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1.发明申请NOVEL ORGANOMETALLIC COMPLEXES WHICH EMIT IN THE RED TO GREEN SPECTRAL REGION AND THEIR USE IN OLEDS 有权红色到绿色光谱区域的新型有机复合物及其在OLEDs中的使用公开(公告)号：US20100127215A1
公开(公告)日：2010-05-27
申请号：US12594429
申请日：2008-04-04
IPC分类号： C09K11/06 , C07F17/00 , C07D211/04 , C07D249/08 , C07D261/06 , C07D231/12
CPC分类号： C07D277/66 , C07D231/12 , C07D249/08 , C07D261/08 , C07F15/0033 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1059 , C09K2211/185 , H01L51/0085 , H01L51/5016
摘要： Organometallic complexes which bear at least one ligand which has a unit having a triplet energy of at least 22 000 cm−1, a process for preparing the organometallic complexes, a mixture comprising at least one inventive organometallic complex, the use of the organometallic complexes or of the mixture in organic light-emitting diodes, the organometallic complexes preferably being used as emitter materials, and specific nitrogen- or phosphorus-substituted triphenylene derivatives and a process for their preparation.
摘要翻译： 具有至少一个具有至少22000cm -1的三线态能量的单元的配体的有机金属络合物，制备有机金属配合物的方法，包含至少一种本发明的有机金属络合物的混合物，使用有机金属络合物或 的有机发光二极管中的混合物，有机金属配合物优选用作发射体材料，特定的氮或磷取代的三亚苯衍生物及其制备方法。
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公开(公告)号：US20100109515A1
公开(公告)日：2010-05-06
申请号：US12593363
申请日：2008-04-04
IPC分类号： H01J1/62
CPC分类号： H01L51/0085 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/5016 , H05B33/14
摘要： The present invention is directed to the field of organic light emitting diode (OLED) electroluminescent devices comprising a light-emitting layer containing an organic metal coordination compound with tailored ligands of the general structure (1) where (2) is a N-containing heterocycle comprising one or more cycle and where (3) is a unit with a triplet energy of at least 22,220 cm−1.
摘要翻译： 本发明涉及有机发光二极管（OLED）电致发光器件的领域，其包括含有一般结构（1）的定制配体的有机金属配位化合物的发光层，其中（2）是含N杂环 包括一个或多个循环，其中（3）是具有至少22,220cm -1的三重态能量的单元。
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3.发明授权Organometallic complexes which emit in the red to green spectral region and their use in OLEDs 有权在红色到绿色光谱区域发射的有机金属配合物及其在OLED中的应用公开(公告)号：US08455112B2
公开(公告)日：2013-06-04
申请号：US12594429
申请日：2008-04-04
CPC分类号： C07D277/66 , C07D231/12 , C07D249/08 , C07D261/08 , C07F15/0033 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1059 , C09K2211/185 , H01L51/0085 , H01L51/5016
摘要： Organometallic complexes which bear at least one ligand which has a unit having a triplet energy of at least 22 000 cm−1, a process for preparing the organometallic complexes, a mixture comprising at least one of these organometallic complexes, the use of the organometallic complexes or of the mixture in organic light-emitting diodes, the organometallic complexes preferably being used as emitter materials, and specific nitrogen- or phosphorus-substituted triphenylene derivatives and a process for their preparation, the organometallic complex including a monoanionic bidentate ligand of formula (IIa)
摘要翻译： 具有至少一个具有至少22000cm -1的三线态能量的单元的配体的有机金属络合物，制备有机金属络合物的方法，包含这些有机金属络合物中的至少一种的混合物，使用有机金属络合物 或有机发光二极管中的混合物，有机金属络合物优选用作发射体材料，以及特定的氮或磷取代的三亚苯衍生物及其制备方法，所述有机金属络合物包括式（IIa）的单阴离子二齿配体 ）
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公开(公告)号：US20080203028A1
公开(公告)日：2008-08-28
申请号：US11816638
申请日：2006-02-14
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5012 , H05B33/14
摘要： An iridium complex Ir(III)L 1L2L3 for emitting light with a central iridium ion Ir(III), with a ligand L3 as dionate from the group comprising pentane-2,4-dionate (acac), 2,2,6,6-tetramethyl-3,5-heptandionate (thd), 7,7-dimethyl-1,1,1,2,2,3,3-heptyfluoro-4,6-octandionate (fod), 4,4,4-trifluorol-(2-thienyl)butane-1,3-dionate (ttfa), 1,3-diphenylpropane-1,3-dionate (dbm), 4,4,4-trifluoro-1-(2-naphthyl)butane-1,3-dionate (tfnb) or 4,4,4-trifluoro-1-(1-naphthyl)butane-1,3-dionate and with two rigid aromatic ligands L1 and L2 with one nitrogen and one carbon atom, sharing in the ligand bond, preferably dibenzo[f,h]chinoline, benzo[h]chinoline or 5,6-dihydro-benzo[h]chinoline, characterized in that the iridium complex Ir(III)L1L2L3 is a first isomer (71), in which the nitrogen atom of the ligand L1 sharing in the ligand bonding and the nitrogen atom of the ligand L2 sharing in the ligand bonding are juxtaposed relative to the central iridium ion. The invention further relates to a method for the separation of the first isomer (71,81) of the iridium complexes (7,8) and an electroluminescent device with an electroluminescent layer (4) comprising light-emitting materials, wherein the component of the first isomer (71,81) in the total quantity of the light-emitting materials is greater than 90%, preferably greater than 95%.
摘要翻译： 铱配合物Ir（III）L 1 L 2 L 3，用于发射具有中心铱离子Ir（III）的光，其中配体L 3作为二烷基化物，由包含戊烷-2,4-二酸盐（acac），2， 2,6,6-四甲基-3,5-庚酸酯（thd），7,7-二甲基-1,1,1,2,2,3,3-全氟-4,6-辛二酸（fod），4， （2-噻吩基）丁烷-1,3-二酮（ttfa），1,3-二苯基丙烷-1,3-二酮（dbm），4,4,4-三氟-1-（2- 萘基）丁烷-1,3-二酮（tfnb）或4,4,4-三氟-1-（1-萘基）丁烷-1,3-二酮和两个刚性芳族配体L 1和L 2与一个氮和 一个碳原子共享配体键，优选二苯并[f，h]喹啉，苯并[h]喹啉或5,6-二氢 - 苯并[h]喹啉，其特征在于铱络合物Ir（III）L 1 L 2 L 3是第一异构体（71），其中配体键合中共享的配体L 1的氮原子和配体键合中共有的配体L 2的氮原子相对于中心铱离子并置。 本发明还涉及用于分离铱络合物（7,8）的第一异构体（71,81）和具有包含发光材料的电致发光层（4）的电致发光器件的方法，其中， 发光材料总量中的第一异构体（71,81）大于90％，优选大于95％。
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公开(公告)号：US07768191B2
公开(公告)日：2010-08-03
申请号：US11816638
申请日：2006-02-14
IPC分类号： H01J1/62
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5012 , H05B33/14
摘要： An iridium complex Ir(III)L 1L2L3 for emitting light with a central iridium ion Ir(III), with a ligand L3 as dionate from the group comprising pentane-2,4-dionate (acac), 2,2,6,6-tetramethyl-3,5-heptandionate (thd), 7,7-dimethyl-1,1,1,2,2,3,3-heptyfluoro-4,6-octandionate (fod), 4,4,4-trifluorol-(2-thienyl)butane-1,3-dionate (ttfa), 1,3-diphenylpropane-1,3-dionate (dbm), 4,4,4-trifluoro-1-(2-naphthyl)butane-1,3-dionate (tfnb) or 4,4,4-trifluoro-1-(1-naphthyl)butane-1,3-dionate and with two rigid aromatic ligands L1 and L2 with one nitrogen and one carbon atom, sharing in the ligand bond, preferably dibenzo[f,h]chinoline, benzo[h]chinoline or 5,6-dihydro-benzo[h]chinoline, characterized in that the iridium complex Ir(III)L1L2L3 is a first isomer (71), in which the nitrogen atom of the ligand L1 sharing in the ligand bonding and the nitrogen atom of the ligand L2 sharing in the ligand bonding are juxtaposed relative to the central iridium ion. The invention further relates to a method for the separation of the first isomer (71,81) of the iridium complexes (7,8) and an electroluminescent device with an electroluminescent layer (4) comprising light-emitting materials, wherein the component of the first isomer (71,81) in the total quantity of the light-emitting materials is greater than 90%, preferably greater than 95%.
摘要翻译： 铱配合物Ir（III）L 1L2L3用于发射具有中心铱离子Ir（III）的光，其中配体L3由二烷基-2,4-二酮（acac），2,2,6,6 （thd），7,7-二甲基-1,1,1,2,2,3,3-全氟-4,6-辛二酸（fod），4,4,4-三氟醇 （2-噻吩基）丁烷-1,3-二酮（ttfa），1,3-二苯基丙烷-1,3-二酮（dbm），4,4,4-三氟-1-（2-萘基）丁烷-1 （tfnb）或4,4,4-三氟-1-（1-萘基）丁烷-1,3-二酮和具有一个氮原子和一个碳原子的两个刚性芳族配体L1和L2，共享于 配体键，优选二苯并[f，h]喹啉，苯并[h]喹啉或5,6-二氢 - 苯并[h]喹啉，其特征在于铱络合物Ir（III）L1L2L3是第一异构体（71） 其中配体键合中共享的配体L1的氮原子和配体键合中共享的配体L2的氮原子相对于中心铱离子并置。 本发明还涉及用于分离铱络合物（7,8）的第一异构体（71,81）和具有包含发光材料的电致发光层（4）的电致发光器件的方法，其中， 发光材料总量中的第一异构体（71,81）大于90％，优选大于95％。
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![Pyrido[3,2-h]quinazolines and/or 5,6-dihydro Derivatives Thereof, a Method for the Production Thereof and Doped Organic Semiconductor Material Containing These](/abs-image/US/2012/02/16/US20120041197A1/abs.jpg.150x150.jpg)
6.发明申请Pyrido[3,2-h]quinazolines and/or 5,6-dihydro Derivatives Thereof, a Method for the Production Thereof and Doped Organic Semiconductor Material Containing These 有权吡啶并[3,2-h]喹唑啉和/或5,6-二氢衍生物，其制备方法和掺杂有机半导体材料公开(公告)号：US20120041197A1
公开(公告)日：2012-02-16
申请号：US13282669
申请日：2011-10-27
申请人： Josef Salbeck , Manfred Kussler , Andrea Lux
发明人： Josef Salbeck , Manfred Kussler , Andrea Lux
IPC分类号： C07D471/14
CPC分类号： C07D471/04 , C07D215/24 , C09B57/00 , H01L51/002 , H01L51/0072 , H01L51/0077 , H01L51/5052 , Y02E10/549 , Y02P70/521
摘要： The present invention relates to pyrido[3,2-h]quinazolines and/or 5,6-dihydro derivatives thereof, methods for their production and doped organic semiconductor material which use such quinazolines.
摘要翻译： 本发明涉及吡啶并[3,2-h]喹唑啉和/或其5,6-二氢衍生物，其制备方法和使用这种喹唑啉的掺杂有机半导体材料。
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公开(公告)号：US20060049397A1
公开(公告)日：2006-03-09
申请号：US11196491
申请日：2005-08-03
IPC分类号： H01B1/12 , C07C211/54
CPC分类号： H05B33/14 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , H01L51/006 , H01L51/5048 , Y02E10/549
摘要： The present invention relates to use of an organic matrix material for producing an organic semiconductor material, characterized in that the organic matrix material is comprised at least partly of a spirobifluorene compound, and the glass transition temperature of the organic matrix material is at least 120° C. and the highest occupied molecular orbital (HOMO) of the matrix material is at a maximum energy level of 5.4 eV; and also to an organic semiconductor material and electronic component.
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公开(公告)号：US06861567B2
公开(公告)日：2005-03-01
申请号：US10243302
申请日：2002-09-13
IPC分类号： C07C13/72 , C07C13/465 , B32B19/00
CPC分类号： C07C13/72 , C07C2603/18 , C07C2603/94
摘要： The present invention relates to novel spiro compounds of the formula (I):
摘要翻译： 本发明涉及式（I）的新型螺环化合物：
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公开(公告)号：US06329082B1
公开(公告)日：2001-12-11
申请号：US08836956
申请日：1997-05-22
申请人： Willi Kreuder , Donald Lupo , Josef Salbeck , Hermann Schenk , Thomas Stehlin
发明人： Willi Kreuder , Donald Lupo , Josef Salbeck , Hermann Schenk , Thomas Stehlin
IPC分类号： H05B3314
CPC分类号： H05B33/14 , C07F7/081 , C07F7/0812 , C07F7/30 , C08G61/00 , C09K11/06 , H01L51/0052 , H01L51/0059 , H01L51/0069 , H01L51/007 , H01L51/0094 , H01L2251/308 , Y10S428/917
摘要： Hetero-spiro compounds of the formula (I), where &PSgr; is an element of the 4th main group of the Periodic Table with the exception of carbon, preferably Sn, Ge or Si, particularly preferably Ge or Si, and K1 and K2 are, independently of one another, conjugated systems, for use in electroluminescence devices. The compounds of the formula (I) have a good solubility in customary organic solvents, improved film-forming properties and a significantly reduced tendency to crystallize.
摘要翻译： 式（I）的杂 - 螺化合物，其中＆PSgr; 是元素周期表的第4主要元素，除了碳，优选Sn，Ge或Si，特别优选Ge或Si，并且K 1和K 2彼此独立地是用于电致发光器件的共轭体系。 式（I）的化合物在常规有机溶剂中具有良好的溶解性，改善的成膜性能和显着降低的结晶倾向。
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10.发明授权Poly(4,5,9,10-tetrahydropyrene-2,7-diyl) derivatives and their use as electroluminescence materials 失效聚（4,5,9,10-四氢芘-2,7-二基）衍生物及其作为电致发光材料的用途
公开(公告)号：US5728480A
公开(公告)日：1998-03-17
申请号：US521263
申请日：1995-08-30
申请人： Roland Stern , Donald Lupo , Josef Salbeck , Hermann Schenk , Thomas Stehlin , Klaus Mullen , Martin Kreyenschmidt , Ullrich Scherf
发明人： Roland Stern , Donald Lupo , Josef Salbeck , Hermann Schenk , Thomas Stehlin , Klaus Mullen , Martin Kreyenschmidt , Ullrich Scherf
IPC分类号： C07C25/22 , C07B61/00 , C07C17/12 , C08G61/00 , C08G61/10 , C09K11/06 , H01L51/30 , H01L51/50 , H05B33/12 , H05B33/14
CPC分类号： C09K11/06 , C07C17/12 , C08G61/10 , H01L51/0035 , C07C2103/50 , C09K2211/1408 , C09K2211/1416 , H01L51/0052 , Y10S428/917 , Y10T428/31504 , Y10T428/31678
摘要： Poly(4,5,9,10-tetrahydropyrene-2,7-diyl) derivatives of the formula (I) ##STR1## where the symbols R.sup.1 to R.sup.4 have the following meanings: R.sup.1, R.sup.2, R.sup.3, R.sup.4 are identically or variously H, a straight-chain or branched alkyl chain containing 1 to 22 carbon atoms, it being possible for one or more nonadjacent CH.sub.2 groups also to be replaced by --O--, --COO--, --OOC-- and/or phenylene, aryl or aryloxy groups, it being possible for the aromatic to be substituted by C.sub.1 -C.sub.22 -alkyl, C.sub.1 -C.sub.22 -alkoxy, Br, Cl, F, CN, and/or NO.sub.2, Br, Cl, F, CN, NO.sub.2, or carboalkoxy containing 2 to 23 carbon atoms; n is 10 to 150, are suitable as electroluminescence materials.
摘要翻译： 式（I）的（4,5,9,10-四氢苯-2,7-二基）衍生物其中符号R1至R4具有下列含义：R1，R2，R3，R4分别为 同样或各种H，含有1至22个碳原子的直链或支链烷基链，一个或多个不相邻的CH 2基团也可以被-O - ， - COO - ， - OOC-和/或亚苯基代替 芳基或芳氧基，芳香族可以被C 1 -C 22 - 烷基，C 1 -C 22 - 烷氧基，Br，Cl，F，CN和/或NO 2，Br，Cl，F，CN，NO 2 或含有2至23个碳原子的烷氧羰基; n为10〜150，适合作为电致发光材料。
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