摘要:
A process for manufacturing polycarbonate powder wherein a solution of polycarbonate in a water-immiscible solvent is emulsified in water which contains a very small amount of a laminator. The solvent is thereafter removed from the emulsion to form a dispersion of the polycarbonate powder. The polycarbonate powder settles out of the dispersion and is removed.
摘要:
The present invention relates to poly-(C.sub.2 -C.sub.10 -.alpha.-olefine)-carboxylic acids of Mw (weight average) 2000 to 350,000, to their preparation by oxidative degradation of polyolefines or by reaction of "Living" polyolefines with CO.sub.2, to their conversion into poly-(C.sub.2 -C.sub.10 -.alpha.-olefine)-carbonyl halides and to their use for preparing polyolefine/polycarbonate block copolymers and the block copolymers obtainable by the process according to the invention.
摘要:
A gas-cooled nuclear reactor whose nuclear-fuel elements are constituted by graphite-encapsulated nuclear fuel particles and have graphite coatings is shut down in accordance with the present invention by introducing into the primary coolant gas circulation, a gadolinium-containing substance which is dispersed in the primary cooling gas before the latter enters the space between the fuel elements within the reactor core so that the gadolinium-containing substance is at least partly deposited on the free graphitic surfaces of the fuel elements.
摘要:
A catalyst comprising(a) a reaction mixture formed by reacting M(RCO.sub.2).sub.3 with AlR.sub.3'.sup.1(b) AlR.sub.3.sup.2 and / or HAlR.sub.2.sup.2 and(c) a Lewis acidwherein M denotes a trivalent rare earth element with an atomic number of 57 to 71, R denotes a saturated or unsaturated, straight chain or branched chain aliphatic hydrocarbon group having 1 to 20 C-atoms which may be substituted one or more times with cycloalkyl having 5 to 7-atoms and/or phenyl, the carboxyl group being attached to a primary, secondary or tertiary C-atom; a cycloalkyl group having 5 to 7 ring carbon atoms, which may be substituted one or more times with alkyl groups having from 1 to 5 C-atoms; or an aromatic group having from 6 to 10 ring carbon atoms, which may be substituted one or more times with alkyl groups having 1 to 5 C-atoms, and R.sup.1 and R.sup.2 are identical or different, straight chain or branched chain alkyl groups having from 1 to 10 C-atoms. Said catalyst may be used for polymerizing diene monomers in solution. Its production takes place by mixing the components in any order.
摘要:
A process for the preparation of a catalyst for the polymerization and copolymerization of cyclic olefins which have 4, 5, 7 or more ring carbon atoms and at least one olefinic double bond in the ring, fromA. at least one halide or oxyhalide of molybdenum, preferably with molybdenum in the oxidation state +5,B. at least one 2-halo alcohol andC. at least one aluminium compound in the molar ratio of a : b = 1 : 1 to 1 : 10 and a : c = 1 : 0.5 to 1 : 30,Characterized in that the molybdenum halide or oxyhalide and the 2-halo alcohol are reacted with the exclusion of solvents or in the presence of chlorinated solvents which are inert towards the molybdenum salt and in which the molybdenum salt is soluble to an extent of at least 0.01 molar, and the aluminium alkyl compound is added, optionally in the presence of the monomers.
摘要:
The instant invention relates to graft polymers of vinyl phosphonic acid esters, optionally together with nitrogen-containing polymerizable vinyl compounds, on polyalkylene glycols and to a process for their production. The polymers so produced necessarily contain phosphorus and, optionally, nitrogen in the molecule. The polymers are rendered flameproof by the phosphorus and, in addition, self-extinguishing by the nitrogen.
摘要:
A non-discoloring stabilizer system for trans-polypentenamer of:A. a sulphur-containing phenol of the formula: ##SPC1##In which R.sub.1 and R.sub.3 are alkyl groups with 1 to 8 carbon atoms, aralkyl radicals with 7 to 9 carbon atoms and cycloalkyl radicals with 5 to 7 carbon atoms, R.sub.3 represents hydrogen, alkyl groups with 1 to 8 carbon atoms, cyclohexyl, cyclohexenyl or methylcyclohexenyl, R.sub.4 represents alkyl groups with 1 to 12 carbon atoms or ##SPC2##Where R.sub.1, R.sub.2 and R.sub.3 are as defined above, andB. a phenol ester of phosphorous acid of the formula: ##SPC3##In which R.sub.5 represents an alkyl or cycloalkyl group with 5 to 10 carbon atoms, R.sub.6 and R.sub.7 are the same or different and represent hydrogen, alkyl and cycloalkyl radicals each with 1 to 7 carbon atoms.
摘要:
Branched low-pressure polyethylenes are prepared by oligomerization of ethylene on a nickel-containing catalyst and polymerization of the oligomers obtained, if appropriate in the presence of ethylene, on a chromium-containing catalyst.
摘要:
The present invention relates to poly-(C.sub.2 -C.sub.10 -.alpha.-olefine)-carboxylic acids of Mw (weight average) 2000 to 350,000, to their preparation by oxidative degradation of polyolefines or by reaction of "Living" polyolefines with CO.sub.2, to their conversion into poly-(C.sub.2 -C.sub.10 -.alpha.-olefine)-carbonyl halides and to their use for preparing polyolefine/polycarbonate block copolymers and the block copolymers obtainable by the process according to the invention.
摘要:
Compounds corresponding to the formula ##STR1## wherein R.sup.1 and R.sup.2 represent H or C.sub.1 -C.sub.4 -alkyl,R.sup.3 represents H or CH.sub.3,R.sup.4 represents C.sub.7 -C.sub.20 -aralkyl,n represents 1 or 2, andm represents an integer of from 1 to 12,are suitable as ageing protecting agents for polymers and in particular for rubbers which are non-extractable in this form and may be added to polymers.