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公开(公告)号:US08044013B2
公开(公告)日:2011-10-25
申请号:US12288382
申请日:2008-10-20
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josée Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler-Richter , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josée Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler-Richter , Brigitte Schmidt , Albert Schneider , Peter Weingartner
CPC分类号: B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要: The present invention relates to the use of metal complex compounds with terpyridine ligands as oxidation catalysts. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds, and to novel ligands. The metal complex compounds are used especially tor improving the action of peroxides, for example in the treatment of textile material, without at the same time causing any appreciable damage to fibres and dyeings.
摘要翻译: 本发明涉及金属络合物与三联吡啶配体作为氧化催化剂的用途。 本发明还涉及包含这种金属络合物的制剂,新颖的金属络合物和新配体。 金属络合物特别用于改善过氧化物的作用,例如在纺织材料的处理中,而不会同时对纤维和染色造成任何明显的损害。
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公开(公告)号:US07692004B2
公开(公告)日:2010-04-06
申请号:US12214491
申请日:2008-06-19
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
CPC分类号: B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要: Use of metal complex compounds of formula [LnMemXp]zYq (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
摘要翻译: 使用式[LnMemXp] zYq(1)的金属络合物,其中Me是锰,钛,铁,钴,镍或铜,X是配位或桥连基团,n和m各自独立地为具有 值为1〜8,p为0〜32的整数,z为金属络合物的电荷,Y为抗衡离子,q = z /(电荷Y),L为 其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8,R 9,R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基 -COOR 12或-SO 3 R 12,其中R 12在各种情况下为氢,阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13,-SO 2 R 13或-OR 13,其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N(R 13)-NR'13R“13其中R 13,R 13和R 13如对R 13所定义; -NR14R15或-N⊕R14R15R16,其中R14,R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基,或者R14和R15与其键合的氮原子一起形成未取代或取代的5 可以任选地含有其它杂原子的6-或7-元环; 条件是R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8,R 9,R 10和R 11不同时为氢,作为氧化反应的催化剂,并且式(1)和新颖的新型金属络合物 式(2)的配体。
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公开(公告)号:US07456285B2
公开(公告)日:2008-11-25
申请号:US11497444
申请日:2006-08-01
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
IPC分类号: C07F15/00
CPC分类号: B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要: Use of metal complex compounds of formula [LnMemXp]zYq, (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11, are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
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公开(公告)号:US07161005B2
公开(公告)日:2007-01-09
申请号:US10476043
申请日:2002-04-25
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
IPC分类号: C07F15/00
CPC分类号: B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要: Use of metal complex compounds of formula [LnMemXp]zYq (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1–C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1–C18alkyl or aryl; —SR13, —OR13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1–C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1–C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
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公开(公告)号:US07612010B2
公开(公告)日:2009-11-03
申请号:US11901660
申请日:2007-09-18
申请人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josée Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
发明人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josée Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
CPC分类号: C07D401/14 , C11D3/168 , C11D3/3932
摘要: Use of metal complex compounds of formula (1) and/or (1′) [LnMemXp]zYq (1), [L′nMemXp]zYq (1′), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.
摘要翻译: 使用式(1)和/或(1')[LnMemXp] zYq(1),[L'nMemXp] zYq(1')的金属配合物化合物,其中所有取代基如权利要求中所定义,作为氧化催化剂 反应,还有新型金属络合物和新配体。
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公开(公告)号:US07494964B2
公开(公告)日:2009-02-24
申请号:US10520841
申请日:2003-07-03
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Uwe Heinz , Markus Frey , Albert Schneider
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Uwe Heinz , Markus Frey , Albert Schneider
CPC分类号: C11D3/168 , C07D213/68 , C07D213/74 , C11D3/3932
摘要: The present invention relates to the use of metal complex compounds which have terpyridine ligands and contain at least one quaternized nitrogen atom as oxidation catalysts. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds and to novel ligands.
摘要翻译: 本发明涉及具有三联吡啶配位体并含有至少一个季铵化氮原子的金属络合物作为氧化催化剂的用途。 本发明还涉及包含这种金属络合物的制剂,新颖的金属络合物和新配体。
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公开(公告)号:US07291584B2
公开(公告)日:2007-11-06
申请号:US11520398
申请日:2006-09-13
申请人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josée Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
发明人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josée Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
CPC分类号: C07D401/14 , C11D3/168 , C11D3/3932
摘要: Use of metal complex compounds of formula (1) and/or (1′) [LnMemXp]zYq, (1) [L′nMemXp]zYq, (1′) wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.
摘要翻译: 使用式(1)和/或(1')的金属络合物化合物<?in-line-formula description =“In-line Formulas”end =“lead”?> [L> n (1)<?在线公式描述=“In” -line公式“end =”tail“?> <?in-line-formula description =”In-line Formulas“end =”lead“?> [L' i> (1')<?in-line-formula description =“在线公式” 其中所有取代基如权利要求中所定义,作为用于氧化反应的催化剂,以及新型金属络合物和新型配体。
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公开(公告)号:US07138363B2
公开(公告)日:2006-11-21
申请号:US10531906
申请日:2003-10-21
申请人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josée Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
发明人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josée Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
CPC分类号: C07D401/14 , C11D3/168 , C11D3/3932
摘要: Use of metal complex compounds of formula (1) and/or (1′) [LnMemXp]zYq (1), [L′MemXp]zYq (1′), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.
摘要翻译: 使用式(1)和/或(1')[LnMemXp] zYq(1),[L'MemXp] zYq(1')的金属配合物化合物,其中所有取代基如权利要求中所定义,作为氧化催化剂 反应,还有新型金属络合物和新配体。
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公开(公告)号:US06689733B1
公开(公告)日:2004-02-10
申请号:US09914911
申请日:2001-09-05
申请人: Frank Bachmann , Rachel Allemann , Josef Dannacher , Marie-Josée Dubs , Cornelia Makowka , Grit Richter , Gunther Schlingloff , Peter Weingartner , Menno Hazenkamp
发明人: Frank Bachmann , Rachel Allemann , Josef Dannacher , Marie-Josée Dubs , Cornelia Makowka , Grit Richter , Gunther Schlingloff , Peter Weingartner , Menno Hazenkamp
IPC分类号: C11D320
CPC分类号: C07F13/005 , C07C251/24 , C07C2601/14 , C11D3/168 , C11D3/3932
摘要: The present invention relates to novel manganese complexes of salen ligands and the use thereof as catalysts that enhance the action of peroxy compounds in washing, cleaning, and disinfecting processes.
摘要翻译: 本发明涉及新型的salen配体的锰络合物及其作为催化剂的用途,其可增强洗涤,清洗和消毒过程中过氧化合物的作用。
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公开(公告)号:US06387863B1
公开(公告)日:2002-05-14
申请号:US09914865
申请日:2001-09-04
申请人: Menno Hazenkamp , Frank Bachmann , Cornelia Makowka , Marie-Josée Dubs , Grit Richter , Gunther Schlingloff , Josef Dannacher , Peter Weingartner
发明人: Menno Hazenkamp , Frank Bachmann , Cornelia Makowka , Marie-Josée Dubs , Grit Richter , Gunther Schlingloff , Josef Dannacher , Peter Weingartner
IPC分类号: C11D732
CPC分类号: C11D3/0021 , C11D3/168 , C11D3/3932 , C11D3/3947
摘要: The inventions is drawn to mixtures of manganese complexes and organic ligands which significantly improve the bleaching effect of hydrogen peroxide in washing liquours and prevent the reabsorption of migrating dyes in peroxide-containing washing liquors.
摘要翻译: 本发明涉及锰络合物和有机配体的混合物,其显着改善过氧化氢在洗涤液中的漂白效果,并防止迁移染料在含过氧化物的洗涤液中的再吸收。
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