摘要:
A process for the gas-phase trimerization of formaldehyde to give trioxane using solid phosphoric acid catalysts. Particularly suitable catalysts for this process are SPA catalysts (solid phosphorous acid), for example “silicon phosphates”. The main advantage of this catalyst system is its simple and inexpensive production and ready availability and also, in particular, its improved long-term stability compared to the few previously described catalysts which are mostly based on supported heteropolyacids.
摘要:
A process for preparing a bicyclooctanone, in particular 1,5-dialkylbicyclo[3.2.1]octan-8-one, by reacting a bicyclooctanol, in particular dialkylbicyclo[3.2.1]octan-8-ol, with a. a catalyst applied to an active-carbon support and comprising heteropolyoxometallate anions of vanadium, molybdenum and phosphorus, and also a corresponding alkali-metal, alkaline-earth-metal and/or ammonium counter ion, and b. a gaseous, oxygen-containing oxidizing agent.
摘要:
The invention relates to a process for the preparation of an amine by single-stage reaction of a C.sub.2 -C.sub.20 -olefin with a compound having an NH.sub.3 group, hydrogen and carbon monoxide, wherein the reaction takes place in the presence of a catalyst, which is present in water in dissolved or suspended form, and the catalyst contains at least two metals from group VIII of the Periodic Table of the Elements in elemental or bonded form.