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公开(公告)号:US4622335A
公开(公告)日:1986-11-11
申请号:US645464
申请日:1984-09-11
IPC分类号: C07D249/08 , A01N43/50 , A01N43/56 , A01N43/653 , C07C45/43 , C07C45/51 , C07C45/63 , C07C49/255 , C07D20060101 , C07D233/60 , C07D233/61 , C07D521/00
CPC分类号: C07D231/12 , A01N43/50 , A01N43/653 , C07C45/43 , C07C45/515 , C07C45/63 , C07C49/255 , C07D233/56 , C07D249/08
摘要: Fungicidally active novel hydroxyethylazolyl-oxime derivatives of the formula ##STR1## in which Ar is optionally substituted aryl,R.sup.1 is hydrogen or alkyl,R.sup.2 is hydrogen, alkyl, alkenyl, alkinyl, optionally substituted aralkyl or optionally substituted cycloalkylalkyl, andX is a nitrogen atom or the CH group,and addition products thereof with acids and metal salts.
摘要翻译: 其中Ar为任选取代的芳基,R 1为氢或烷基,R 2为氢,烷基,链烯基,炔基,任选取代的芳烷基或任选取代的环烷基烷基,X为氮原子的杀真菌活性的新型羟乙唑基肟衍生物 原子或CH基团,以及其与酸和金属盐的加成产物。
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公开(公告)号:US4645767A
公开(公告)日:1987-02-24
申请号:US650965
申请日:1984-09-14
IPC分类号: A01N43/50 , A01N43/653 , C07D233/60 , C07D233/61 , C07D249/08 , C07D317/26 , C07D407/06 , C07D521/00
CPC分类号: C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08 , C07D317/26 , C07D407/06
摘要: Hydroxyethyl-azole derivatives of the formula ##STR1## in which R.sup.1 represents alkyl or the grouping Ar--Y--,Ar represents optionally substituted aryl,X represents a nitrogen atom or the CH group,Y represents a direct bond or the grouping --CH.sub.2 --, --CH.sub.2 CH.sub.2 --, --OCH.sub.2 --, --SCH.sub.2 --, --CH.dbd.CH-- or --C.tbd.C--,Z represents oxygen or the NOR.sup.2 group andR.sup.2 represents hydrogen, alkyl, alkenyl, alkinyl, optionally substituted aralkyl or optionally substituted cycloalkylalkyl,or addition products thereof with acids or metal salts, which possess fungicidal activity.
摘要翻译: 其中R 1表示烷基或Ar-Y-,Ar表示任选取代的芳基,X表示氮原子或CH基团,Y表示直接键或-CH 2 - ,-CH 2 CH 2 - , - OCH 2 - , - CH 2 - , - CH = CH-或-CB 3 -C-,Z表示氧或NOR 2基团,R 2表示氢,烷基,烯基,炔基,任选取代的芳烷基或任选取代的环烷基烷基 或其与酸或金属盐的加成产物,其具有杀真菌活性。
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3.
公开(公告)号:US4898875A
公开(公告)日:1990-02-06
申请号:US91557
申请日:1987-08-31
申请人: Karl H. Buchel , Graham Holmwood , Udo Kraatz , Wolfgang Kramer , Paul Reinecke , Wilhelm Brandes , Wilhelm Stendel
发明人: Karl H. Buchel , Graham Holmwood , Udo Kraatz , Wolfgang Kramer , Paul Reinecke , Wilhelm Brandes , Wilhelm Stendel
IPC分类号: A01N43/653 , C07D249/08 , C07D521/00
CPC分类号: C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要: Novel mercapto-substituted hydroxyethyl-(triazol-l-yl) derivatives of the formula ##STR1## in which Ar represents optionally substituted aryl,X represents oxygen, sulphur, a direct bond or the groupings --CH.sub.2 --, --CH.sub.2 --CH.sub.2 --, --O--CH.sub.2 --, --SCH.sub.2 --, --O--CH.sub.2 --CH.sub.2 --, and --S--CH.sub.2 --CH.sub.2 --, the hetero atom being bonded to the aryl radical if X represents --OCH.sub.2 --, --SCH.sub.2 --, --O--CH.sub.2 --CH.sub.2 -- or --S--CH.sub.2 --CH.sub.2 -- andR represents hydrogen, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl or optionally substituted phenyl, and their acid addition salts and metal salt complexes are very effective as fungicides and parasiticides. Novel oxiranes of the formula ##STR2## in which Ar and X have the above-mentioned meaning, and their use as intermediates for the synthesis of the mercapto-substituted hydroxyethyl-(triazol-l-yl) derivatives.
摘要翻译: 式(I)的新型巯基取代的羟乙基 - (三唑-1-基)衍生物,其中Ar表示任选取代的芳基,X表示氧,硫,直接键或-CH 2 - , - CH2-,-O-CH2-,-SCH2-,-O-CH2-CH2-和-S-CH2-CH2-,如果X表示-OCH2-,-SCH2-,则杂原子键合到芳基上, -O-CH 2 -CH 2 - 或-S-CH 2 -CH 2 - ,R表示氢,任选取代的烷基,任选取代的烯基,任选取代的炔基,任选取代的环烷基,任选取代的环烷基烷基,任选取代的芳烷基或任选取代的苯基, 酸加成盐和金属盐络合物作为杀真菌剂和杀寄生物剂是非常有效的。 其中Ar和X具有上述含义的式“IMAGE”的新型环氧乙烷及其作为合成巯基取代的羟乙基 - (三唑-1-基)衍生物的中间体的用途。
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公开(公告)号:US4960781A
公开(公告)日:1990-10-02
申请号:US481780
申请日:1990-02-16
申请人: Graham Holmwood , Wolfgang Kramer , Erik Regel , Hans L. Elbe , Karl H. Buchel , Stefan Dutzmann , Wilhelm Brandes , Paul Reinecke
发明人: Graham Holmwood , Wolfgang Kramer , Erik Regel , Hans L. Elbe , Karl H. Buchel , Stefan Dutzmann , Wilhelm Brandes , Paul Reinecke
IPC分类号: A01N43/653 , C07D231/12 , C07D231/16 , C07D249/08 , C07D249/10 , C07D403/06 , C07D405/06 , C07D521/00
CPC分类号: C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要: Fungicidal bisazolyl-hydroxyalkyl derivatives of the formula ##STR1## in which Ar stands for optionally substituted aryl,X stands for a grouping --CH.sub.2 CH.sub.2 --, --OCH.sub.2 --, --SCH.sub.2 -- or --SH.dbd.CH--,Y stands for a nitrogen atom or the grouping CR.sup.3,R.sup.1, R.sup.2 and R.sup.3 stand for hydrogen, halogen or methyl, andn stands for the numbers 0, 1 or 2,and acid addition salts and metal salt complexes thereof. Intermediates of the formulas ##STR2## are also new.
摘要翻译: 式(I)的杀真菌双唑基 - 羟烷基衍生物,其中Ar代表任选取代的芳基,X代表基团-CH 2 CH 2 - , - OCH 2 - , - CH 2 - 或-SH = CH-,Y代表 氮原子或分组CR 3,R 1,R 2和R 3代表氢,卤素或甲基,n代表数字0,1或2及其酸加成盐和金属盐络合物。 (IMAG)(II)
(IV) (VI)的中间体也是新的。 -
公开(公告)号:US4843088A
公开(公告)日:1989-06-27
申请号:US868402
申请日:1986-05-29
IPC分类号: A01N43/50 , A01N43/653 , C07D233/60 , C07D233/61 , C07D249/08 , C07D317/26 , C07D407/06 , C07D521/00
CPC分类号: C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08 , C07D317/26 , C07D407/06
摘要: Hydroxyethyl-azole derivatives of the formula ##STR1## in which R.sup.1 represents alkyl or the grouping Ar--Y--,Ar represents optionally substituted aryl,X represents a nitrogen atom or the CH group,Y represents a direct bond or the grouping --CH.sub.2 --, --CH.sub.2 CH.sub.2 --, --OCH.sub.2 --, --SCH.sub.2 --, --CH.dbd.CH-- or --C.tbd.C--,Z represents oxygen or the NOR.sup.2 group andR.sup.2 represents hydrogen, alkyl, alkenyl, alkynyl, optionally substituted aralkyl or optionally substituted cycloalkylalkyl,or addition products thereof with acids or metal salts, which possess fungicidal activity.
摘要翻译: 其中R 1表示烷基或Ar-Y-,Ar表示任选取代的芳基,X表示氮原子或CH基团,Y表示直接键或-CH 2 - ,-CH 2 CH 2 - , - OCH 2 - , - CH 2 - , - CH = CH-或-CB 3 -C-,Z表示氧或NOR 2基团,R 2表示氢,烷基,烯基,炔基,任选取代的芳烷基或任选取代的环烷基烷基 或其与酸或金属盐的加成产物,其具有杀真菌活性。
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6.
公开(公告)号:US4639462A
公开(公告)日:1987-01-27
申请号:US547807
申请日:1983-11-01
申请人: Wolfgang Kramer , Karl H. Buchel , Graham Holmwood , Erik Regel , Paul Reinecke , Wilhelm Brandes
发明人: Wolfgang Kramer , Karl H. Buchel , Graham Holmwood , Erik Regel , Paul Reinecke , Wilhelm Brandes
IPC分类号: A01N43/50 , A01N43/653 , C07C45/56 , C07C49/185 , C07D249/08 , C07D317/26 , C07D319/06 , C07D405/06 , C07D405/14 , C07D407/04 , C07D407/06 , C07D521/00 , C07D233/60
CPC分类号: C07D231/12 , A01N43/50 , A01N43/653 , C07C45/56 , C07C49/185 , C07D233/56 , C07D249/08 , C07D317/26 , C07D319/06 , C07D407/04 , C07D407/06
摘要: Heterocyclyl-hydroxyalkyl-azolyl derivatives of the formula ##STR1## in which Az represents 1,2,4-triazol-1-yl, 1,2,4-triazol-4-yl or imidazol-1-yl,Het represents optionally substituted dioxolanyl or 1,3-dioxanyl,R represents alkyl, optionally substituted phenyl, optionally substituted phenylalkyl, optionally substituted phenoxyalky, optionally substituted phenylthioalkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, alkenyl, optionally substituted phenylalkenyl, optionally substituted cyclohexylalkenyl, furyl, naphthyloxymethyl or azolylalkyl,R' represents hydrogen, optionally substituted alkyl or alkenyl andn represents the number 0 or 1,or addition products thereof with acids or metal salts, which possess fungicidal activity.
摘要翻译: 其中Az表示1,2,4-三唑-1-基,1,2,4-三唑-4-基或咪唑-1-基的式(I)的杂环基 - 羟基烷基 - 唑基衍生物,Het 任选取代的苯氧基烷基,任选取代的苯硫基烷基,任选取代的环烷基,任选取代的环烷基烷基,烯基,任选取代的苯基烯基,任选取代的环己基烯基,呋喃基 ,萘氧基甲基或唑基烷基,R'表示氢,任选取代的烷基或链烯基,n表示0或1,或其与具有杀真菌活性的酸或金属盐的加成产物。
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7.
公开(公告)号:US4918093A
公开(公告)日:1990-04-17
申请号:US218718
申请日:1988-07-13
IPC分类号: A01N43/653 , C07D249/08 , C07D303/36 , C07D521/00
CPC分类号: C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08 , C07D303/36
摘要: Hydroxyethyl-azolyl oxime ethers of the formula ##STR1## in which R represents hydrogen, alkyl with 1 to 6 carbon atoms or alkenyl with 2 to 6 carbon atoms andR.sup.1 represents the radicals of the formula ##STR2## wherein R.sup.2 represents hydrogen, fluorine or chlorine,R.sup.3 represents hydrogen, fluorine or chlorine andX represents oxygen, sulphur or a CH.sub.2 group,and acid addition salts and metal salt complexes thereof. Such hydroxyethyl-azolyl oxime ethers are useful as fungicides.
摘要翻译: 其中R表示氢,具有1至6个碳原子的烷基或具有2至6个碳原子的烯基的式(I)的羟乙基 - 唑基肟醚,R 1表示下式的基团:其中 R 2表示氢,氟或氯,R 3表示氢,氟或氯,X表示氧,硫或CH 2基,以及其酸加成盐和金属盐络合物。 这种羟乙基 - 唑基肟醚可用作杀真菌剂。
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8.
公开(公告)号:US4878939A
公开(公告)日:1989-11-07
申请号:US258108
申请日:1988-10-13
申请人: Gerhard Jager , Manfred Jautelat , Wolfgang Kramer , Karl H. Buchel , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler , Klaus Lurssen
发明人: Gerhard Jager , Manfred Jautelat , Wolfgang Kramer , Karl H. Buchel , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler , Klaus Lurssen
IPC分类号: C07C43/225 , A01N43/50 , A01N43/653 , C07C41/00 , C07C45/00 , C07C49/167 , C07C49/175 , C07C67/00 , C07D233/60 , C07D249/08 , C07D521/00
CPC分类号: C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要: Azolyl ether ketones and alcohols of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently represents alkyl with more than one carbon atom, orR.sup.1 represents dichloromethyl, trichloromethyl, chlorovinyl or dichlorovinyl, andR.sup.2 represents alkyl,R.sup.3 represents alkyl,A represents the keto group or a CH(OH) grouping,Z represents a nitrogen atom or the CH group,X represents oxygen or sulphur andAr represents optionally substituted phenyl,or addition products thereof with acids and metal salts, are active against fungi and in regulating the growth of plants. New intermediates therefor are also shown.
摘要翻译: 其中R 1和R 2各自独立地表示具有多于一个碳原子的烷基,或者R 1表示二氯甲基,三氯甲基,氯乙烯基或二氯乙烯基,并且R 2表示烷基,R 3表示烷基, 酮基或CH(OH)基,Z表示氮原子或CH基,X表示氧或硫,Ar表示任选取代的苯基,或其与酸和金属盐的加成产物对真菌有活性, 植物生长。 还显示了其新的中间体。
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公开(公告)号:US4740515A
公开(公告)日:1988-04-26
申请号:US632138
申请日:1984-07-18
IPC分类号: A01N43/653 , C07C17/14 , C07D249/08 , C07D521/00
CPC分类号: C07D231/12 , A01N43/653 , C07C17/14 , C07D233/56 , C07D249/08
摘要: 3-(1,2,4-Triazol-1-yl)-prop-1-enes of the general formula (I) ##STR1## in which X.sup.1 and X.sup.2 independently of one another represent hydrogen or methyl,R.sup.1 represents alkyl, alkenyl, in each case optionally substituted cycloalkyl or cycloalkenyl or in each case optionally substituted phenyl or benzyl andR.sup.2 represents alkyl, alkenyl, in each case optionally substituted cycloalkyl or cycloalkenyl, halogenoalkyl, in each case optionally substituted phenyl or phenylalkyl, phenoxyalkyl or phenylthioalkyl, in each case optionally substituted in the phenyl part,but whereinR.sup.1 and R.sup.2 may not simultaneously represent optionally substituted phenyl if X.sup.1 and/or X.sup.2 represent hydrogen,and acid addition salts and metal salt complexes thereof which are tolerated by plants, exhibit fungicidal activity.
摘要翻译: 其中X 1和X 2彼此独立地表示氢或甲基的通式(I)的(I)的3-(1,2,4-三唑-1-基) - 丙-1-烯,R 1表示 烷基,烯基,在每种情况下均为任选取代的环烷基或环烯基,或在每种情况下为任选取代的苯基或苄基,并且R 2表示烷基,烯基,在每种情况下为任选取代的环烷基或环烯基,卤代烷基,在每种情况下为任选取代的苯基或苯基烷基,苯氧基烷基或 苯硫基烷基,在每种情况下都可以在苯基部分被取代,但如果X1和/或X2代表氢,其中R1和R2不能同时代表任选取代的苯基,并且其被植物耐受的酸加成盐和金属盐络合物显示为杀真菌剂 活动。
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10.
公开(公告)号:US4917720A
公开(公告)日:1990-04-17
申请号:US256808
申请日:1988-10-12
申请人: Gerhard Jager , Manfred Jautelat , Wolfgang Kramer , Karl H. Buchel , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler , Klaus Lurssen
发明人: Gerhard Jager , Manfred Jautelat , Wolfgang Kramer , Karl H. Buchel , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler , Klaus Lurssen
IPC分类号: C07C43/225 , A01N43/50 , A01N43/653 , C07C41/00 , C07C45/00 , C07C49/167 , C07C49/175 , C07C67/00 , C07D233/60 , C07D249/08 , C07D521/00
CPC分类号: C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要: Azolyl ether ketones and alcohols of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently represents alkyl with more than one carbon atom, orR.sup.1 represents dichloromethyl, trichloromethyl, chlorovinyl or dichlorovinyl, andR.sup.2 represents alkyl,R.sup.3 represents alkyl,A represents the keto group or a CH(OH) grouping,Z represents a nitrogen atom or the CH group,X represents oxygen or sulfur andAr represents optionally substituted phenyl,or addition products thereof with acids and metal salts, are active against fungi and in regulating the growth of plants. New intermediates therefor are also shown.
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