公开(公告)号：US06619071B2

公开(公告)日：2003-09-16

申请号：US10163732

申请日：2002-06-06

申请人： Hideaki Sato ,  Katsuya Ishii ,  Atsushi Kosaka ,  Shigeo Numazawa ,  Seiji Inoue ,  Kouji Inagaki ,  Kazuhisa Yano ,  Norihiko Setoyama ,  Yoshiaki Fukuyama

发明人： Hideaki Sato ,  Katsuya Ishii ,  Atsushi Kosaka ,  Shigeo Numazawa ,  Seiji Inoue ,  Kouji Inagaki ,  Kazuhisa Yano ,  Norihiko Setoyama ,  Yoshiaki Fukuyama

IPC分类号： F25B1500

CPC分类号： F25B17/083 ,  B60H1/3201 ,  F25B2500/29

摘要： In an adsorption-type refrigerating apparatus, an adsorber includes therein an adsorbent having a temperature-dependent characteristic in which an amount adsorbed in an adsorption step is larger than an amount adsorbed in a desorption step, even when a vapor pressure rate in the adsorption step is equal to or lower than a vapor pressure rate in the desorption step. Therefore, even when the cooling temperature of outside air for cooling the adsorbent increases, a sufficient cooling capacity can be obtained. In addition, a difference between the amount adsorbed in the adsorption step and the amount adsorbed in the desorption step can be made larger.

摘要翻译： 在吸附式制冷装置中，吸附塔具有吸附步骤中吸附的吸附量大于脱附工序吸附量的温度依赖特性的吸附剂，即使吸附工序中的蒸汽压力 等于或低于解吸步骤中的蒸汽压力速率。 因此，即使用于冷却吸附剂的外部空气的冷却温度升高，也能够获得足够的冷却能力。 此外，可以使吸附步骤中吸附的量与解吸步骤吸附量之间的差较大。

公开(公告)号：US20090025403A1

公开(公告)日：2009-01-29

申请号：US12243278

申请日：2008-10-01

申请人： Hiroyuki Kakiuchi ,  Takahiko Takewaki ,  Masaru Fujii ,  Masanori Yamazaki ,  Hideaki Takumi ,  Hiromu Watanabe ,  Kouji Inagaki ,  Atsushi Kosaka ,  Seiji Inoue ,  Satoshi Inoue

发明人： Hiroyuki Kakiuchi ,  Takahiko Takewaki ,  Masaru Fujii ,  Masanori Yamazaki ,  Hideaki Takumi ,  Hiromu Watanabe ,  Kouji Inagaki ,  Atsushi Kosaka ,  Seiji Inoue ,  Satoshi Inoue

IPC分类号： F25B15/00 ,  F25B13/00

CPC分类号： F25B30/04 ,  B01J20/0292 ,  B01J20/18 ,  B01J20/28011 ,  F25B17/083

摘要： An adsorption heat pump is provided in which water vapor can be efficiently adsorbed and desorbed using a heat source having a lower temperature than ones heretofore in use because the pump employs an adsorbent which has a large difference in water adsorption amount in adsorption/desorption and can be regenerated (release the adsorbate) at a low temperature.The invention provides an adsorption heat pump which comprises an adsorbate, an adsorption/desorption part having an adsorbent for adsorbate adsorption/desorption, a vaporization part for adsorbate vaporization which has been connected to the adsorption/desorption part, and a condensation part for adsorbate condensation which has been connected to the adsorption/desorption part, wherein the adsorbent, when examined at 25° C., gives a water vapor adsorption isotherm which, in the relative vapor pressure range of from 0.05 to 0.30, has a relative vapor pressure region in which a change in relative vapor pressure of 0.15 results in a change in water adsorption amount of 0.18 g/g or larger.

摘要翻译： 提供了一种吸附热泵，其中使用具有比以前使用的温度低的热源可以有效地吸附和解吸水蒸汽，因为泵采用吸附/解吸中的吸水量差异大的吸附剂，并且可以 在低温下再生（释放被吸附物质）。 本发明提供了一种吸附热泵，其包括被吸附物，吸附/解吸部分，其具有用于吸附/解吸附的吸附剂，吸附/解吸部分连接的用于吸附汽化的汽化部分和用于吸附冷凝的冷凝部分 其与吸附/解吸部分连接，其中当在25℃下检查时，吸附剂得到水蒸气吸附等温线，其在相对蒸气压范围为0.05至0.30的相对蒸汽压力范围内为 相对蒸气压的变化为0.15，导致吸水量的变化为0.18g / g以上。

公开(公告)号：US07497089B2

公开(公告)日：2009-03-03

申请号：US10644859

申请日：2003-08-21

申请人： Hiroyuki Kakiuchi ,  Takahiko Takewaki ,  Masaru Fujii ,  Masanori Yamazaki ,  Hideaki Takumi ,  Hiromu Watanabe ,  Kouji Inagaki ,  Atsushi Kosaka ,  Seiji Inoue ,  Satoshi Inoue

发明人： Hiroyuki Kakiuchi ,  Takahiko Takewaki ,  Masaru Fujii ,  Masanori Yamazaki ,  Hideaki Takumi ,  Hiromu Watanabe ,  Kouji Inagaki ,  Atsushi Kosaka ,  Seiji Inoue ,  Satoshi Inoue

IPC分类号： F25B15/00 ,  F25B13/00 ,  B01J29/06

CPC分类号： F25B30/04 ,  B01J20/0292 ,  B01J20/18 ,  B01J20/28011 ,  F25B17/083

摘要： An adsorption heat pump is provided in which water vapor can be efficiently adsorbed and desorbed using a heat source having a lower temperature than ones heretofore in use because the pump employs an adsorbent which has a large difference in water adsorption amount in adsorption/desorption and can be regenerated (release the adsorbate) at a low temperature.The invention provides an adsorption heat pump which comprises an adsorbate, an adsorption/desorption part having an adsorbent for adsorbate adsorption/desorption, a vaporization part for adsorbate vaporization which has been connected to the adsorption/desorption part, and a condensation part for adsorbate condensation which has been connected to the adsorption/desorption part, wherein the adsorbent, when examined at 25° C., gives a water vapor adsorption isotherm which, in the relative vapor pressure range of from 0.05 to 0.30, has a relative vapor pressure region in which a change in relative vapor pressure of 0.15 results in a change in water adsorption amount of 0.18 g/g or larger.

摘要翻译： 提供了一种吸附热泵，其中使用具有比以前使用的温度低的热源可以有效地吸附和解吸水蒸汽，因为泵采用吸附/解吸中的吸水量差异大的吸附剂，并且可以 在低温下再生（释放被吸附物质）。 本发明提供了一种吸附热泵，其包括被吸附物，吸附/解吸部分，其具有用于吸附/解吸附的吸附剂，吸附/解吸部分连接的用于吸附汽化的汽化部分和用于吸附冷凝的冷凝部分 其与吸附/解吸部分连接，其中当在25℃下检查时，吸附剂得到水蒸气吸附等温线，其在相对蒸气压范围为0.05至0.30的相对蒸汽压力范围内为 相对蒸气压的变化为0.15，导致吸水量的变化为0.18g / g以上。

公开(公告)号：US08333079B2

公开(公告)日：2012-12-18

申请号：US12243278

申请日：2008-10-01

申请人： Hiroyuki Kakiuchi ,  Takahiko Takewaki ,  Masaru Fujii ,  Masanori Yamazaki ,  Hideaki Takumi ,  Hiromu Watanabe ,  Kouji Inagaki ,  Atsushi Kosaka ,  Seiji Inoue ,  Satoshi Inoue

发明人： Hiroyuki Kakiuchi ,  Takahiko Takewaki ,  Masaru Fujii ,  Masanori Yamazaki ,  Hideaki Takumi ,  Hiromu Watanabe ,  Kouji Inagaki ,  Atsushi Kosaka ,  Seiji Inoue ,  Satoshi Inoue

IPC分类号： F25B15/00 ,  F25B13/00 ,  B01J29/06

CPC分类号： F25B30/04 ,  B01J20/0292 ,  B01J20/18 ,  B01J20/28011 ,  F25B17/083

摘要： An adsorption heat pump is provided in which water vapor can be efficiently adsorbed and desorbed using a heat source having a lower temperature than ones heretofore in use because the pump employs an adsorbent which has a large difference in water adsorption amount in adsorption/desorption and can be regenerated (release the adsorbate) at a low temperature.The invention provides an adsorption heat pump which comprises an adsorbate, an adsorption/desorption part having an adsorbent for adsorbate adsorption/desorption, a vaporization part for adsorbate vaporization which has been connected to the adsorption/desorption part, and a condensation part for adsorbate condensation which has been connected to the adsorption/desorption part, wherein the adsorbent, when examined at 25° C., gives a water vapor adsorption isotherm which, in the relative vapor pressure range of from 0.05 to 0.30, has a relative vapor pressure region in which a change in relative vapor pressure of 0.15 results in a change in water adsorption amount of 0.18 g/g or larger.

摘要翻译： 提供了一种吸附热泵，其中使用具有比以前使用的温度低的热源可以有效地吸附和解吸水蒸汽，因为泵采用吸附/解吸中的吸水量差异大的吸附剂，并且可以 在低温下再生（释放被吸附物质）。 本发明提供了一种吸附热泵，其包括被吸附物，吸附/解吸部分，其具有用于吸附/解吸附的吸附剂，吸附/解吸部分连接的用于吸附汽化的汽化部分和用于吸附冷凝的冷凝部分 其与吸附/解吸部分连接，其中当在25℃下检查时，吸附剂得到水蒸气吸附等温线，其在相对蒸气压范围为0.05至0.30的相对蒸汽压力范围内为 相对蒸气压的变化为0.15，导致吸水量的变化为0.18g / g以上。

公开(公告)号：US07527777B2

公开(公告)日：2009-05-05

申请号：US11311562

申请日：2005-12-20

申请人： Hiromu Watanabe ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiroyuki Kakiuchi ,  Kouji Inagaki ,  Atsushi Kosaka ,  Norikazu Hosokawa

发明人： Hiromu Watanabe ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiroyuki Kakiuchi ,  Kouji Inagaki ,  Atsushi Kosaka ,  Norikazu Hosokawa

IPC分类号： C01B37/04 ,  C01B37/06 ,  C01B37/08 ,  F25B15/00 ,  F28D20/00 ,  F28F23/00 ,  F28F21/00

CPC分类号： B82Y30/00 ,  B01J20/0292 ,  B01J20/18 ,  B82Y10/00 ,  C01B37/04 ,  C01B37/06 ,  C01B37/08 ,  C01B39/54 ,  F25B17/08 ,  Y02P20/129 ,  Y10S423/30

摘要： Subjects for the invention are to provide a zeolite reduced in performance deterioration in repetitions of use or during long-term use and a process for producing the same and to provide an adsorbent comprising the zeolite and a heat utilization system or the like employing the adsorbent.The invention relates to a zeolite which has a framework density of from 10 T/nm3 to 16 T/nm3 and a carbon content of from 1% by weight to 6% by weight and satisfies the following (1) or (2): (1) the zeolite is an aluminophosphate which has a nitrogen content of from 0.5% by weight to 12% by weight and in which the aluminum may be partly replaced by Me; (2) the zeolite is a silicoaluminophosphate in which the aluminum may be partly replaced by Me and which, when burned to a carbon content lower than 0.3% by weight, retains the framework structure possessed by the silicoaluminophosphate before the burning: (provided that Me in (1) and (2) above is at least one element selected from the elements in Groups 2A, 7A, 8, 1B, and 2B of the periodic table).

摘要翻译： 本发明的目的是提供在使用重复或长期使用中降低性能劣化的沸石及其制备方法，并提供使用该吸附剂的沸石的吸附剂和热利用系统等。 本发明涉及一种沸石，其骨架密度为10T / nm 3至16T / nm 3，碳含量为1％至6％（重量），满足下列（1）或（2）：（ 1）沸石是氮含量为0.5重量％至12重量％的铝磷酸盐，其中铝可部分被Me取代; （2）沸石是硅铝磷酸盐，其中铝可以部分地被Me替代，并且当燃烧到低于0.3重量％的碳含量时，在燃烧之前保留硅铝磷酸盐所具有的骨架结构：（如果Me 在上述（1）和（2）中，是选自元素周期表第2A，7A，8，1B和2B族元素中的至少一种元素）。

公开(公告)号：US20060245994A1

公开(公告)日：2006-11-02

申请号：US11311562

申请日：2005-12-20

申请人： Hiromu Watanabe ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiroyuki Kakiuchi ,  Kouji Inagaki ,  Atsushi Kosaka ,  Norikazu Hosokawa

发明人： Hiromu Watanabe ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiroyuki Kakiuchi ,  Kouji Inagaki ,  Atsushi Kosaka ,  Norikazu Hosokawa

IPC分类号： B01J27/00 ,  B01J27/182 ,  C01B15/16 ,  C01B25/26 ,  C01B37/04 ,  C01B37/08

CPC分类号： B82Y30/00 ,  B01J20/0292 ,  B01J20/18 ,  B82Y10/00 ,  C01B37/04 ,  C01B37/06 ,  C01B37/08 ,  C01B39/54 ,  F25B17/08 ,  Y02P20/129 ,  Y10S423/30

摘要： Subjects for the invention are to provide a zeolite reduced in performance deterioration in repetitions of use or during long-term use and a process for producing the same and to provide an adsorbent comprising the zeolite and a heat utilization system or the like employing the adsorbent. The invention relates to a zeolite which has a framework density of from 10 T/nm3 to 16 T/nm3 and a carbon content of from 1% by weight to 6% by weight and satisfies the following (1) or (2): (1) the zeolite is an aluminophosphate which has a nitrogen content of from 0.5% by weight to 12% by weight and in which the aluminum may be partly replaced by Me; (2) the zeolite is a silicoaluminophosphate in which the aluminum may be partly replaced by Me and which, when burned to a carbon content lower than 0.3% by weight, retains the framework structure possessed by the silicoaluminophosphate before the burning: (provided that Me in (1) and (2) above is at least one element selected from the elements in Groups 2A, 7A, 8, 1B, and 2B of the periodic table).

摘要翻译： 本发明的目的是提供在使用重复或长期使用中降低性能劣化的沸石及其制备方法，并提供使用该吸附剂的沸石的吸附剂和热利用系统等。 本发明涉及一种沸石，其骨架密度为10T / nm 3至16T / nm 3，碳含量为1％至6％ 重量百分比，满足下列（1）或（2）：（1）沸石是氮含量为0.5重量％至12重量％的铝磷酸盐，其中铝可部分被Me取代 ; （2）沸石是硅铝磷酸盐，其中铝可以部分地被Me替代，并且当燃烧到低于0.3重量％的碳含量时，在燃烧之前保留硅铝磷酸盐所具有的骨架结构：（如果Me 在上述（1）和（2）中，是选自元素周期表第2A，7A，8，1B和2B族元素中的至少一种元素）。

公开(公告)号：US07037360B2

公开(公告)日：2006-05-02

申请号：US10638357

申请日：2003-08-12

申请人： Kouji Inagaki ,  Atsushi Kosaka ,  Satoshi Inoue ,  Yasukazu Aikawa ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiromu Watanabe ,  Hiroyuki Kakiuchi ,  Miki Iwade

发明人： Kouji Inagaki ,  Atsushi Kosaka ,  Satoshi Inoue ,  Yasukazu Aikawa ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiromu Watanabe ,  Hiroyuki Kakiuchi ,  Miki Iwade

IPC分类号： B01D53/04

CPC分类号： B01J20/2803 ,  B01J20/0229 ,  B01J20/0248 ,  B01J20/0251 ,  B01J20/0292 ,  B01J20/18 ,  B01J20/28042 ,  C01B37/065 ,  C09K5/047 ,  F02G5/00 ,  F25B17/08 ,  F25B25/02 ,  F25B27/02 ,  Y02A30/274 ,  Y02E20/14 ,  Y02P20/129 ,  Y02T10/166 ,  Y10S95/902

摘要： An adsorbent for regenerator systems, to a heat utilization system and a regenerator system that comprise the adsorbent, and to a ferroaluminophosphate and a method for production thereof. More precisely, the invention relates to an adsorbent favorable for regenerator systems, which efficiently utilizes the heat source obtainable from cars and the like to thereby realize efficient regenerator systems, to a regenerator system that comprises the adsorbent, to a ferroaluminophosphate to be the adsorbent favorable for regenerator systems, and to a method for production thereof.

摘要翻译： 用于再生器系统的吸附剂，包括吸附剂的热利用系统和再生器系统以及铁磷酸铁及其制备方法。 更准确地说，本发明涉及一种有利于再生器系统的吸附剂，其有效地利用可从汽车等获得的热源，从而将包含该吸附剂的再生器系统实现有效的再生器系统，作为有利的吸附剂的铁磷酸铁 用于再生器系统，以及其生产方法。