M4/0409 ,  H01M4/0416 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/386 ,  H01M4/622 ,  H01M10/0525 ,  Y02E60/122 ,  C08L65/00

摘要： A family of carboxylic acid group containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

公开(公告)号：US20150311529A1

公开(公告)日：2015-10-29

申请号：US14790299

申请日：2015-07-02

申请人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng ,  Mingyan Wu

发明人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng ,  Mingyan Wu

IPC分类号： H01M4/62

CPC分类号： H01M4/622 ,  B82Y30/00 ,  C07D221/00 ,  C08G61/02 ,  C08G2261/1414 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/312 ,  C08G2261/3142 ,  C08G2261/516 ,  C08J5/005 ,  C08J2365/00 ,  C08K3/08 ,  C08L65/00 ,  H01B1/128 ,  H01M4/134 ,  H01M4/386 ,  H01M10/0525 ,  Y02E60/122

摘要： A family of carboxylic acid groups containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. Triethyleneoxide side chains provide improved adhesion to materials such as, graphite, silicon, silicon alloy, tin, tin alloy. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

摘要翻译： 在制造用于锂离子电池的负极中，公开了含有芴/芴酮共聚物的一族羧酸基团作为硅颗粒的粘合剂。 三环氧乙烷侧链为石墨，硅，硅合金，锡，锡合金等材料提供了更好的粘合性。 这些粘合剂使得能够使用硅作为电极材料，因为它们通过防止电极劣化随时间而显着地提高硅的循环性能。 特别地，这些在第一次充电时导电的聚合物与电极的硅颗粒结合是柔性的，以便在充电/放电期间更好地适应电极的膨胀和收缩，并且导电促进流动电池电流。

公开(公告)号：US09077039B2

公开(公告)日：2015-07-07

申请号：US13615402

申请日：2012-09-13

申请人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng ,  Mingyan Wu

发明人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng ,  Mingyan Wu

IPC分类号： H01B1/00 ,  C07D221/00 ,  H01M4/62 ,  H01B1/12 ,  B82Y30/00 ,  C08J5/00 ,  C08G61/02 ,  C08K3/08 ,  H01M4/134 ,  H01M4/38 ,  C08L65/00 ,  H01M10/0525

CPC分类号： H01M4/622 ,  B82Y30/00 ,  C07D221/00 ,  C08G61/02 ,  C08G2261/1414 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/312 ,  C08G2261/3142 ,  C08G2261/516 ,  C08J5/005 ,  C08J2365/00 ,  C08K3/08 ,  C08L65/00 ,  H01B1/128 ,  H01M4/134 ,  H01M4/386 ,  H01M10/0525 ,  Y02E60/122

摘要： A family of carboxylic acid groups containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. Triethyleneoxide side chains provide improved adhesion to materials such as, graphite, silicon, silicon alloy, tin, tin alloy. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

公开(公告)号：US20150034881A1

公开(公告)日：2015-02-05

申请号：US14458977

申请日：2014-08-13

申请人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng

发明人： Gao Liu ,  Shidi Xun ,  Vincent S. Battaglia ,  Honghe Zheng

IPC分类号： H01M4/62 ,  H01M4/1395 ,  H01M4/04 ,  C08G61/10 ,  H01M4/38

CPC分类号： H01M4/624 ,  B82Y30/00 ,  C08G61/02 ,  C08G61/10 ,  C08G2261/12 ,  C08G2261/3142 ,  C08G2261/516 ,  C08J5/005 ,  C08J2365/00 ,  C08K3/08 ,  H01B1/121 ,  H01M4/0409 ,  H01M4/0416 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/386 ,  H01M4/622 ,  H01M10/0525 ,  Y02E60/122 ,  C08L65/00

摘要： A family of carboxylic acid group containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

摘要翻译： 在制造用于锂离子电池的负极中，公开了含有芴/芴酮共聚物的羧酸基团作为硅颗粒的粘合剂。 这些粘合剂使得能够使用硅作为电极材料，因为它们通过防止电极劣化随时间而显着地提高硅的循环性能。 特别地，这些在第一次充电时导电的聚合物与电极的硅颗粒结合是柔性的，以便在充电/放电期间更好地适应电极的膨胀和收缩，并且导电促进流动电池电流。

公开(公告)号：US20100167118A1

公开(公告)日：2010-07-01

申请号：US12614195

申请日：2009-11-06

申请人： Gao Liu ,  Vincent S. Battaglia ,  Honghe Zheng

发明人： Gao Liu ,  Vincent S. Battaglia ,  Honghe Zheng

IPC分类号： H01M2/00 ,  H01M4/58 ,  H01M4/04 ,  H01M10/04 ,  B05D5/12

CPC分类号： H01M10/0525 ,  H01M4/0404 ,  H01M4/0435 ,  H01M4/13 ,  H01M4/131 ,  H01M4/139 ,  H01M4/525 ,  H01M4/622 ,  H01M4/625 ,  Y02T10/7011 ,  Y10T29/49108

摘要： The present invention provides for a lithium ion battery and process for creating such, comprising higher binder to carbon conductor ratios than presently used in the industry. The battery is characterized by much lower interfacial resistances at the anode and cathode as a result of initially mixing a carbon conductor with a binder, then with the active material. Further improvements in cycleability can also be realized by first mixing the carbon conductor with the active material first and then adding the binder.

摘要翻译： 本发明提供一种锂离子电池及其制造方法，其包括比目前在工业上使用的更高的粘结剂与碳导体比。 电池的特征在于阳极和阴极具有低得多的界面电阻，这是由于首先将碳导体与粘合剂混合，然后与活性材料混合。 首先将碳导体与活性材料混合，然后添加粘合剂，也可以实现循环性的进一步改善。

公开(公告)号：US08703009B2

公开(公告)日：2014-04-22

申请号：US12614195

申请日：2009-11-06

申请人： Gao Liu ,  Vincent S. Battaglia ,  Honghe Zheng

发明人： Gao Liu ,  Vincent S. Battaglia ,  Honghe Zheng

IPC分类号： H01M4/88

CPC分类号： H01M10/0525 ,  H01M4/0404 ,  H01M4/0435 ,  H01M4/13 ,  H01M4/131 ,  H01M4/139 ,  H01M4/525 ,  H01M4/622 ,  H01M4/625 ,  Y02T10/7011 ,  Y10T29/49108

摘要： The present invention provides for a lithium ion battery and process for creating such, comprising higher binder to carbon conductor ratios than presently used in the industry. The battery is characterized by much lower interfacial resistances at the anode and cathode as a result of initially mixing a carbon conductor with a binder, then with the active material. Further improvements in cycleability can also be realized by first mixing the carbon conductor with the active material first and then adding the binder.

摘要翻译： 本发明提供一种锂离子电池及其制造方法，其包括比目前在工业上使用的更高的粘结剂与碳导体比。 电池的特征在于阳极和阴极具有低得多的界面电阻，这是由于首先将碳导体与粘合剂混合，然后与活性材料混合。 首先将碳导体与活性材料混合，然后添加粘合剂，也可以实现循环性的进一步改善。