公开(公告)号：US07674349B2

公开(公告)日：2010-03-09

申请号：US10570609

申请日：2004-05-12

申请人： Hideki Hiraoka ,  Kouzou Kubota ,  Takeo Yamaguchi ,  Shyusei Ohya ,  Hiroshi Harada

发明人： Hideki Hiraoka ,  Kouzou Kubota ,  Takeo Yamaguchi ,  Shyusei Ohya ,  Hiroshi Harada

IPC分类号： B32B37/18 ,  B32B37/20 ,  B29C63/00

CPC分类号： B01D67/0088 ,  B01D67/0093 ,  B01D2323/30 ,  B29C44/5618 ,  H01M2/145 ,  H01M2/16 ,  H01M8/1023 ,  H01M8/106 ,  H01M8/1072 ,  H01M2300/0082 ,  Y02P70/56 ,  Y10T156/1168

摘要： There is provided a method for continuous production of a functional membrane whereby a functional membrane in which a functional polymer is filled into the micropores of a porous resin sheet can be obtained both continuously and efficiently.The method for continuous production of a functional membrane of the present invention comprises a step for impregnating and depositing a polymer precursor having a functional group on a continuously conveyed porous resin sheet; a polymerization step for continuously feeding and bringing into contact first and second resin films to one side and the other side, respectively, of the precursor-impregnated/deposited sheet comprising the porous resin sheet into which the polymer precursor is impregnated and deposited, and polymerizing the polymer precursor in a state in which the sheet is sandwiched between the two resin films; a film peeling step; and a polymer removal step.

摘要翻译： 提供连续制造功能膜的方法，由此可以连续有效地获得功能性聚合物填充到多孔树脂片的微孔中的功能膜。 连续制造本发明的功能膜的方法包括在连续输送的多孔树脂片上浸渍并沉积具有官能团的聚合物前体的步骤; 聚合步骤，用于连续地进料并使第一和第二树脂膜分别与包含聚合物前体浸渍和沉积的多孔树脂片的前体浸渍沉积片的一侧和另一侧接触，并聚合 所述聚合物前体处于所述两片树脂膜之间的状态下; 薄膜剥离步骤; 和聚合物去除步骤。

公开(公告)号：US20080216942A1

公开(公告)日：2008-09-11

申请号：US10570609

申请日：2004-05-12

申请人： Hideki Hiraoka ,  Kouzou Kubota ,  Takeo Yamaguchi ,  Nobuo Ooya ,  Hiroshi Harada

发明人： Hideki Hiraoka ,  Kouzou Kubota ,  Takeo Yamaguchi ,  Nobuo Ooya ,  Hiroshi Harada

IPC分类号： B32B38/08

CPC分类号： B01D67/0088 ,  B01D67/0093 ,  B01D2323/30 ,  B29C44/5618 ,  H01M2/145 ,  H01M2/16 ,  H01M8/1023 ,  H01M8/106 ,  H01M8/1072 ,  H01M2300/0082 ,  Y02P70/56 ,  Y10T156/1168

摘要： There is provided a method for continuous production of a functional membrane whereby a functional membrane in which a functional polymer is filled into the micropores of a porous resin sheet can be obtained both continuously and efficiently.The method for continuous production of a functional membrane of the present invention comprises a step for impregnating and depositing a polymer precursor (2-acrylamido-2-methylpropane sulfonic acid or the like) having a functional group on a continuously conveyed porous resin sheet (a porous polyethylene sheet or the like); a polymerization step for continuously feeding and bringing into contact first and second resin films (both films comprising polyester films or the like) to one side and the other side, respectively, of the precursor-impregnated/deposited sheet comprising the porous resin sheet into which the polymer precursor is impregnated and deposited, and polymerizing (by irradiation with active energy rays, or by another method) the polymer precursor in a state in which the sheet is sandwiched between the two resin films; a film peeling step; and a polymer removal step.

摘要翻译： 提供连续制造功能膜的方法，由此可以连续有效地获得功能性聚合物填充到多孔树脂片的微孔中的功能膜。 连续制造本发明的功能膜的方法包括在连续输送的多孔树脂片（a）上浸渍并沉积具有官能团的聚合物前体（2-丙烯酰氨基-2-甲基丙烷磺酸等） 多孔聚乙烯片等）; 聚合步骤，用于分别连续进料并将包含多孔树脂片的前体浸渍沉积片的第一和第二树脂膜（包括聚酯膜等的两个膜）分别接触到一侧和另一侧，其中 聚合物前体被浸渍和沉积，并且在片材夹在两个树脂膜之间的状态下聚合（通过用活性能量射线或通过另一种方法照射）聚合物前体; 薄膜剥离步骤; 和聚合物去除步骤。

公开(公告)号：US20080286627A1

公开(公告)日：2008-11-20

申请号：US11631678

申请日：2005-07-05

申请人： Kouzou Kubota ,  Hideki Hiraoka ,  Yoshinori Yamada

发明人： Kouzou Kubota ,  Hideki Hiraoka ,  Yoshinori Yamada

IPC分类号： H01M8/10 ,  B05D5/12 ,  B05D3/06

CPC分类号： H01B1/122 ,  C08F220/58 ,  C08F222/1006 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/103 ,  H01M8/1058 ,  H01M8/1081 ,  Y02E60/523 ,  Y02P70/56

摘要： To provide an inexpensive electrolyte membrane that can be used in electrochemical device applications such as a solid polymer type fuel cell, has high proton conductivity, has excellent performance in preventing permeation of methanol when used in a DMFC, and has excellent durability when operated as a fuel cell.An electrolyte membrane comprising a crosslinked electrolyte polymer comprising as essential constituent monomers (a) a compound having a polymerizable carbon-carbon double bond and a sulfonic acid group in one molecule, or a salt thereof, and (b) a (meth)acrylamide derivative represented by a specific structural formula.

摘要翻译： 为了提供可用于诸如固体聚合物型燃料电池的电化学装置应用中的便宜的电解质膜，具有高质子传导性，当在DMFC中使用时具有优异的防止甲醇渗透的性能，并且当作为 燃料电池。 一种包含交联电解质聚合物的电解质膜，其包含作为主要组分的单体（a）一分子中具有可聚合碳 - 碳双键和磺酸基的化合物或其盐，和（b）（甲基）丙烯酰胺衍生物 由具体的结构式表示。