公开(公告)号：US4142018A

公开(公告)日：1979-02-27

申请号：US762182

申请日：1977-01-24

申请人： Hiroshi Ozawa ,  Yoshinori Torii ,  Nobuki Kobayashi ,  Koji Ishikawa

发明人： Hiroshi Ozawa ,  Yoshinori Torii ,  Nobuki Kobayashi ,  Koji Ishikawa

IPC分类号： B05D1/38 ,  B05D5/06 ,  B05D7/00 ,  B32B7/08 ,  B05D3/02

CPC分类号： B05D7/536 ,  B05D5/068 ,  B05D7/576 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/31692 ,  Y10T428/31906 ,  Y10T428/31928

摘要： A process for forming a coating with a metallic finish, which comprises(1) a first step of coating an article with [A] a water-thinnable paint comprising (a) a cross-linkable (meth)acrylate ester copolymer or a mixture of the (meth)acrylate ester copolymers containing at least 0.1 equivalent, per 1,000 g of resin solids, of a carboxyl or carboxyl ion group and a group capable of undergoing a ring-opening reaction with the carboxyl or carboxy ion group upon heating, both of said groups being contained in the same or different copolymers, and having a number average molecular weight of at least 3,000 and (b) metallic scales, and baking the coating paint to form a coating containing the metallic scales and(2) a second step of coating [B] a powder paint comprising a (meth)acrylate ester copolymer having a glycidyl or .beta.-methylglycidyl group and a polycarboxylic acid on the scale-containing coating obtained in the first step, and baking the coated paint to form a protective coating for the scale-containing coating.

摘要翻译： 一种形成具有金属涂层的涂层的方法，其包括（1）用[A]一种水稀释涂料涂料的第一步骤，其包含（a）可交联（甲基）丙烯酸酯共聚物或 （甲基）丙烯酸酯共聚物，每1000克树脂固体含有至少0.1当量的羧基或羧基离子基团和能够在加热时与羧基或羧基离子基团开环反应的基团，两者均为 所述基团包含在相同或不同的共聚物中，并且具有至少3,000的数均分子量和（b）金属垢，并烘烤涂料以形成包含金属垢的涂层和（2）第二步 涂料[B]一种粉末涂料，其包含在第一步骤中获得的含水垢的涂料上含有缩水甘油基或β-甲基缩水甘油基的（甲基）丙烯酸酯共聚物和多元羧酸，并烘烤涂覆的涂料以形成保护涂层 含鳞屑的涂层。

公开(公告)号：US4139672A

公开(公告)日：1979-02-13

申请号：US750414

申请日：1976-12-14

申请人： Hiroshi Ozawa ,  Yoshinori Torii ,  Yasuo Okita ,  Nobuki Kobayashi ,  Koji Ishikawa

发明人： Hiroshi Ozawa ,  Yoshinori Torii ,  Yasuo Okita ,  Nobuki Kobayashi ,  Koji Ishikawa

IPC分类号： B05D1/00 ,  B05D1/38 ,  B05D5/06 ,  B05D7/00 ,  C08L33/06 ,  C09D5/38 ,  C09D133/06 ,  B32B7/08 ,  B05D3/02

CPC分类号： B05D7/577 ,  B05D5/068 ,  C09D133/068 ,  C09D5/38 ,  B05D1/007 ,  B05D2202/00 ,  B05D2451/00 ,  C08L33/066 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/31692 ,  Y10T428/31906 ,  Y10T428/31928

摘要： A process for forming a coating having a metallic finish, which comprises (I) coating an undercoat paint (A) by electrodeposition on an article to be coated, (II) coating a water-thinnable intermediate coat paint (B) containing metallic scales on the coated surface of the undercoat before the undercoat is baked, (III) baking the undercoat and the intermediate coat, (IV) coating a powdery top coat paint (C) on the baked surface of the intermediate coat, and then (V) baking the top coat, said intermediate coat paint (B) containing a solid resin component at least 60% by weight of the entire resin solids which consists of a (meth)acrylate ester copolymer containing at least 0.1 equivalent, per 1,000 g of the solids content of the copolymer, of carboxyl or carboxyl ion groups and having a number average molecular weight of at least 3,000, and said top coat paint (C) containing a (meth)acrylate ester copolymer containing a glycidyl or .beta.-methlglycidyl group and a polycarboxylic acid.

摘要翻译： 一种用于形成具有金属光洁度的涂层的方法，其包括（I）通过电沉积在待涂覆的物品上涂覆底漆（A），（II）将含有金属垢的可水稀释的中间涂料涂料（B） 烘烤底漆前的底层涂层表面，（III）烘烤底涂层和中间涂层，（IV）在中间涂层的烘烤表面上涂覆粉末状面漆（C），然后（V）烘烤 表面涂层，所述中间涂料涂料（B）含有至少60重量％的整个树脂固体的固体树脂组分，所述固体树脂组分由含有至少0.1当量的（甲基）丙烯酸酯共聚物组成，每1000克固含量 的共聚物，羧基或羧基离子基团，数均分子量为3,000以上，所述面漆（C）含有含有缩水甘油基或β-甲基缩水甘油基的（甲基）丙烯酸酯共聚物和多元羧酸 。

公开(公告)号：US4455360A

公开(公告)日：1984-06-19

申请号：US154910

申请日：1980-05-30

申请人： Koji Ishikawa ,  Hiroshi Ozawa ,  Nobuki Kobayashi ,  Yoshio Kikuta ,  Kenichi Nakane

发明人： Koji Ishikawa ,  Hiroshi Ozawa ,  Nobuki Kobayashi ,  Yoshio Kikuta ,  Kenichi Nakane

IPC分类号： G03G9/087 ,  G03G9/08

CPC分类号： G03G9/08726 ,  Y10S430/105

摘要： An electrophotographic toner comprising a constituent resin and a colorant, in which the constituent resin has a softening point ranging from room temperature to 170.degree. C. and comprises (a) a copolymer of cinnamic acid and one or more vinyl monomers, (b) a mixture of a copolymer as defined in (a) and a polymer having good compatibility therewith, (c) a mixture of a copolymer as defined in (a) and cinnamic acid, (d) a mixture of a polymer as defined in (b) and cinnamic acid, or (e) a mixture of a mixture as defined in (b) and cinnamic acid, the cinnamic acid content of the constituent resin being from 1 to 25 parts by weight per 100 parts by weight of the constituent resin in the case of cinnamic acid copolymerized with one or more vinyl monomers and from 0.1 to 25 parts by weight per 100 parts by weight of the constituent resin in the case of cinnamic acid present in the uncombined state.

摘要翻译： 包含构成树脂和着色剂的电子照相调色剂，其中构成树脂的软化点为室温至170℃，并且包含（a）肉桂酸和一种或多种乙烯基单体的共聚物，（b） （a）中定义的共聚物和与其具有良好相容性的聚合物的混合物，（c）如（a）中定义的共聚物和肉桂酸的混合物，（d）如（b）中所定义的聚合物的混合物， 和（e）如（b）中定义的混合物和肉桂酸的混合物，构成树脂的肉桂酸含量为每100重量份构成树脂中的成分树脂1至25重量份 与一种或多种乙烯基单体共聚的肉桂酸的情况和在未组合状态下存在肉桂酸的情况下每100重量份组分树脂为0.1至25重量份。

公开(公告)号：USRE32261E

公开(公告)日：1986-10-07

申请号：US21982

申请日：1979-03-19

申请人： Kuniomi Hirota ,  Akio Masumoto ,  Hiroshi Ozawa ,  Nobuki Kobayashi ,  Teruo Honda

发明人： Kuniomi Hirota ,  Akio Masumoto ,  Hiroshi Ozawa ,  Nobuki Kobayashi ,  Teruo Honda

IPC分类号： C08F220/12 ,  C08F220/32 ,  C08L33/06 ,  C09D133/06

CPC分类号： C09D133/068 ,  C08F220/12 ,  C08F220/32 ,  C08L33/064 ,  Y10T428/31699

摘要： Solid copolymers are produced by copolymerizing a mixture of: (A) at least 30% by weight of a monomer having the formula: ##STR1## wherein R.sub.1 is H or CH.sub.3 and R.sub.2 is an alkyl radical containing from 1 to 14 carbon atoms; (B) from 3 to 20% by weight of an ethylenic .alpha.,.beta. unsaturated carboxylic acid or anhydride thereof, or from 3 to 40% by weight of glycidyl acrylate or glycidyl methacrylate; and (C) from 0 to 67% by weight of a monomer copolymerizable with said monomers (A) and (B). Preferably, the mixture is first bulk-polymerized until conversion to the copolymer is from 10 to 80% by weight and the polymerization is completed by suspension-polymerization. Thermosetting solid coating compositions are produced by mixing a major proportion of a solid copolymer so produced with a minor proportion of a cross-linking compound or with an epoxy resin containing at least 2 epoxy radicals in the molecule in presence of a tertiary amine curing accelerator.

公开(公告)号：US4042645A

公开(公告)日：1977-08-16

申请号：US426954

申请日：1973-12-13

申请人： Kuniomi Hirota ,  Akio Masumoto ,  Hiroshi Ozawa ,  Nobuki Kobayashi ,  Teruo Honda

发明人： Kuniomi Hirota ,  Akio Masumoto ,  Hiroshi Ozawa ,  Nobuki Kobayashi ,  Teruo Honda

IPC分类号： C08F2/20 ,  C08F220/12 ,  C08F220/32 ,  C08L33/06 ,  C09D133/06 ,  C08F6/00 ,  C08L33/04

CPC分类号： C09D133/068 ,  C08F220/12 ,  C08F220/32 ,  C08L33/064 ,  Y10T428/31699

摘要： Solid copolymers are produced by copolymerizing a mixture of: (A) at least 30% by weight of a monomer having the formula: ##STR1## wherein R.sub.1 is H or CH.sub.3 and R.sub.2 is an alkyl radical containing from 1 to 14 carbon atoms; (B) from 3 to 20% by weight of an ethylenic .alpha., .beta. unsaturated carboxylic acid or anhydride thereof, or from 3 to 40% by weight of glycidyl acrylate or glycidyl methacrylate; and (C) from 0 to 67% by weight of a monomer copolymerizable with said monomers (A) and (B). Preferably, the mixture is first bulk-polymerized until conversion to the copolymer is from 10 to 80% by weight and the polymerization is completed by suspension-polymerization. Thermosetting solid coating compositions are produced by mixing a major proportion of a solid copolymer so produced with a minor proportion of a cross-linking compound or with an epoxy resin containing at least 2 epoxy radicals in the molecule in presence of a tertiary amine curing accelerator.

摘要翻译： 通过共聚以下混合物制备固体共聚物：（A）至少30重量％的具有下式的单体：其中R 1是H或CH 3，R 2是含有1至14个碳原子的烷基; （B）3至20重量％的烯属α，β不饱和羧酸或其酸酐，或3至40重量％的丙烯酸缩水甘油酯或甲基丙烯酸缩水甘油酯; 和（C）0〜67重量％的可与所述单体（A）和（B）共聚的单体。 优选地，首先将混合物本体聚合直至共聚物的转化率为10至80重量％，并通过悬浮聚合完成聚合。 热固性固体涂料组合物通过在叔胺固化促进剂的存在下，将大部分如此制备的固体共聚物与少量交联化合物或含有至少2个环氧基团的环氧树脂混合而制备。

公开(公告)号：US3954898A

公开(公告)日：1976-05-04

申请号：US318833

申请日：1972-12-27

申请人： Kuniomi Hirota ,  Akio Masumoto ,  Hiroshi Ozawa ,  Nobuki Kobayashi ,  Teruo Honda

发明人： Kuniomi Hirota ,  Akio Masumoto ,  Hiroshi Ozawa ,  Nobuki Kobayashi ,  Teruo Honda

IPC分类号： C08F220/12 ,  C08F220/32 ,  C08L33/06 ,  C09D5/46 ,  C09D133/06 ,  C08L63/00

CPC分类号： C09D133/068 ,  C08F220/12 ,  C08F220/32 ,  C08L33/064 ,  Y10S525/934

摘要： Solid copolymers are produced by copolymerizing a mixture of: (A) at least 30% by weight of a monomer having the formula: ##EQU1## wherein R.sub.1 is H or CH.sub.3 and R.sub.2 is an alkyl radical containing from 1 to 14 carbon atoms; (B) from 3 to 20% by weight of an ethylenic .alpha., .beta. unsaturated carboxylic acid or anhydride thereof, or from 3 to 40% by weight of glycidyl acrylate or glycidyl methacrylate; and (C) from 0 to 67% by weight of a monomer copolymerizable with said monomers (A) and (B). Preferably, the mixture is first bulk-polymerized until conversion to the copolymer is from 10% to 80% by weight and the polymerization is completed by suspension-polymerization. Thermosetting solid coating compositions are produced by mixing and melting 60 to 95 parts by weight of the solid copolymer and 40 to 5 parts by weight of a cross-linking compound or of an epoxy resin containing at least 2 epoxy radicals in the molecule in presence of a tertiary amine curing accelerator.

摘要翻译： 通过共聚以下混合物制备固体共聚物：（A）至少30重量％的具有下式的单体：R 1 CH 2 = C ANGLE COOR 2，其中R 1是H或CH 3，R 2是含有1至14个碳原子的烷基 原子 （B）3至20重量％的烯属α，β不饱和羧酸或其酸酐，或3至40重量％的丙烯酸缩水甘油酯或甲基丙烯酸缩水甘油酯; 和（C）0〜67重量％的可与所述单体（A）和（B）共聚的单体。 优选地，混合物首先被体积聚合，直到转化为共聚物为10重量％至80重量％，聚合通过悬浮聚合完成。 通过将60至95重量份的固体共聚物和40至5重量份的交联化合物或在分子中含有至少2个环氧基的环氧树脂混合并熔化而制备热固性固体涂料组合物， 叔胺固化促进剂。

公开(公告)号：US4048136A

公开(公告)日：1977-09-13

申请号：US621518

申请日：1975-10-10

申请人： Sadao Kobayashi ,  Hiroshi Ozawa ,  Nobuki Kobayashi

发明人： Sadao Kobayashi ,  Hiroshi Ozawa ,  Nobuki Kobayashi

IPC分类号： C09C1/62 ,  C09D5/10 ,  C09D201/00 ,  C08K9/04 ,  C08K9/10

CPC分类号： C09D5/10 ,  C09C1/62 ,  C09D201/00 ,  C01P2004/10 ,  C01P2004/12 ,  C01P2004/32 ,  C01P2004/50

摘要： A metallic tone powder coating composition of acrylic resin series which prises a polymer-capsulated metal powder composite material wherein a vinyl monomer is chemically combined with a powder of a metal such as aluminum and a copolymer having a glass transition temperature of at least 20.degree. C wherein the sum of an acrylic ester and a methacrylic ester is at least 30% by weight of the total monomer constituting the copolymer. This powder coating composition provides a coating film having excellent weather-resistance and beautiful appearance and is suited for use in electrostatic powder spraying.

摘要翻译： 丙烯酸树脂系列的金属色调粉末涂料组合物，其包含聚合物包覆的金属粉末复合材料，其中乙烯基单体与金属如铝的粉末和玻璃化转变温度为至少20℃的共聚物化学结合 其中丙烯酸酯和甲基丙烯酸酯的总和为构成共聚物的总单体的至少30重量％。 该粉末涂料组合物提供了具有优异的耐候性和美观的涂膜，适用于静电粉末喷涂。

公开(公告)号：US06804952B2

公开(公告)日：2004-10-19

申请号：US10369629

申请日：2003-02-21

申请人： Shizuo Sasaki ,  Kouji Yoshizaki ,  Nobuki Kobayashi ,  Yoshiki Hashimoto

发明人： Shizuo Sasaki ,  Kouji Yoshizaki ,  Nobuki Kobayashi ,  Yoshiki Hashimoto

IPC分类号： F01N300

CPC分类号： F02D41/0057 ,  F02D41/0255 ,  F02D41/3035 ,  F02D41/3076 ,  F02D2200/0802 ,  F02P19/026 ,  Y02T10/26 ,  Y02T10/47

摘要： Diesel engine is operated in a first warm-up mode in an early warm-up period after startup so as to accelerate activation of the catalyst, and then in a second warm-up mode in a late warm-up period after the early warm-up period so as to maintain activity of the catalyst. The first warm-up mode provides more energy to the catalyst with exhaust gases than the normal operation mode of the diesel engine. The second warm-up mode provides exhaust gases of higher temperature to the catalyst than the normal operation mode.

摘要翻译： 柴油发动机在启动后的早期预热期间以第一预热模式运行，以加速催化剂的活化，然后在早期预热后的预热期间的第二预热模式中， 以保持催化剂的活性。 第一个预热模式为催化剂提供比柴油发动机的正常运行模式更多的能量。 第二预热模式提供比正常操作模式更高温度的催化剂废气。

公开(公告)号：US20050229903A1

公开(公告)日：2005-10-20

申请号：US10527232

申请日：2003-09-08

申请人： Nobuki Kobayashi ,  Shizuo Sasaki ,  Taro Aoyama ,  Kouji Yoshizaki ,  Hiroki Murata ,  Yoshiki Hashimoto ,  Kazuhisa Inagaki ,  Kiyomi Nakakita ,  Shoji Nakahara ,  Yoshihiro Hotta

发明人： Nobuki Kobayashi ,  Shizuo Sasaki ,  Taro Aoyama ,  Kouji Yoshizaki ,  Hiroki Murata ,  Yoshiki Hashimoto ,  Kazuhisa Inagaki ,  Kiyomi Nakakita ,  Shoji Nakahara ,  Yoshihiro Hotta

IPC分类号： F02B3/06 ,  F02D21/08 ,  F02D35/02 ,  F02D41/00 ,  F02D41/30 ,  F02D41/38 ,  F02D41/40 ,  F02M7/00 ,  F02M25/07

CPC分类号： F02D41/0052 ,  F02B3/06 ,  F02D35/023 ,  F02D35/028 ,  F02D41/3035 ,  F02D41/3064 ,  F02D41/38 ,  F02D41/3809 ,  F02D41/402 ,  Y02T10/128 ,  Y02T10/44 ,  Y02T10/47

摘要： Cylinders of a diesel engine 1 are provided with cylinder pressure sensors 29a to 29d for detecting combustion chamber pressures. An electronic control unit (ECU) 20 of the engine selects optimum combustion parameters in accordance with a fuel injection mode of fuel injectors 10a to 10d of the engine and a combustion mode determined by the amount of EGR gas supplied from the EGR valve 35 from among a plurality of types of combustion parameters expressing the combustion state of the engine calculated based on the cylinder pressure sensor output and feedback controls the fuel injection amount and fuel injection timing so that the values of the combustion parameters match target values determined in accordance with the engine operating conditions. Due to this, the engine combustion state is controlled to the optimum state at all times regardless of the fuel injection mode or combustion mode.

摘要翻译： 柴油发动机1的气缸设置有用于检测燃烧室压力的气缸压力传感器29a至29d。 发动机的电子控制单元（ECU）20根据发动机的燃料喷射器10 a至10 d的燃料喷射模式选择最佳燃烧参数，以及由从EGR阀35供给的EGR气体量确定的燃烧模式 从表示基于气缸压力传感器输出计算出的发动机的燃烧状态的多种燃烧参数中，从燃料喷射量和燃料喷射正时控制燃烧参数的值符合根据 发动机工作条件。 由此，无论燃料喷射模式或燃烧模式如何，始终将发动机燃烧状态始终控制在最佳状态。

公开(公告)号：US4545031A

公开(公告)日：1985-10-01

申请号：US417282

申请日：1982-09-13

申请人： Nobuki Kobayashi

发明人： Nobuki Kobayashi

IPC分类号： B41F33/00 ,  G07D7/12 ,  G06F15/20

CPC分类号： G07D7/12 ,  B41F33/0036

摘要： An apparatus for monitoring automatically plural sheets of printed papers, includes a plurality of photosensors placed across the printed papers' moving direction for scanning and detecting a printed surface of each printed paper to produce analog signals designating dark levels of the printed surface thereof when each of the printed papers is being transferred, an AD converter for converting the analog signals into digital signals at a plurality of sampling points, a standard memory for storing such digital signals, a plurality of monitoring memories for storing such digital signals, circuitry for comparing the digital signals of the standard memory with the digital signals of the monitoring memories at the corresponding sampling points to decide whether or not the digital signals of the monitoring memories are within a tolerance range of the digital signals of the standard memory so that either "NO" signals or "YES" signals are produced, circuitry for counting only such "NO" signals to produce an "irregular" or "non-identity" signal when the number of such "NO" signals sums to a predetermined value, and circuitry for electrically compensating shifting of the papers when the digital signals of the standard memory are compared with the digital signals of the monitoring memories.

摘要翻译： 一种用于自动监测多张打印纸张的装置，包括放置在打印纸移动方向上的多个光电传感器，用于扫描和检测每个打印纸的打印表面，以产生模拟信号，当模拟信号指示其印刷表面的黑暗层级时 打印的纸张被传送，用于将模拟信号转换成多个采样点的数字信号的AD转换器，用于存储这种数字信号的标准存储器，用于存储这种数字信号的多个监视存储器，用于比较数字信号的电路 标准存储器的信号与相应采样点处的监视存储器的数字信号相关联，以确定监视存储器的数字信号是否在标准存储器的数字信号的容差范围内，使得“否”信号 或“是”信号，仅用于仅计数这种“否”信号的电路 当这种“否”信号的数量与预定值相加时，产生“不规则”或“非标识”信号，并且当将标准存储器的数字信号与数字 监视存储器的信号。