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    Use of metal complex compounds as oxidation catalysts
    1.
    发明授权
    Use of metal complex compounds as oxidation catalysts 失效
    使用金属络合物作为氧化催化剂

    公开(公告)号：US07692004B2

    公开(公告)日：2010-04-06

    申请号：US12214491

    申请日：2008-06-19

    申请人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josée Dubs ,  Menno Hazenkamp ,  Grit Hänsler (-Richter) ,  Brigitte Schmidt ,  Albert Schneider ,  Peter Weingartner

    发明人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josée Dubs ,  Menno Hazenkamp ,  Grit Hänsler (-Richter) ,  Brigitte Schmidt ,  Albert Schneider ,  Peter Weingartner

    IPC分类号： C07F15/00 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06

    CPC分类号： B01J31/1815 ,  B01J23/34 ,  B01J2231/70 ,  B01J2231/72 ,  B01J2531/16 ,  B01J2531/46 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07D213/61 ,  C07D213/68 ,  C07D213/74 ,  C07F13/005 ,  C11D3/3932 ,  D06L4/10 ,  D06L4/12 ,  D06P5/02 ,  D06P5/153 ,  D21C9/1036 ,  D21C9/163

    摘要： Use of metal complex compounds of formula [LnMemXp]zYq  (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).

    摘要翻译： 使用式[LnMemXp] zYq（1）的金属络合物，其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥连基团，n和m各自独立地为具有 值为1〜8，p为0〜32的整数，z为金属络合物的电荷，Y为抗衡离子，q = z /（电荷Y），L为 其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基 -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R 13）-NR'13R“13其中R 13，R 13和R 13如对R 13所定义; -NR14R15或-N⊕R14R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与其键合的氮原子一起形成未取代或取代的5 可以任选地含有其它杂原子的6-或7-元环; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11不同时为氢，作为氧化反应的催化剂，并且式（1）和新颖的新型金属络合物 式（2）的配体。