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    WATER-AND-OIL REPELLANT COMPOSITION, FUNCTIONAL TEXTILE PRODUCT, AND PRODUCTION METHOD FOR FUNCTIONAL TEXTILE PRODUCT
    1.
    发明申请
    WATER-AND-OIL REPELLANT COMPOSITION, FUNCTIONAL TEXTILE PRODUCT, AND PRODUCTION METHOD FOR FUNCTIONAL TEXTILE PRODUCT 审中-公开
    水性油脂组合物，功能性纺织品，以及功能性纺织品的生产方法

    公开(公告)号：US20130165006A1

    公开(公告)日：2013-06-27

    申请号：US13812884

    申请日：2011-07-25

    申请人： Gou Yoshino ,  Norihiro Taniguchi ,  Hiromu Oda ,  Makoto Nishikawa ,  Takashi Enomoto ,  Masahiro Miyahara ,  Ikuo Yamamoto

    发明人： Gou Yoshino ,  Norihiro Taniguchi ,  Hiromu Oda ,  Makoto Nishikawa ,  Takashi Enomoto ,  Masahiro Miyahara ,  Ikuo Yamamoto

    IPC分类号： C09K3/18

    CPC分类号： D06M15/256 ,  C08G18/0823 ,  C08G18/283 ,  C08G18/285 ,  C08G18/286 ,  C08G18/3206 ,  C08G18/348 ,  C08G18/7831 ,  C08G18/792 ,  C08G18/8016 ,  C08G18/807 ,  C08G18/8077 ,  D06M13/395 ,  D06M15/277 ,  D06M15/564 ,  D06M15/576 ,  D06M2200/10 ,  D06M2200/11 ,  D06M2200/12 ,  F16D2200/0069 ,  Y10T442/2221

    摘要： The water-and-oil repellant composition of the invention including an aqueous dispersion of a pyrazole blocked hydrophobic polyisocyanate containing a pyrazole blocked hydrophobic polyisocyanate represented by the following formula (I) and a non-ionic surface active agent, and a water-and-oil repellant component having a perfluoroalkyl group with 6 carbon atoms or less is provided: R(—NH—CO—Z)m  (I) [in the formula (I), m represents an integer of 2 or more; R represents a residue after an “m” number of isocyanate groups have been removed from a polyisocyanate compound with an “m” number of isocyanate groups; Z represents a residue, which is the same or different from each other, after hydrogen atoms have been removed from active hydrogen-containing compounds that are capable of reacting with an isocyanate group, and at least two of the Z's are a pyrazole groups represented by the formula (II): {in the formula (II), n represents an integer of from 0 to 3; if n is 1 or higher, R1, which is the same or different from each other, represents an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, an N-substituted carbamyl group, a phenyl group, —NO2, a halogen atom, or —CO—O—R2 (in the formula, R2 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms)}].

    摘要翻译： 本发明的拒水拒油剂组合物包括含有由下式（I）表示的吡唑封闭的疏水性多异氰酸酯和非离子表面活性剂的吡唑封端的疏水性多异氰酸酯的水分散体和水 - 提供具有6个碳原子或更少碳原子的全氟烷基的斥油剂组分：R（-NH-CO-Z）m（I）[在式（I）中，m表示2或更大的整数; R表示从具有“m”个异氰酸酯基的多异氰酸酯化合物除去“m”个异氰酸酯基之后的残基; Z表示在与能够与异氰酸酯基反应的活性含氢化合物除去氢原子之后，彼此相同或不同的残基，Z中的至少两个为由 式（II）：{式（II）中，n表示0〜3的整数， 如果n为1以上，则相同或不同的R1表示碳原子数1〜6的烷基，碳原子数2〜6的烯基，碳原子数7〜12的芳烷基， N-取代氨基甲酰基，苯基，-NO 2，卤素原子或-CO-O-R 2（式中，R 2为氢原子或碳原子数1〜6的烷基）}。

    Fluorine-containing copolymer, paper processing agent, and coating film-forming agent for cosmetic preparation
    6.
    发明授权
    Fluorine-containing copolymer, paper processing agent, and coating film-forming agent for cosmetic preparation 有权
    含氟共聚物，纸张加工剂和化妆品制备用涂膜成膜剂

    公开(公告)号：US08568886B2

    公开(公告)日：2013-10-29

    申请号：US12935554

    申请日：2009-03-27

    申请人： Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

    发明人： Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

    IPC分类号： B32B27/10

    CPC分类号： D21H17/20 ,  A61K8/8152 ,  A61Q3/02 ,  A61Q5/06 ,  A61Q19/00 ,  B29C33/62 ,  C08F220/24 ,  C08F222/1006 ,  C09D133/16 ,  D21H19/20 ,  Y10T428/3154 ,  C08F220/26

    摘要： Disclosed is a fluorine-containing copolymer having sufficient stability in water, which is capable of providing paper with sufficient oil resistance. The fluorine-containing polymer contains, as essential components, (a) a fluorine-containing monomer represented by general formula (I) CH2═C(—X)—C(═O)—Y—[—(CH2)m—Z—]p—(CH2)n—Rf (wherein X represents a hydrogen atom; Y represents —O— or —NH—; Z represents a direct bond, —S— or —SO2—; Rf represents a fluoroalkyl group having 1-6 carbon atoms; m is a number of 1-10; n is a number of 0-10; and p is 0 or 1) and (b) an alkoxy group-containing monomer represented by general formula (II) CH2═C(X′)—C(═O)—O—(RO)q—H (wherein X′ represents a hydrogen atom or a methyl group; R represents an alkylene group having 2-4 carbon atoms wherein a part or all of hydrogen atoms may be substituted by a hydroxyl group; and q represent an integer of 1-50). The fluorine-containing polymer does not contain a monomer having an amino group.

    摘要翻译： 公开了一种在水中具有足够稳定性的含氟共聚物，其能够为纸提供足够的耐油性。 含氟聚合物含有（a）由通式（I）表示的含氟单体CH 2 = C（-X）-C（= O）-Y - [ - （CH 2）m Z-） 对 - （CH 2）n -R f（其中X表示氢原子; Y表示-O-或-NH-; Z表示直接键，-S-或-SO 2 - ; Rf表示具有1-6个碳原子的氟代烷基 原子; m是1-10的数; n是0-10的数; p是0或1）和（b）由通式（II）表示的含烷氧基的单体CH 2 = C（X' ）-C（= O）-O-（RO）qH（其中X'表示氢原子或甲基; R表示具有2-4个碳原子的亚烷基，其中部分或全部氢原子可以被 羟基; q表示1-50的整数）。 含氟聚合物不含有具有氨基的单体。

    Water-and-oil repellent treatment of textile
    7.
    发明授权
    Water-and-oil repellent treatment of textile 有权
    防水和拒油处理纺织品

    公开(公告)号：US07758656B2

    公开(公告)日：2010-07-20

    申请号：US10258067

    申请日：2001-04-16

    申请人： Takashi Enomoto ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda ,  Kayo Kusumi

    发明人： Takashi Enomoto ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda ,  Kayo Kusumi

    IPC分类号： D06M15/00 ,  B05D7/00

    CPC分类号： D06M13/184 ,  D06M15/277 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T442/2164 ,  Y10T442/2189 ,  Y10T442/2197

    摘要： A textile having excellent water- and oil-repellency can be obtained by a method of preparing a treated textile, having steps of: (1) preparing a treatment liquid comprising a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, preferably at most 3, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent is at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains an organic salt.

    摘要翻译： 通过制备处理过的纺织品的方法可以获得具有优异的拒水拒油性的织物，其具有以下步骤：（1）制备包含拒水拒油剂的处理液，（2）调节 （3）将处理液施加到纺织品上，（4）用蒸汽处理织物，和（5）用水洗涤织物并使织物脱水，其中， 防油剂为选自含氟聚合物和含氟低分子化合物中的至少一种含氟化合物，防水防油剂或处理液含有有机物 盐。

    FLUORINE-CONTAINING COPOLYMER, PAPER PROCESSING AGENT, AND COATING FILM-FORMING AGENT FOR COSMETIC PREPARATION
    8.
    发明申请
    FLUORINE-CONTAINING COPOLYMER, PAPER PROCESSING AGENT, AND COATING FILM-FORMING AGENT FOR COSMETIC PREPARATION 有权
    含氟聚合物，纸张加工剂和涂料成膜剂用于化妆品制备

    公开(公告)号：US20110027593A1

    公开(公告)日：2011-02-03

    申请号：US12935554

    申请日：2009-03-27

    申请人： Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

    发明人： Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

    IPC分类号： B32B27/10 ,  C08F220/22 ,  C08L27/12

    CPC分类号： D21H17/20 ,  A61K8/8152 ,  A61Q3/02 ,  A61Q5/06 ,  A61Q19/00 ,  B29C33/62 ,  C08F220/24 ,  C08F222/1006 ,  C09D133/16 ,  D21H19/20 ,  Y10T428/3154 ,  C08F220/26

    摘要： Disclosed is a fluorine-containing copolymer having sufficient stability in water, which is capable of providing paper with sufficient oil resistance. The fluorine-containing polymer contains, as essential components, (a) a fluorine-containing monomer represented by general formula (I) CH2═C(—X)—C(═O)—Y—[—(CH2)m—Z—]p—(CH2)n—Rf (wherein X represents a hydrogen atom; Y represents —O— or —NH—; Z represents a direct bond, —S— or —SO2—; Rf represents a fluoroalkyl group having 1-6 carbon atoms; m is a number of 1-10; n is a number of 0-10; and p is 0 or 1) and (b) an alkoxy group-containing monomer represented by general formula (II) CH2═C(X′)—C(═O)—O—(RO)q—H (wherein X′ represents a hydrogen atom or a methyl group; R represents an alkylene group having 2-4 carbon atoms wherein a part or all of hydrogen atoms may be substituted by a hydroxyl group; and q represent an integer of 1-50). The fluorine-containing polymer does not contain a monomer having an amino group.

    摘要翻译： 公开了一种在水中具有足够稳定性的含氟共聚物，其能够为纸提供足够的耐油性。 含氟聚合物含有作为必要成分的（a）由通式（I）表示的含氟单体CH 2 = C（-X）-C（= O）-Y - [ - （CH 2）m-Z - ]对 - （CH 2）n -R f（其中X表示氢原子; Y表示-O-或-NH-; Z表示直接键，-S-或-SO 2 - ; Rf表示具有1- 6个碳原子; m是1-10的数; n是0-10的数; p是0或1）和（b）由通式（II）表示的含烷氧基的单体CH 2 = C（ X'）-C（= O）-O-（RO）q-H（其中X'表示氢原子或甲基; R表示具有2-4个碳原子的亚烷基，其中部分或全部氢原子 可以被羟基取代; q表示1-50的整数）。 含氟聚合物不含有具有氨基的单体。

    Water- and oil-repellent treatment of textile
    9.
    发明授权
    Water- and oil-repellent treatment of textile 有权
    防水和拒油处理纺织品

    公开(公告)号：US06939580B2

    公开(公告)日：2005-09-06

    申请号：US10239994

    申请日：2001-03-29

    申请人： Takashi Enomoto ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda

    发明人： Takashi Enomoto ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda

    IPC分类号： A47G27/02 ,  C03C25/26 ,  C09K3/18 ,  D06M13/236 ,  D06M13/428 ,  D06M15/277 ,  D06M15/576 ,  B05D3/02 ,  B05D3/04 ,  B05D3/10

    CPC分类号： C03C25/26 ,  D06M13/236 ,  D06M13/428 ,  D06M15/277 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12

    摘要： A textile having durability of maintaining water- and sufficient oil-repellency and soil releasability before and after cleaning can be obtained by a method of preparing a treated textile, having steps of: (1) preparing a treatment liquid containing a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, preferably at most 3, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent is an emulsion containing a fluorine-containing compound and an emulsifier, the fluorine-containing compound is a fluorine-containing polymer and/or a fluorine-containing low molecular weight compound, and the emulsifier contains an anionic surface active agent having pKa of at least 2.

    摘要翻译： 可以通过制备经处理的织物的方法获得在清洁之前和之后保持水和足够的防油性和污垢释放性的耐久性的织物，其具有以下步骤：（1）制备含有水和油 - （2）将处理液的pH调节至7以下，优选为3以下，（3）将处理液施加到织物上，（4）用蒸汽处理织物，（5）用纺织品洗涤 水和脱水剂，其中拒水拒油剂是含有含氟化合物和乳化剂的乳液，含氟化合物是含氟聚合物和/或含氟低分子化合物 ，乳化剂含有pKa为2以上的阴离子表面活性剂。

    Superwide-angle lens system
    10.
    发明授权
    Superwide-angle lens system 有权
    超广角镜头系统

    公开(公告)号：US08659841B2

    公开(公告)日：2014-02-25

    申请号：US13570389

    申请日：2012-08-09

    申请人： Takashi Enomoto

    发明人： Takashi Enomoto

    IPC分类号： G02B13/04 ,  G02B9/10

    CPC分类号： G02B13/06

    摘要： A superwide-angle lens system includes a negative first lens group, an aperture diaphragm, and a positive second lens group. The first lens group includes two negative meniscus lens elements, and a positive lens element. The second lens group includes a cemented lens having negative and positive lens elements; and a positive lens element. The following conditions (1) and (2) are satisfied: −1.45

    摘要翻译： 超广角镜头系统包括负第一透镜组，孔径光阑和正第二透镜组。 第一透镜组包括两个负弯月透镜元件和正透镜元件。 第二透镜组包括具有负透镜和正透镜元件的胶合透镜; 和正透镜元件。 满足以下条件（1）和（2）：-1.45