公开(公告)号：US07473575B2

公开(公告)日：2009-01-06

申请号：US10737569

申请日：2003-12-16

申请人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

发明人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

IPC分类号： H01L51/40

CPC分类号： H01L51/5016 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0062 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5048 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/508 ,  H01L51/5206 ,  H01L51/5234 ,  H01L2251/552 ,  Y10S428/917

摘要： A triplet light emitting device which has high efficiency and improved stability and which can be fabricated by a simpler process is provided by simplifying the device structure and avoiding use of an unstable material. In a multilayer device structure using no hole blocking layer conventionally used in a triplet light emitting device, that is, a device structure in which on a substrate, there are formed an anode, a hole transporting layer constituted by a hole transporting material, an electron transporting and light emitting layer constituted by an electron transporting material and a dopant capable of triplet light emission, and a cathode, which are laminated in the stated order, the combination of the hole transporting material and the electron transporting material and the combination of the electron transporting material and the dopant material are optimized.

摘要翻译： 通过简化器件结构并避免使用不稳定的材料，提供了具有高效率和改进的稳定性并且可以通过更简单的工艺制造的三重态发光器件。 在三重态发光器件中常规使用的不使用空穴阻挡层的多层器件结构中，即在衬底上形成阳极的器件结构，由空穴传输材料构成的空穴传输层，电子 由电子传输材料和能够三重发光的掺杂剂构成的传输和发光层和阴极，按照所述顺序层叠空穴传输材料和电子传输材料的组合以及电子的组合 运输材料和掺杂剂材料被优化。

公开(公告)号：US08610109B2

公开(公告)日：2013-12-17

申请号：US12793735

申请日：2010-06-04

申请人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

发明人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

IPC分类号： H01L29/00

CPC分类号： H01L51/5016 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0062 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5048 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/508 ,  H01L51/5206 ,  H01L51/5234 ,  H01L2251/552 ,  Y10S428/917

摘要： A triplet light emitting device which has high efficiency and improved stability and which can be fabricated by a simpler process is provided by simplifying the device structure and avoiding use of an unstable material. In a multilayer device structure using no hole blocking layer conventionally used in a triplet light emitting device, that is, a device structure in which on a substrate, there are formed an anode, a hole transporting layer constituted by a hole transporting material, an electron transporting and light emitting layer constituted by an electron transporting material and a dopant capable of triplet light emission, and a cathode, which are laminated in the stated order, the combination of the hole transporting material and the electron transporting material and the combination of the electron transporting material and the dopant material are optimized.

公开(公告)号：US06734457B2

公开(公告)日：2004-05-11

申请号：US10304410

申请日：2002-11-26

申请人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

发明人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

IPC分类号： H01L3524

CPC分类号： H01L51/5016 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0062 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5048 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/508 ,  H01L51/5206 ,  H01L51/5234 ,  H01L2251/552 ,  Y10S428/917

摘要： A triplet light emitting device which has high efficiency and improved stability and which can be fabricated by a simpler process is provided by simplifying the device structure and avoiding use of an unstable material. In a multilayer device structure using no hole blocking layer conventionally used in a triplet light emitting device, that is, a device structure in which on a substrate, there are formed an anode, a hole transporting layer constituted by a hole transporting material, an electron transporting and light emitting layer constituted by an electron transporting material and a dopant capable of triplet light emission, and a cathode, which are laminated in the stated order, the combination of the hole transporting material and the electron transporting material and the combination of the electron transporting material and the dopant material are optimized.

摘要翻译： 通过简化器件结构并避免使用不稳定的材料，提供了具有高效率和改进的稳定性并且可以通过更简单的工艺制造的三重态发光器件。 在三重态发光器件中常规使用的不使用空穴阻挡层的多层器件结构中，即在衬底上形成阳极的器件结构，由空穴传输材料构成的空穴传输层，电子 由电子传输材料和能够三重发光的掺杂剂构成的传输和发光层和阴极，按照所述顺序层叠空穴传输材料和电子传输材料的组合以及电子的组合 运输材料和掺杂剂材料被优化。

公开(公告)号：US07482626B2

公开(公告)日：2009-01-27

申请号：US11976781

申请日：2007-10-29

申请人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

发明人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

IPC分类号： H01L51/40

CPC分类号： H01L51/5016 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0062 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5048 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/508 ,  H01L51/5206 ,  H01L51/5234 ,  H01L2251/552 ,  Y10S428/917

摘要： A triplet light emitting device which has high efficiency and improved stability and which can be fabricated by a simpler process is provided by simplifying the device structure and avoiding use of an unstable material. In a multilayer device structure using no hole blocking layer conventionally used in a triplet light emitting device, that is, a device structure in which on a substrate, there are formed an anode, a hole transporting layer constituted by a hole transporting material, an electron transporting and light emitting layer constituted by an electron transporting material and a dopant capable of triplet light emission, and a cathode, which are laminated in the stated order, the combination of the hole transporting material and the electron transporting material and the combination of the electron transporting material and the dopant material are optimized.

公开(公告)号：US20080143254A1

公开(公告)日：2008-06-19

申请号：US11976781

申请日：2007-10-29

申请人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

发明人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

IPC分类号： H01J1/63

CPC分类号： H01L51/5016 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0062 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5048 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/508 ,  H01L51/5206 ,  H01L51/5234 ,  H01L2251/552 ,  Y10S428/917

摘要： A triplet light emitting device which has high efficiency and improved stability and which can be fabricated by a simpler process is provided by simplifying the device structure and avoiding use of an unstable material. In a multilayer device structure using no hole blocking layer conventionally used in a triplet light emitting device, that is, a device structure in which on a substrate, there are formed an anode, a hole transporting layer constituted by a hole transporting material, an electron transporting and light emitting layer constituted by an electron transporting material and a dopant capable of triplet light emission, and a cathode, which are laminated in the stated order, the combination of the hole transporting material and the electron transporting material and the combination of the electron transporting material and the dopant material are optimized.

摘要翻译： 通过简化器件结构并避免使用不稳定的材料，提供了具有高效率和改进的稳定性并且可以通过更简单的工艺制造的三重态发光器件。 在三重态发光器件中常规使用的不使用空穴阻挡层的多层器件结构中，即在衬底上形成阳极的器件结构，由空穴传输材料构成的空穴传输层，电子 由电子传输材料和能够三重发光的掺杂剂构成的传输和发光层和阴极，按照所述顺序层叠空穴传输材料和电子传输材料的组合以及电子 运输材料和掺杂剂材料被优化。

公开(公告)号：US07737437B2

公开(公告)日：2010-06-15

申请号：US12335747

申请日：2008-12-16

申请人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

发明人： Hiroko Yamazaki ,  Atsushi Tokuda ,  Tetsuo Tsutsui

IPC分类号： H01L51/40

CPC分类号： H01L51/5016 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0062 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5048 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/508 ,  H01L51/5206 ,  H01L51/5234 ,  H01L2251/552 ,  Y10S428/917

摘要： A triplet light emitting device which has high efficiency and improved stability and which can be fabricated by a simpler process is provided by simplifying the device structure and avoiding use of an unstable material. In a multilayer device structure using no hole blocking layer conventionally used in a triplet light emitting device, that is, a device structure in which on a substrate, there are formed an anode, a hole transporting layer constituted by a hole transporting material, an electron transporting and light emitting layer constituted by an electron transporting material and a dopant capable of triplet light emission, and a cathode, which are laminated in the stated order, the combination of the hole transporting material and the electron transporting material and the combination of the electron transporting material and the dopant material are optimized.

摘要翻译： 通过简化器件结构并避免使用不稳定的材料，提供了具有高效率和改进的稳定性并且可以通过更简单的工艺制造的三重态发光器件。 在三重态发光器件中常规使用的不使用空穴阻挡层的多层器件结构中，即在衬底上形成阳极的器件结构，由空穴传输材料构成的空穴传输层，电子 由电子传输材料和能够三重发光的掺杂剂构成的传输和发光层和阴极，按照所述顺序层叠空穴传输材料和电子传输材料的组合以及电子的组合 运输材料和掺杂剂材料被优化。

公开(公告)号：US07951470B2

公开(公告)日：2011-05-31

申请号：US11632593

申请日：2005-08-12

申请人： Atsushi Tokuda ,  Masakazu Egawa

发明人： Atsushi Tokuda ,  Masakazu Egawa

IPC分类号： H01L51/54

CPC分类号： H01L51/0054 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1044 ,  H01L51/0072 ,  H01L51/5012 ,  H01L2251/5338 ,  H01L2251/5361 ,  H05B33/14 ,  Y10S428/917

摘要： According to the present invention, a light-emitting element, a light-emitting device, and a lighting system, each of which has a broad spectrum like sunlight and has high color rendering properties, can be obtained. One embodiment of the present invention has a light-emitting device which includes at least two kinds of luminescence center materials, and at least one kind of the luminescence center materials is a quinoxaline derivative represented by the following general formula (1): wherein R1 to R4 are individually hydrogen or an alkyl group having 4 carbon atoms (a straight-chain structure or a branch structure).

摘要翻译： 根据本发明，可以获得具有像太阳光这样的宽光谱并且具有高显色性的发光元件，发光元件和照明系统。 本发明的一个实施方案具有包含至少两种发光中心材料的发光装置，并且至少一种发光中心材料是由以下通式（1）表示的喹喔啉衍生物：其中R1至 R4独立地为氢或具有4个碳原子的烷基（直链结构或分支结构）。

公开(公告)号：US07601435B2

公开(公告)日：2009-10-13

申请号：US10826838

申请日：2004-04-16

申请人： Satoko Shitagaki ,  Atsushi Tokuda ,  Hiroko Abe ,  Ryoji Nomura ,  Satoshi Seo

发明人： Satoko Shitagaki ,  Atsushi Tokuda ,  Hiroko Abe ,  Ryoji Nomura ,  Satoshi Seo

IPC分类号： B32B9/00 ,  C07D241/36

CPC分类号： C07D403/14 ,  C07D241/42 ,  C07D401/10 ,  C07D401/14 ,  C09K11/06 ,  C09K2211/1044 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0071 ,  H01L51/0078 ,  H01L51/0081 ,  H01L51/5012 ,  H01L51/5016 ,  H05B33/14 ,  Y10S428/917

摘要： Target is to provide an organic compound material having a bipolar character.A quinoxaline derivative represented by a general formula (1) is provided. In the formula, R1-R12 each independently represents a hydrogen atom, a halogen atom, a lower alkyl group, an alkoxy group, an acyl group, a nitro group, a cyano group, an amino group, a dialkylamino group, a diarylamino group, a vinyl group, an aryl group, or a heterocyclic residue group. R9 and R10, R10 and R11, and R11 and R12 are each independent or respectively mutually bonded to form an aromatic ring. Ar1-Ar4 each independently represents an aryl group or a heterocyclic residue group. Ar1, Ar2, Ar3 and Ar4 are each independent or Ar1 and Ar2, and Ar3 and Ar4 are respectively mutually bonded directly, or Ar1 and Ar3, and Ar3 and Ar4 are bonded via oxygen (O), sulfur (S) or a carbonyl group.

摘要翻译： 目标是提供具有双极性的有机化合物。 提供由通式（1）表示的喹喔啉衍生物。 式中，R 1 -R 12各自独立地表示氢原子，卤素原子，低级烷基，烷氧基，酰基，硝基，氰基，氨基，二烷基氨基，二芳基氨基 ，乙烯基，芳基或杂环残基。 R9和R10，R10和R11，以及R11和R12各自独立地或分别相互结合形成芳香环。 Ar1-Ar4各自独立地表示芳基或杂环残基。 Ar1，Ar2，Ar3和Ar4各自独立，Ar1和Ar2，Ar3和Ar4分别直接相互键合，或Ar1和Ar3，Ar3和Ar4通过氧（O），硫（S）或羰基 。

公开(公告)号：US07560177B2

公开(公告)日：2009-07-14

申请号：US11506856

申请日：2006-08-21

申请人： Satoshi Seo ,  Atsushi Tokuda ,  Yasuo Nakamura

发明人： Satoshi Seo ,  Atsushi Tokuda ,  Yasuo Nakamura

IPC分类号： H01L51/54

CPC分类号： H01L51/5016 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1025 ,  C09K2211/183 ,  H01L51/0077 ,  Y10S428/917

摘要： A chelate complex having as its central metal tungsten which is an inexpensive metal and which is a heavy atom is applied to an organic light emitting element, thereby obtaining an organic light emitting element capable of converting the triplet excitation energy into light emission. By applying the organic light emitting element using this metal complex, an inexpensive light emitting device which is bright but consumes little power can be provided as well as an electric appliance using the light emitting device.

摘要翻译： 作为其中心金属钨作为廉价金属并且是重质原子的螯合络合物被施加到有机发光元件上，从而获得能够将三重态激发能转化为发光的有机发光元件。 通过使用该金属络合物涂布有机发光元件，可以提供明亮但消耗很少功率的廉价的发光器件以及使用该发光器件的电器。

公开(公告)号：US20060280969A1

公开(公告)日：2006-12-14

申请号：US11506856

申请日：2006-08-21

申请人： Satoshi Seo ,  Atsushi Tokuda ,  Yasuo Nakamura

发明人： Satoshi Seo ,  Atsushi Tokuda ,  Yasuo Nakamura

IPC分类号： B32B19/00 ,  B32B9/00

CPC分类号： H01L51/5016 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1025 ,  C09K2211/183 ,  H01L51/0077 ,  Y10S428/917

摘要： A chelate complex having as its central metal tungsten which is an inexpensive metal and which is a heavy atom is applied to an organic light emitting element, thereby obtaining an organic light emitting element capable of converting the triplet excitation energy into light emission. By applying the organic light emitting element using this metal complex, an inexpensive light emitting device which is bright but consumes little power can be provided as well as an electric appliance using the light emitting device.