Carbonate polymer resins containing low volatility aromatic phosphate
ester compounds
    2.
    发明授权
    Carbonate polymer resins containing low volatility aromatic phosphate ester compounds 失效
    含低挥发性芳族磷酸酯化合物的碳酸酯聚合物树脂

    公开(公告)号:US5663280A

    公开(公告)日:1997-09-02

    申请号:US636291

    申请日:1996-04-23

    CPC分类号: C08K5/43 C08K5/523

    摘要: Disclosed is a carbonate polymer composition comprising (a) a carbonate polymer having a weight average molecular weight of from about 20,000 to about 40,000 and (b) from greater than about 0.1 to less than about 1.0 weight percent (based on carbonate polymer composition weight) low volatility aromatic phosphate ester compound, and optionally (c) from about 0.001 to about 0.1 weight percent (based on carbonate polymer compositions weight) of an alkali metal salt having a pH of at least about 7. Preferably the low volatility aromatic phosphate ester is selected from the group of aromatic phosphate ester oligomer compounds or haloaryl phosphate compounds. It has been found to be preferable to use a low volatility aromatic phosphate ester which experiences a weight loss of no more than 5 weight percent at 250.degree. C. when heated to a temperature of 500.degree. C. in a thermogravimetric analysis (TGA) at a heating rate of 20.degree. C. per minute, more preferably no more than 40 percent at 300.degree. C. It has been found that these compositions surprisingly achieve the Underwriters Laboratory (UL-94) V-2 rating without significantly sacrificing the otherwise good combinations of properties of carbonate polymer resins.

    摘要翻译: 公开了一种碳酸酯聚合物组合物,其包含(a)重均分子量为约20,000至约40,000的碳酸酯聚合物和(b)大于约0.1至小于约1.0重量%(基于碳酸酯聚合物组合物重量) 低挥发性芳族磷酸酯化合物,以及任选地(c)约0.001至约0.1重量%(基于碳酸酯聚合物组合物重量)的pH为至少约7的碱金属盐。优选地,低挥发性芳族磷酸酯是 选自芳族磷酸酯低聚物化合物或卤代芳基磷酸酯化合物。 已经发现,优选使用低挥发性芳族磷酸酯,当在热重分析(TGA)中加热到500℃时,在250℃下经历重量损失不超过5重量% 加热速度为每分钟20℃,更优选在300℃下更优选不超过40%。已经发现,这些组合物令人惊讶地实现了保险商实验室(UL-94)V-2等级,而没有显着牺牲其他良好 碳酸酯聚合物树脂的性能组合。

    Ignition resistant carbonate polymer with improved processing stability
    3.
    发明授权
    Ignition resistant carbonate polymer with improved processing stability 失效
    具有改善加工稳定性的耐点燃碳酸酯聚合物

    公开(公告)号:US4727101A

    公开(公告)日:1988-02-23

    申请号:US878928

    申请日:1986-06-26

    IPC分类号: C08K5/43 C08K5/47

    CPC分类号: C08K5/43

    摘要: A carbonate polymer composition comprising a carbonate polymer such as a bisphenol-A homopolycarbonate which carbonate polymer contains an amount of a salt represented by the formula: ##STR1## wherein Ar is an aromatic group, R is a monovalent organic moiety, or Ar and R collectively are a divalent aromatic moiety M is a cation, and n is a number corresponding to the valence of M and an amount of a free aromatic sulfimide, which carbonate polymer composition resists combustion upon exposure to an ignition source, exhibits good optical properties, and exhibits molecular weight stability. Optionally, a halogenated organic compound may be added to the composition.

    摘要翻译: 一种碳酸酯聚合物组合物,其包含碳酸酯聚合物如双酚-A均聚碳酸酯,该碳酸酯聚合物含有一定量的由下式表示的盐:其中Ar是芳族基团,R是一价有机部分,或Ar和R 总是二价芳族部分M是阳离子,n是对应于M的化合价的数量和一定量的游离芳香族硫酰亚胺,该碳酸酯聚合物组合物在暴露于点燃源时可以抵抗燃烧,表现出良好的光学性能, 表现出分子量稳定性。 任选地,可以向组合物中加入卤代有机化合物。

    Dispersing ignition resistant additives into carbonate polymers
    6.
    发明授权
    Dispersing ignition resistant additives into carbonate polymers 失效
    将耐燃添加剂分散在碳酸酯聚合物中

    公开(公告)号:US5041479A

    公开(公告)日:1991-08-20

    申请号:US398036

    申请日:1989-08-24

    申请人: Samuel A. Ogoe

    发明人: Samuel A. Ogoe

    摘要: A process for dispersing one or more powdered ignition resistant or flame retardant additives into carbonate polymers which comprises the steps of preparing a base concentrate having about 5 to about 50 weight per cent of said additives by blending said additives with a carbonate polymer having a melt flow rate from about 3 to about 20, pelletizing said base concentrate having said ignition resistant additive dispersed therein, dry blending said concentrate pellets with carbonate pellets having a melt flow rate from about 1 to about 80 whereby said polymer/concentrate blend has an amount of said additive dispersed therein effective to render said blend ignition resistant, and pelletizing or molding said carbonate polymer/concentrate blend. The use of this method gives ignition resistant carbonate polymers with improved impact properties as measured by Izod impact tests.

    Ignition resistant carbonate polymer blends
    9.
    发明授权
    Ignition resistant carbonate polymer blends 失效
    耐点燃碳酸酯聚合物共混物

    公开(公告)号:US5276077A

    公开(公告)日:1994-01-04

    申请号:US893188

    申请日:1992-06-03

    摘要: According to the present invention there are obtained improved ignition resistant carbonate polymer blends having unexpectedly better combinations of toughness, ignition resistance, processability and stability. In particular the blend comprises a major amount of carbonate polymer, a minor amount of a rubber-modified monovinylidene aromatic copolymer, and an optional rubbery core/shell graft copolymer impact modifier. As ignition resistance additives the blends contain a metal salt of an aromatic sulfur compound, a buffering aromatic sulfur compound, an organophosphorus compound, and a tetrafluoroethylene polymer.

    摘要翻译: 根据本发明,获得了改进的耐点燃碳酸酯聚合物共混物,其具有出乎意料的更好的韧性,耐点火性,加工性和稳定性的组合。 特别地,共混物包含主要量的碳酸酯聚合物,少量的橡胶改性的单亚乙烯基芳族共聚物和任选的橡胶核/壳接枝共聚物抗冲改性剂。 作为耐火添加剂,共混物含有芳族硫化合物的金属盐,缓冲芳香族硫化合物,有机磷化合物和四氟乙烯聚合物。

    Fire retardant impact modified carbonate polymer composition
    10.
    发明授权
    Fire retardant impact modified carbonate polymer composition 失效
    阻燃冲击改性碳酸酯聚合物组成

    公开(公告)号:US4837258A

    公开(公告)日:1989-06-06

    申请号:US228203

    申请日:1988-08-04

    IPC分类号: C08L69/00

    CPC分类号: C08L69/00 C08L69/005

    摘要: A flame retardant, impact resistant carbonate polymer composition comprising a mixture of one or more carbonate polymers, an impact modifying quantity of a rubbery polymer containing residual ethylenic unsaturation, a fluorine containing polymer of the fibril forming type flame retarding quantities of an aromatic sulfur containing compound and a chlorine or bromine substituted organic compound, and, optionally a melt stability enhancing quantity of an organoposphorus compound.

    摘要翻译: 包含一种或多种碳酸酯聚合物的混合物的阻燃抗冲击碳酸酯聚合物组合物,含有残余烯属不饱和度的橡胶状聚合物的抗冲击改性量,含芳香族含硫化合物的原纤维形成型阻燃剂的含氟聚合物 和氯或溴取代的有机化合物,以及任选的熔体稳定性增强量的有机磷化合物。