Use of metal complex compounds as oxidation catalysts

    公开(公告)号:US20060100123A1

    公开(公告)日:2006-05-11

    申请号:US10520841

    申请日:2003-07-03

    IPC分类号: C11D3/00

    摘要: Use of metal complex compounds of formula (1) [LnMcmXp]zYq wherein Mc is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen: unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl: —SR13, —SO12R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —NR14R15; —(C1-C6alkylene)-NR14R15; —NoR14R15R16; —(C1-C6alkylene)-NoR14R15R16; —N(R)15)—(C1-C6alkylene)-NR1R15; —N[(C1-C6alkylene)-NR14R15]2; —N(R13)—(C1-C6alkylene)-NoR14R15R16, —N[C1-C6alkylene)-NoR14R15R16]2; —N(R13)—N—R14R15 or —N(R13)—NoR14R15R16: wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heterotatoms; with the proviso that (i) at least one of the substituents R1—R11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I′ nor Cl′ in the case that Me is Mn(II), R1—R5 and R7—R11 are hydrogen and R6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.

    METAL FREE BLEACHING COMPOSITION
    3.
    发明申请
    METAL FREE BLEACHING COMPOSITION 有权
    无金属漂白组合物

    公开(公告)号:US20130117941A1

    公开(公告)日:2013-05-16

    申请号:US13703385

    申请日:2011-06-21

    IPC分类号: D06L3/02

    摘要: The present invention relates to the use of a composition comprising specific a-amino-ketones, H2O2, a H2O2 precursor or a peracid and optionally an activator as a bleaching mixture for textile materials or dishes either manually or in an automatic washing machine or dish washer. Further aspects of the invention are the composition comprising specific a-aminoketones and H2O2, a H2O2 precursor or a peracid and a process for bleaching of stains or of soiling on textile materials or dishes in the context of a washing process either manually or in an automatic washing machine or dish washer. Also aspects of the invention are detergent formulations comprising such a composition and novel compounds.

    摘要翻译: 本发明涉及包含特定的α-氨基酮,H 2 O 2,H 2 O 2前体或过酸和任选的活化剂的组合物作为纺织材料或盘子的漂白混合物的手段或者在自动洗衣机或洗碗机中的用途 。 本发明的其它方面是包含特定的α-氨基酮和H 2 O 2,H 2 O 2前体或过酸的组合物,以及在洗涤过程中手动或自动地漂洗污渍或污染纺织品材料或菜肴的方法 洗衣机或洗碗机。 本发明的另外方面是包含这种组合物和新化合物的洗涤剂制剂。

    SILSESQUIOXANE PHOTOINITIATORS
    6.
    发明申请
    SILSESQUIOXANE PHOTOINITIATORS 有权
    SILSESQUIOXANE照相机

    公开(公告)号:US20120142793A1

    公开(公告)日:2012-06-07

    申请号:US13130796

    申请日:2009-11-24

    CPC分类号: C07F7/21 B33Y70/00

    摘要: Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1′) wherein n is 2m; m is an integer of 2 to 30; the sum of n′+a is an integer 4-60; n′ is an even-numbered integer; a is an even- or uneven-numbered integer; and for example different A C1-C12alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C1-C3alkylene, preferably propylene; R1 and R2 for example are a photoactive moiety Q, or C2-20alkyl; Q is for example a group of formula (4); Z2 is for example C1-C6alkylene which is unsubstituted or substituted by one or more OR6; and R6, R12, R13 and R14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.

    摘要翻译: 光引发剂化合物,其包含与多面体低聚倍半硅氧烷结合的光活性部分和胺官能团,该光引发剂由式(1)或(1')表示,其中n为2m; m为2〜30的整数, n'+ a的和为4-60的整数; n'是偶数整数; a是偶数或不均匀的整数; 例如不同的A C1-C12烷基或光活性部分Q1或式(2)的基团; E例如是直接键合,L是直链或支链C1-C3亚烷基,优选丙烯; R1和R2例如是光活性部分Q或C2-20烷基; Q例如是式(4)的一组; Z2为例如未被取代或被一个或多个OR 6取代的C 1 -C 6亚烷基; R 6,R 12,R 13和R 14例如为氢; 特别适用于低迁移性光引发剂。

    Process for the synthesis of amine ethers
    8.
    发明申请
    Process for the synthesis of amine ethers 审中-公开
    胺醚合成方法

    公开(公告)号:US20070191516A1

    公开(公告)日:2007-08-16

    申请号:US10591778

    申请日:2005-03-07

    CPC分类号: C07C239/20 C07D211/94

    摘要: A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C5-C18alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.

    摘要翻译: 一种制备空间位阻胺醚的方法,其包括使相应的空间位阻氨基氧化物与C 5 -C 18烷-1-烯的存在下反应, 有机氢过氧化物,并任选地氢化所得产物以及由其获得的产物混合物及其作为稳定剂和阻燃剂的用途。