4-jod-2[N-(N-alkyl-aminocarbonyl)-aminosulfonyl]-benzoic acid methyl
ester and derivatived thereof and method for their production
    4.
    发明授权
    4-jod-2[N-(N-alkyl-aminocarbonyl)-aminosulfonyl]-benzoic acid methyl ester and derivatived thereof and method for their production 有权
    4-氨基-2- [N-(N-烷基 - 氨基羰基) - 氨基磺酰基] - 苯甲酸甲酯并衍生并制备

    公开(公告)号:US6147248A

    公开(公告)日:2000-11-14

    申请号:US214041

    申请日:1998-12-23

    CPC分类号: C07C311/58 C07C311/37

    摘要: The invention relates to compounds of the formula (I) ##STR1## in which R=(subst.) alkyl or (subst.) cycloalkyl, which are suitable as intermediates for preparing herbicidal sulfonylureas. According to the invention, the compounds (I) are prepared by(a) diazotizing a compound of the formula (II) ##STR2## in the presence of an acid H.sup.+ X.sup.-, where X.sup.- is an equivalent of an anion, to give the novel compounds (diazonium salts) of the formula (III) ##STR3## (b) reacting the compound of the formula (III) in the presence of iodide ions to give the compound (IV) and ##STR4## (c) reacting the compound of the formula (IV) with an isocyanate of the formula (V)R--N.dbd.C.dbd.O (V)in which R is as defined in formula (I), to give the compound of the formula (I).

    摘要翻译: PCT No.PCT / EP97 / 03170 Sec。 371日期1998年12月23日第 102(e)1998年12月23日日期PCT 1997年6月18日PCT公布。 公开号WO98 / 00396 日本1998年1月8日本发明涉及式(I)化合物,其中R =(低级)烷基或(低级)环烷基,其适用作制备除草磺酰脲类的中间体。 根据本发明,化合物(I)通过(a)在酸H + X-存在下重氮化式(II)的化合物来制备,其中X-是阴离子当量,得到新颖的 式(III)化合物(重氮盐)(b)在碘离子存在下使式(Ⅲ)化合物反应,得到化合物(Ⅳ)和(ⅲ)使式(Ⅳ)化合物与式 式(Ⅴ)的异氰酸酯RN = C = O(Ⅴ)其中R如式(Ⅰ)所定义,得到式(Ⅰ)化合物。

    Safeners based on acrylic-aliphatic carboxylic acid derivatives
    8.
    发明授权
    Safeners based on acrylic-aliphatic carboxylic acid derivatives 失效
    基于丙烯酸 - 脂族羧酸衍生物的安全剂

    公开(公告)号:US07838463B2

    公开(公告)日:2010-11-23

    申请号:US10911669

    申请日:2004-08-04

    IPC分类号: A01N25/32 A01N37/36 A01N47/40

    摘要: Compounds of the formula (I) or salts thereof, which R1 is COOH or a derivative thereof, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(X′R′)(X″R″)—Y—R, in which R is H, a (subst.) hydrocarbon radical, a heterocyclic radical or acyl, Y is a direct bond or O, S, NRc or NRc—NRdRe, n is the integer 1, 2, 3, 4, 5 or 6 and R′, R″, X, X′, X″, Ra, Rb, Rc, Rd, Re, R2, R3 (R4)m are as defined in claim 1 are suitable as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides such as herbicides in these plants, where compounds of the formula (I) or salts thereof in which R1 is COOH, R2, R3 are each hydrogen, (R4)m is a hydroxyl radical (m=1) in any position or two radicals R4 (m=2) in any position, where in the latter case one radical is a hydroxyl group and the other radical is hydroxyl or methoxy, and n is the number 1, are used as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals other than glyphosate.

    摘要翻译: 式(I)化合物或其盐,其中R 1为COOH或其衍生物,优选式-CN,-C(= X)-Y-R或-C(X'R')(X “R”)-Y-R,其中R为H,(基)烃基,杂环基或酰基,Y为直接键或O,S,NRc或NRc-NRdRe,n为整数1 ,2,3,4,5或6,R',R“,X,X',X”,Ra,Rb,Rc,Rd,Re,R2,R3(R4)m如权利要求1中所定义, 作为防治农药的植物毒性作用的安全剂,优选作为防止农药如这些植物中除草剂作用的安全剂,其中R1为COOH,R2,R3的式(Ⅰ)化合物或其盐为 每个氢,(R4)m是在任何位置的任何位置或两个基团R 4(m = 2)的羟基(m = 1),其中在后一种情况下一个基团是羟基,另一个基团是羟基或 甲氧基,n为数1,用作作物作物或用途的安全剂 l植物除草甘膦以外的农药的植物毒性作用。