LITHIUM SECONDARY BATTERY AND PRODUCTION METHOD OF THE SAME
    1.
    发明申请
    LITHIUM SECONDARY BATTERY AND PRODUCTION METHOD OF THE SAME 有权
    锂二次电池及其生产方法

    公开(公告)号:US20090263721A1

    公开(公告)日:2009-10-22

    申请号:US12388580

    申请日:2009-02-19

    IPC分类号: H01M4/58

    摘要: To provide a lithium secondary battery which suppresses a decrease in the charge and discharge efficiency during a battery storage test and which is excellent in maintaining the battery capacity after the storage test. There are disclosed a nonaqueous lithium battery, comprising: a positive electrode active material comprising a lithium-containing oxide capable of inserting and detaching lithium ions; a negative electrode active material comprising a carbon material capable of inserting and detaching lithium ions; and an electrolytic solution containing a lithium ion, wherein the surface of the negative electrode active material after initializing charging is coated with a compound derived from vinylene carbonate, and wherein a weight power density of the lithium battery is no less than 100 Wh/kg, and a method of producing a nonaqueous lithium battery comprising a step of sealing a positive electrode active material, a negative electrode active material, and a nonaqueous electrolytic solution using a sealed container, wherein a predetermined amount of vinylene carbonate is added into the nonaqueous electrolytic solution, and the initializing charging is carried out to form a coating on the surface of the negative electrode active material, the coating being derived from the vinylene carbonate.

    摘要翻译: 提供一种锂二次电池,其抑制电池存储试验期间的充放电效率的降低,并且在保存试验后保持电池容量优异。 公开了一种非水锂电池,其包括:正极活性物质,其包含能够插入和分离锂离子的含锂氧化物; 包含能够插入和分离锂离子的碳材料的负极活性材料; 以及含有锂离子的电解液,其中,初始化充电后的负极活性物质的表面涂布有碳酸亚乙烯酯衍生的化合物,其中锂电池的重量功率密度为100Wh / kg以上, 以及一种制造非水锂电池的方法,包括使用密封容器密封正极活性物质,负极活性物质和非水电解液的步骤,其中将预定量的碳酸亚乙烯酯加入到非水电解液 ,并进行初始化充电以在负极活性材料的表面上形成涂层,该涂层源自碳酸亚乙烯酯。

    Lithium secondary battery and production method of the same
    2.
    发明授权
    Lithium secondary battery and production method of the same 有权
    锂二次电池及其制作方法相同

    公开(公告)号:US08192871B2

    公开(公告)日:2012-06-05

    申请号:US12388580

    申请日:2009-02-19

    IPC分类号: H01M4/13

    摘要: To provide a lithium secondary battery which suppresses a decrease in the charge and discharge efficiency during a battery storage test and which is excellent in maintaining the battery capacity after the storage test. There are disclosed a nonaqueous lithium battery, comprising: a positive electrode active material comprising a lithium-containing oxide capable of inserting and detaching lithium ions; a negative electrode active material comprising a carbon material capable of inserting and detaching lithium ions; and an electrolytic solution containing a lithium ion, wherein the surface of the negative electrode active material after initializing charging is coated with a compound derived from vinylene carbonate, and wherein a weight power density of the lithium battery is no less than 100 Wh/kg, and a method of producing a nonaqueous lithium battery comprising a step of sealing a positive electrode active material, a negative electrode active material, and a nonaqueous electrolytic solution using a sealed container, wherein a predetermined amount of vinylene carbonate is added into the nonaqueous electrolytic solution, and the initializing charging is carried out to form a coating on the surface of the negative electrode active material, the coating being derived from the vinylene carbonate.

    摘要翻译: 提供一种锂二次电池,其抑制电池存储试验期间的充放电效率的降低,并且在保存试验后保持电池容量优异。 公开了一种非水锂电池,其包括:正极活性物质,其包含能够插入和分离锂离子的含锂氧化物; 包含能够插入和分离锂离子的碳材料的负极活性材料; 以及含有锂离子的电解液,其中,初始化充电后的负极活性物质的表面涂布有碳酸亚乙烯酯衍生的化合物,其中锂电池的重量功率密度为100Wh / kg以上, 以及一种制造非水锂电池的方法,包括使用密封容器密封正极活性物质,负极活性物质和非水电解液的步骤,其中将预定量的碳酸亚乙烯酯加入到非水电解液 ,并进行初始化充电以在负极活性材料的表面上形成涂层,该涂层源自碳酸亚乙烯酯。

    Lithium-Ion Battery
    3.
    发明申请
    Lithium-Ion Battery 审中-公开
    锂离子电池

    公开(公告)号:US20130189591A1

    公开(公告)日:2013-07-25

    申请号:US13877687

    申请日:2011-08-19

    IPC分类号: H01M10/056

    摘要: The present invention aims to improve the fire resistance of an electrolytic solution used for a lithium-ion battery and improve the life characteristics of the lithium-ion battery. In the lithium ion battery of the present invention, specific amounts of ethylene carbonate and dimethyl carbonate are used for a non-aqueous electrolytic solution, and trimethyl phosphate is added thereto. Specifically, the non-aqueous electrolytic solution contains 60 vol % or more of ethylene carbonate (EC) and dimethyl carbonate (DMC). The volume ratio of DMC to the sum of EC and DMC is 0.3 to 0.6, and the non-aqueous electrolytic solution contains 3 to 5 wt % of trimethyl phosphate (TMP) with respect to the total weight of the non-aqueous electrolytic solution. Such a non-aqueous electrolytic solution has an effect of improving the self-fire extinguishing property, and thus improves the safety of the lithium-ion battery.

    摘要翻译: 本发明旨在提高用于锂离子电池的电解液的耐火性,并提高锂离子电池的使用寿命。 在本发明的锂离子电池中,对于非水电解液使用碳酸亚乙酯和碳酸二甲酯的特定量,并向其中加入磷酸三甲酯。 具体地说,非水电解液含有60体积%以上的碳酸亚乙酯(EC)和碳酸二甲酯(DMC)。 DMC与EC和DMC的总和的体积比为0.3〜0.6,相对于非水电解液的总重量,非水电解液含有3〜5重量%的磷酸三甲酯(TMP)。 这样的非水电解液具有提高自熄灭性的效果,提高了锂离子电池的安全性。

    Lithium-Ion Rechargeable Battery
    5.
    发明申请
    Lithium-Ion Rechargeable Battery 有权
    锂离子充电电池

    公开(公告)号:US20130202957A1

    公开(公告)日:2013-08-08

    申请号:US13877621

    申请日:2011-08-19

    摘要: Provided is a technique of achieving a longer-life lithium ion secondary battery. The lithium ion secondary battery includes a cathode including a cathode active material containing Mn, an anode including an anode active material containing graphite and non-aqueous electrolytic solution including electrolyte, and LiBF4 and LiPF6 are allowed to coexist in the non-aqueous electrolytic solution. Especially preferably LiPF6 is contained more than LiBF4 in the electrolytic solution. Preferably the electrolytic solution further includes iodide salt. As a result, an oxide of phosphor and boron is deposited on the cathode, thus preventing elution of Mn included in the cathode. The amount of these electrolytes is preferably in the decreasing order of phosphor, boron and then iodine.

    摘要翻译: 提供了一种实现更长寿命的锂离子二次电池的技术。 锂离子二次电池包括含有包含Mn的正极活性物质的阴极,包含含有石墨的负极活性物质的阳极和包含电解质的非水电解液,LiBF 4和LiPF 6的阴极共存在非水电解液中。 特别优选LiPF 6在电解液中含有多于LiBF 4。 优选地,电解液还包含碘化物盐。 结果,在阴极上沉积荧光体和硼的氧化物,从而防止阴极中包含的Mn的溶出。 这些电解质的量优选为荧光体,硼和碘的降序。

    Charging/discharging control unit for lithium secondary battery
    6.
    发明授权
    Charging/discharging control unit for lithium secondary battery 失效
    锂二次电池充放电控制单元

    公开(公告)号:US08421418B2

    公开(公告)日:2013-04-16

    申请号:US12541612

    申请日:2009-08-14

    IPC分类号: H02J7/00

    CPC分类号: H02J7/0086

    摘要: In a charging/discharging unit provided with: a lithium secondary battery, a voltage detecting sensor for detecting a voltage and a current detecting sensor; the charging/discharging control unit is further provided with a controller, and a discharging element for performing a constant voltage discharging operation of 3 V. A voltage, V0, of the battery when a discharging operation is terminated (t=0) is measured by the voltage detecting sensor. If V0≦3.6 V, within a rest time during which the battery is not charged/discharged until a next charging operation, a voltage, V1, of the battery when a time, t1, has elapsed is measured by the voltage detecting sensor. If this voltage charge is in a range of V1-V0≧0.2 V, then the constant voltage discharging operation of 3 V is carried out for a time duration longer than or equal to 1 hour.

    摘要翻译: 在具有锂二次电池,用于检测电压的电压检测传感器和电流检测传感器的充电/放电单元中, 充放电控制单元还设置有控制器和用于执行3V的恒定电压放电操作的放电元件。当放电操作终止时,电池的电压V0(t = 0)通过 电压检测传感器。 如果V0≦̸ 3.6V,则在电池在下一次充电操作之前未被充电/放电的休息时间内,当经过时间t1时,电池的电压V1由电压检测传感器测量。 如果该电压在V1-V0≥0.2V的范围内,则3V的恒定电压放电动作持续时间大于等于1小时。

    Charging/Discharging Control Unit for Lithium Secondary Battery
    7.
    发明申请
    Charging/Discharging Control Unit for Lithium Secondary Battery 失效
    锂二次电池充电/放电控制单元

    公开(公告)号:US20100072949A1

    公开(公告)日:2010-03-25

    申请号:US12541612

    申请日:2009-08-14

    IPC分类号: H02J7/04

    CPC分类号: H02J7/0086

    摘要: In a charging/discharging unit provided with: a lithium secondary battery, a voltage detecting sensor for detecting a voltage and a current detecting sensor; the charging/discharging control unit is further provided with a controller, and a discharging element for performing a constant voltage discharging operation of 3 V. A voltage, V0, of the battery when a discharging operation is terminated (t=0) is measured by the voltage detecting sensor. If V0≦3.6 V, within a rest time during which the battery is not charged/discharged until a next charging operation, a voltage, V1, of the battery when a time, t1, has elapsed is measured by the voltage detecting sensor. If this voltage charge is in a range of V1−V0≧0.2 V, then the constant voltage discharging operation of 3 V is carried out for a time duration longer than or equal to 1 hour.

    摘要翻译: 在具有锂二次电池,用于检测电压的电压检测传感器和电流检测传感器的充电/放电单元中, 充放电控制单元还设置有控制器和用于执行3V的恒定电压放电操作的放电元件。当放电操作终止时,电池的电压V0(t = 0)通过 电压检测传感器。 如果V0≦̸ 3.6V,则在电池在下一次充电操作之前未被充电/放电的休息时间内,当经过时间t1时,电池的电压V1由电压检测传感器测量。 如果该电压在V1-V0≥0.2V的范围内,则3V的恒定电压放电动作持续时间大于等于1小时。