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1.发明授权Reaction injection moulding compositions comprising a prepolymer and at least one imino-functional compound 失效包含预聚物和至少一种亚氨基官能化合物的反应注射成型组合物
公开(公告)号：US4910279A
公开(公告)日：1990-03-20
申请号：US163922
申请日：1988-03-04
IPC分类号： B29C39/00 , B29C45/00 , B29K75/00 , C08G18/10 , C08G18/12 , C08G18/30 , C08G18/32 , C08G18/38 , C08G18/40 , C08G18/46 , C08G18/48 , C08G18/50 , C08G18/64 , C08G18/65 , C08G18/66
CPC分类号： C08G18/6685 , C08G18/10 , C08G18/12 , C08G18/3256 , C08G18/4009 , C08G18/482 , C08G18/5024 , C08G18/503 , C08G2120/00 , C08G2125/00
摘要： A reaction system for use in making a reaction injection moulded elastomer, said system comprising the following components:(A) a polyisocyanate composition comprising a reaction product of a stoichiometric excess of an organic polyisocyanate and:(i) a polymeric polyol having an average nominal hydroxyl functionality greater than 2 and an average hydroxyl equivalent weight of from about 500 to about 5000, and(ii) a polymeric polyamine having an average nominal primary and/or secondary amino functionality of from about 2 to about 3 and an average amine equivalent weight of from about 500 to about 5000, the polyol and the polyamine having glass transition temperatures below room temperature.(B) an isocyanate-reactive composition comprising at least one imino-functional compound.
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公开(公告)号：US5142013A
公开(公告)日：1992-08-25
申请号：US400636
申请日：1989-08-30
IPC分类号： C08G18/10 , C08G18/12 , C08G18/32 , C08G18/40 , C08G18/48 , C08G18/50 , C08G18/66 , C08G18/67 , C08G65/332 , C08G65/333 , C08K7/02
CPC分类号： C08G18/10 , C08G18/12 , C08G18/3256 , C08G18/4009 , C08G18/482 , C08G18/5024 , C08G18/503 , C08G18/6685 , C08G18/6795 , C08G65/3322 , C08G65/33303 , C08G65/3331 , C08K7/02 , C08G2101/0008 , C08G2101/0025 , C08G2120/00 , C08G2125/00
摘要： An isocyanate-reactive polymer comprising the reaction product of: (a) an isocyanate-terminated polyurethane prepolymer formed by reacting a polymeric polyol having a hydroxyl equivalent weight of at least 500 with a stoichiometric excess of an organic polyisocyanate, and (b) a stoichiometric excess, relative to the free isocyanate groups present in the prepolymer, of an imino-functional or enamine containing compound having a molecular weight less than about 750. The polymer is useful in reaction injection molding systems as an isocyanate-reactive ingredient.
摘要翻译： 异氰酸酯反应性聚合物，其包含以下反应产物：（a）通过使具有至少500的羟基当量的聚合多元醇与化学计量过量的有机多异氰酸酯反应形成的异氰酸酯封端的聚氨酯预聚物，和（b）化学计量 相对于存在于预聚物中的游离异氰酸酯基团，具有分子量小于约750的亚氨基官能或含烯胺化合物的过量。该聚合物可用作反应注射成型体系，作为异氰酸酯反应性成分。
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公开(公告)号：US4933416A
公开(公告)日：1990-06-12
申请号：US164393
申请日：1988-03-04
IPC分类号： B29C39/00 , B29C45/00 , B29K75/00 , C08G18/10 , C08G18/12 , C08G18/30 , C08G18/32 , C08G18/38 , C08G18/40 , C08G18/46 , C08G18/48 , C08G18/50 , C08G18/64 , C08G18/65 , C08G18/66
CPC分类号： C08G18/6685 , C08G18/10 , C08G18/12 , C08G18/3256 , C08G18/4009 , C08G18/482 , C08G18/5024 , C08G18/503 , C08G2120/00 , C08G2125/00
摘要： A polyisocyanate composition comprising a reaction product of a stoichiometric excess of an organic polyisocyanate and:(i) a polymeric polyol having an average nominal hydroxyl functionality greater than 2 and an average hydroxyl equivalent weight of from about 500 to about 5000, and(ii) a polymeric polyamine having an average nominal primary and/or secondary amino functionality of from about 2 to about 3 and an average amine equivalent weight of from about 500 to about 5000, the polyol and the polyamine having glass transition temperatures below room temperature. The composition is especially useful in the production of elastomers by the RIM process.
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公开(公告)号：US5114480A
公开(公告)日：1992-05-19
申请号：US731964
申请日：1991-07-18
IPC分类号： C10M111/04 , B29C33/60 , C08K5/00 , C08K5/098 , C08K5/16 , C08K5/29 , C08K5/3445 , C08K5/372 , C08L75/00 , C08L75/04 , C10N10/04 , C10N40/36
CPC分类号： C08K5/29 , B29C33/60 , C08K5/0008 , C08K5/098 , C08K5/3445 , C08K5/3725
摘要： An internal mould release composition, suitable for use in the production of moulded articles by the RIM process, comprising:a) a metal salt of an organic acid, said metal salt having mould release properties, andb) a compatibilising amount of an amidine or imidate compound.
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公开(公告)号：US4906674A
公开(公告)日：1990-03-06
申请号：US245431
申请日：1988-09-16
IPC分类号： C08G18/08 , C08G18/00 , C08G18/10 , C08G18/50 , C08G18/64 , C08G18/66 , C08G18/67 , C08G18/78 , C08G18/79 , C08G18/80
CPC分类号： C08G18/8054 , C08G18/10 , C08G18/5024 , C08G18/503 , C08G18/6685 , C08G18/7818 , C08G18/7831 , C08G18/7837 , C08G18/797 , C08G2101/0041 , C08G2105/02 , C08G2120/00
摘要： A polyisocyanate composition, suitable for use in the production of elastomers by the RIM process, or foams, said composition being the product of reacting an imino-functional or enamine-containing compound having a molecular weight of at least 1000 with a stoichiometric excess of an organic polyisocyanate.
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6.发明授权
公开(公告)号：US4990548A
公开(公告)日：1991-02-05
申请号：US400646
申请日：1989-08-30
IPC分类号： B29C39/00 , B29C45/00 , B29K75/00 , C08G18/10 , C08G18/12 , C08G18/30 , C08G18/32 , C08G18/38 , C08G18/40 , C08G18/46 , C08G18/48 , C08G18/50 , C08G18/64 , C08G18/65 , C08G18/66
CPC分类号： C08G18/6685 , C08G18/10 , C08G18/12 , C08G18/3256 , C08G18/4009 , C08G18/482 , C08G18/5024 , C08G18/503 , C08G2120/00 , C08G2125/00
摘要： Polyurethane/polyurea foams are made by reacting an organic polyisocyanate with resins containing imino/enamino-functional groups in the presence of blowing agents. Control of foam properties is offered by selecting imino/enamino-functional groups which decompose with water at the temperature of the reaction to produce volatile gases.
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公开(公告)号：US4935460A
公开(公告)日：1990-06-19
申请号：US378445
申请日：1989-07-07
IPC分类号： C08G18/10 , C08G18/12 , C08G18/32 , C08G18/40 , C08G18/48 , C08G18/50 , C08G18/66 , C08G18/67 , C08G65/332 , C08G65/333 , C08K7/02
CPC分类号： C08G18/10 , C08G18/12 , C08G18/3256 , C08G18/4009 , C08G18/482 , C08G18/5024 , C08G18/503 , C08G18/6685 , C08G18/6795 , C08G65/3322 , C08G65/33303 , C08G65/3331 , C08K7/02 , C08G2101/0008 , C08G2101/0025 , C08G2120/00 , C08G2125/00
摘要： An isocyanate-reactive polymer comprising the reaction product of:(a) an isocyanate-terminated polyuretane prepolymer formed by reacting a polymeric polyol having a hydroxyl equivalent weight of at least 500 with a stoichiometric excess of an organic polyisocyanate, and(b) a stoichiometric excess, relative to the free isocyanate groups present in the prepolymer, of an imino-functional or enamine-containing compound having a molecular weight less than about 750.
摘要翻译： 异氰酸酯反应性聚合物，其包含以下反应产物：（a）通过使具有至少500的羟基当量的聚合多元醇与化学计量过量的有机多异氰酸酯反应而形成的异氰酸酯封端的聚脲烷预聚物，和（b）化学计量 相对于存在于预聚物中的游离异氰酸酯基，具有分子量小于约750的亚氨基官能或含烯胺化合物。
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公开(公告)号：US4866103A
公开(公告)日：1989-09-12
申请号：US246128
申请日：1988-09-16
IPC分类号： C08G18/08 , C08G18/00 , C08G18/10 , C08G18/50 , C08G18/64 , C08G18/66 , C08G18/67 , C08G18/78 , C08G18/79 , C08G18/80
CPC分类号： C08G18/8054 , C08G18/10 , C08G18/5024 , C08G18/503 , C08G18/6685 , C08G18/7818 , C08G18/7831 , C08G18/7837 , C08G18/797 , C08G2101/0041 , C08G2105/02 , C08G2120/00
摘要： A polyisocyanate composition, suitable for use in the production of elastomers by the RIM process, said composition being the product of reacting an alcohol and/or thiol having an average hydroxyl and/or thiol functionality of from about 1.5 to about 4 and an average hydroxyl and/or thiol equivalent weight of at least 500 with at least 2 equivalents, per hydroxyl and/or thiol equivalent, of an organic polyisocyanate under such conditions that at least about 20% of the initially formed urethane and/or thiourethane groups are converted to allophanate and/or thioallophanate groups.
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公开(公告)号：US5055134A
公开(公告)日：1991-10-08
申请号：US331402
申请日：1989-03-30
IPC分类号： C10M111/04 , B29C33/60 , C08K5/00 , C08K5/098 , C08K5/16 , C08K5/29 , C08K5/3445 , C08K5/372 , C08L75/00 , C08L75/04 , C10N10/04 , C10N40/36
CPC分类号： C08K5/29 , B29C33/60 , C08K5/0008 , C08K5/098 , C08K5/3445 , C08K5/3725
摘要： An internal mould release composition, suitable for use in the production of moulded articles by the RIM process, comprising:a) a metal salt of an organic acid, said metal salt having mould release properties, andb) a compatibilizing amount of an amidine or imidate compound.
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10.发明授权公开(公告)号：US06774153B2
公开(公告)日：2004-08-10
申请号：US10191371
申请日：2002-07-01
申请人： Alain Parfondry , Jianming Yu
发明人： Alain Parfondry , Jianming Yu
IPC分类号： C08G1848
CPC分类号： C08G18/409 , C08G18/7664 , Y10S521/904
摘要： Process for making free rise or slabstock flexible polyurethane foams with high resilience using diphenylmethane diisocyanate and a polyol composition comprising: (a) a polyoxyethylene-polyoxypropylene-polyol, having an average nominal hydroxyl functionality of 2-8, an average equivalent weight of 1000-4000 and containing 10-25% by weight of oxyethylene groups; (b) 3 to 8 parts by weight of water as the sole blowing agent or optionally together with CO2 as the sole blowing agents; and (c) 2 to 20, preferably 2 to 10 parts by weight of a polyether polyol having an average nominal hydroxyl functionality of 2-6, an average equivalent weight of 200-600 and containing at least 60% by weight of oxyethylene groups; and optionally (d) up to 30 and preferably 2-25 parts by weight of particulate material which is dispersed in said polyol composition; the amounts of (b)(ii) to (b)(iv) being calculated per 100 parts by weight of (b)(i); and optionally (e) auxiliaries and additives.
摘要翻译： 使用二苯基甲烷二异氰酸酯和多元醇组合物制备具有高回弹性的自由起泡或块状软质聚氨酯泡沫的方法，所述多元醇组合物包含：（a）平均标称羟基官能度为2-8的聚氧乙烯 - 聚氧丙烯多元醇，平均当量为1000- 4000，含有10-25重量％的氧化乙烯基团; （b）作为唯一发泡剂的3至8重量份的水或任选地与作为唯一发泡剂的CO 2一起; 和（c）2至20，优选2至10重量份的平均标称羟基官能度为2-6的聚醚多元醇，平均当量为200-600，并含有至少60重量％的氧化乙烯基团; 和任选地（d）最多30个，优选2-25重量份的分散在所述多元醇组合物中的颗粒材料; （b）（ii）至（b）（iv）的量按（b）（i）每100重量份计算; 和任选的（e）助剂和添加剂。
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