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    Method for producing mixtures of monoolefinic C5-mononitriles by catalytic hydrocyanation
    4.
    发明授权
    Method for producing mixtures of monoolefinic C5-mononitriles by catalytic hydrocyanation 失效
    通过催化氢化法生产单烯烃C5-单腈混合物的方法

    公开(公告)号：US06169198A

    公开(公告)日：2001-01-02

    申请号：US09463820

    申请日：2000-02-01

    申请人： Jakob Fischer ,  Wolfgang Siegel

    发明人： Jakob Fischer ,  Wolfgang Siegel

    IPC分类号： C07C25310

    CPC分类号： C07C253/10 ,  C07C255/04 ,  C07C255/07

    摘要： A process for preparing mixtures of monoolefinic C5 mononitriles with nonconjugated C═C and C≡N bonds by catalytic hydrocyanation of 1,3-butadiene or a 1,3-butadiene-containing hydrocarbon mixture, wherein the hydrocyanation takes place in the presence of a catalyst which comprises at least one metallocene-phosphorus(III)-nickel(0) complex which comprises at least one monodentate or bidentate metallocene-phosphorus(III) ligand of the formula I or salts and mixtures thereof.

    摘要翻译： 通过1,3-丁二烯或含1,3-丁二烯的烃混合物的催化氢化制备单烯烃C5单腈与非共轭C = C和C = N键的混合物的方法，其中氢氰化在 催化剂，其包含至少一种茂金属 - 磷（III） - 镍（0）络合物，其包含至少一种式I或其盐及其混合物的单齿或二齿茂金属 - 磷（III）配体。

    Phosphites
    6.
    发明授权
    Phosphites 有权

    公开(公告)号：US06770770B1

    公开(公告)日：2004-08-03

    申请号：US10111477

    申请日：2002-04-25

    申请人： Robert Baumann ,  Jakob Fischer ,  Tim Jungkamp ,  Dagmar Pascale Kunsmann-Keitel ,  Wolfgang Siegel

    发明人： Robert Baumann ,  Jakob Fischer ,  Tim Jungkamp ,  Dagmar Pascale Kunsmann-Keitel ,  Wolfgang Siegel

    IPC分类号： C07F9145

    CPC分类号： C07C253/30 ,  B01J31/185 ,  B01J2231/323 ,  B01J2231/52 ,  B01J2531/847 ,  C07C253/10 ,  C07F9/145 ,  C07C255/04 ,  C07C255/07 ,  C07C255/19

    摘要： Novel phosphites have the formula I P(O—R1)x(O—R2)y(O—R3)z(O—R4)p  I where R1: aromatic radical having a C1-C18-alkyl substituent in the o position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, or having an aromatic substituent in the o position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, or having an aromatic system fused on in the o position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, R2: aromatic radical having a C1-C18-alkyl substituent in the m position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, or having an aromatic substituent in the m position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, or having an aromatic system fused on in the m position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, where the aromatic radical bears a hydrogen atom in the o position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, R3: aromatic radical having a C1-C18-alkyl substituent in the p position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, or having an aromatic substituent in the p position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, where the aromatic radical bears a hydrogen atom in the o position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, R4: aromatic radical which bears substituents other than those defined for R1, R2 and R3 in the o, m and p positions relative to the oxygen atom which connects the phosphorus atom to the aromatic system, where the aromatic radical bears a hydrogen atom in the o position relative to the oxygen atom which connects the phosphorus atom to the aromatic system, x: 1 or 2, y, z, p: independently of one another, 0, 1 or 2, with the proviso that x+y+z+p=3.