公开(公告)号：US07728103B2

公开(公告)日：2010-06-01

申请号：US12533024

申请日：2009-07-31

申请人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

发明人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

IPC分类号： C08G63/06

CPC分类号： C07C217/90 ,  C08G73/1039

摘要： Polymer compounds obtained by polymerization of a fluorine-containing polymerizable monomer represented by the formula [1] in which A represents a single bond, oxygen atom, sulfur atom, CO, CH2, SO, SO2, C(CH3)2, NHCO, C(CF3)2, phenyl, or aliphatic ring; “a” and “b” each independently represent an integer of 0-2, and 1≦a+b≦4. This fluorine-containing polymerizable monomer can be used as an effective polymerizable monomer, which can exhibit water repellency, oil repellency, low water absorptive property, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index property, low dielectric property, etc., and can be used for advanced polymer material fields.

摘要翻译： A表示单键，氧原子，硫原子，CO，CH 2，SO，SO 2，C（CH 3）2，NHCO，C的式[1]表示的含氟聚合性单体聚合得到的高分子化合物 （CF 3）2，苯基或脂族环; “a”和“b”各自独立地表示0-2的整数，1＆nlE; a + b＆nlE; 4。 该含氟聚合性单体可以用作有效的可聚合单体，其可以具有防水性，拒油性，低吸水性，耐热性，耐候性，耐腐蚀性，透明性，光敏性，低折射率性，低介电性 等，可用于高级聚合物材料领域。

公开(公告)号：US07932348B2

公开(公告)日：2011-04-26

申请号：US12787894

申请日：2010-05-26

申请人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

发明人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

IPC分类号： C08G73/24

CPC分类号： C07C215/68 ,  C08G69/26 ,  C08G73/06 ,  C08G73/1039

摘要： Polymers made by polymerization or cyclization condensation of a fluorine-containing polymerizable monomer represented by the formula [1] wherein “a” represents an integer from 1 to 4. The monomer contains a plurality of polymerizable amines in the molecule and at the same time one or more hexafluoroisopropyl group(s). With this structure it can be used as an effective polymerizable monomer, which can exhibit water repellency, oil repellency, low water absorptive property, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index property, low dielectric property, etc., and it can be used for advanced polymer material fields.

摘要翻译： 通过由式[1]表示的含氟可聚合单体的聚合或环化缩合制备的聚合物，其中“a”表示1至4的整数。该单体在分子中含有多个可聚合胺，同时一个 或更多的六氟异丙基。 具有这种结构，可以用作有效的可聚合单体，其具有防水性，拒油性，低吸水性，耐热性，耐候性，耐腐蚀性，透明性，光敏性，低折射率性，低介电性等。 ，可用于高级聚合物材料领域。

公开(公告)号：US07825280B2

公开(公告)日：2010-11-02

申请号：US10586183

申请日：2005-10-17

申请人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

发明人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

IPC分类号： C07C211/00

CPC分类号： C07C215/68 ,  C08G69/26 ,  C08G73/06 ,  C08G73/1039

摘要： The present invention relates to a fluorine-containing polymerizable monomer represented by the formula [1],[Chem. 31] wherein “a” represents an integer of 1-4. This monomer has a plurality of polymerizable amines in the molecule and at the same time a hexafluoroisopropyl group(s). With this, it can be used as an effective polymerizable monomer, which can exhibit water repellency, oil repellency, low water absorptive property, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index property, low dielectric property, etc., and can be used for advanced polymer material fields.

摘要翻译： 本发明涉及由式[1]表示的含氟可聚合单体，[Chem。 31]其中“a”表示1-4的整数。 该单体在分子中具有多个可聚合的胺，同时具有六氟异丙基。 由此可以将其用作有效的聚合性单体，其具有防水性，拒油性，低吸水性，耐热性，耐候性，耐腐蚀性，透明性，光敏性，低折射率性，低介电性等。 可用于高级材料领域。

公开(公告)号：US20100234556A1

公开(公告)日：2010-09-16

申请号：US12787894

申请日：2010-05-26

申请人： Hiroshi SAEGUSA ,  Satoru Narizuka ,  Kazuhiko Maeda

发明人： Hiroshi SAEGUSA ,  Satoru Narizuka ,  Kazuhiko Maeda

IPC分类号： C08G69/08 ,  C08G73/02

CPC分类号： C07C215/68 ,  C08G69/26 ,  C08G73/06 ,  C08G73/1039

摘要： Polymers made by polymerization or cyclization condensation of a fluorine-containing polymerizable monomer represented by the formula [1] wherein “a” represents an integer from 1 to 4. The monomer contains a plurality of polymerizable amines in the molecule and at the same time one or more hexafluoroisopropyl group(s). With this structure it can be used as an effective polymerizable monomer, which can exhibit water repellency, oil repellency, low water absorptive property, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index property, low dielectric property, etc., and it can be used for advanced polymer material fields.

摘要翻译： 通过由式[1]表示的含氟可聚合单体的聚合或环化缩合制备的聚合物，其中“a”表示1至4的整数。该单体在分子中含有多个可聚合胺，同时一个 或更多的六氟异丙基。 具有这种结构，可以用作有效的可聚合单体，其具有防水性，拒油性，低吸水性，耐热性，耐候性，耐腐蚀性，透明性，光敏性，低折射率性，低介电性等。 ，可用于高级聚合物材料领域。

公开(公告)号：US20090023886A1

公开(公告)日：2009-01-22

申请号：US10586183

申请日：2005-10-17

申请人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

发明人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

IPC分类号： C08G69/42 ,  C07C211/51 ,  C08G73/10 ,  C08G73/02

CPC分类号： C07C215/68 ,  C08G69/26 ,  C08G73/06 ,  C08G73/1039

摘要： Disclosed is a fluorine-containing polymerizable monomer represented by the formula [1] below. (In the formula [1], a represents an integer of 1-4.) By having a plurality of polymerizable amines in a molecule while containing a hexafluoroisopropyl group, this fluorine-containing polymerizable monomer exhibiting water repellancy, oil repellency, low water absorbency, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric properties, and the like, and thus can be applied to the field of advanced polymer materials.

摘要翻译： 公开了下述式[1]表示的含氟聚合性单体。 （式[1]中，a表示1-4的整数。）通过在含有六氟异丙基的分子中具有多个聚合性胺，该含氟聚合性单体具有防水性，拒油性，低吸水性 耐热性，耐候性，耐腐蚀性，透明性，光敏性，低折射率，低介电特性等，因此可以应用于先进的聚合物材料领域。

公开(公告)号：US07629434B2

公开(公告)日：2009-12-08

申请号：US10586184

申请日：2005-10-13

申请人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

发明人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

IPC分类号： C08G63/06

CPC分类号： C07C217/90 ,  C08G73/1039

摘要： Disclosed is a fluorine-containing polymerizable monomer represented by the formula [1] below. (In the formula, A represents a single bond, an oxygen atom, a sulfur atom, CO, CH2, SO, SO2, C(CH3)2, NHCO, C(CF3)2, a phenyl or an alicyclic ring; a and b independently represent an integer of 0-2; and 1≦a+b≦4.) Such a fluorine-containing polymerizable monomer can be used as an effective polymerizable monomer exhibiting water repellency, oil repellency, low water absorbency, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric properties and the like. Consequently, the fluorine-containing polymerizable monomer can be applied to the field of advanced polymer materials.

摘要翻译： 公开了下述式[1]表示的含氟聚合性单体。 （式中，A表示单键，氧原子，硫原子，CO，CH2，SO，SO2，C（CH3）2，NHCO，C（CF3）2，苯基或脂环族环; b独立地表示0-2的整数，1 <= a + b <= 4）。这样的含氟聚合性单体可以用作显示疏水性，拒油性，低吸水性，耐热性的有效的聚合性单体 耐候性，耐腐蚀性，透明性，光敏性，低折射率，低介电性等。 因此，含氟聚合性单体可以应用于高分子材料领域。

公开(公告)号：US20090292104A1

公开(公告)日：2009-11-26

申请号：US12533024

申请日：2009-07-31

申请人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

发明人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

IPC分类号： C08G69/08 ,  C08G73/02

CPC分类号： C07C217/90 ,  C08G73/1039

摘要： Polymer compounds obtained by polymerization of a fluorine-containing polymerizable monomer represented by the formula [1] in which A represents a single bond, oxygen atom, sulfur atom, CO, CH2, SO, SO2, C(CH3)2, NHCO, C(CF3)2, phenyl, or aliphatic ring; “a” and “b” each independently represent an integer of 0-2, and 1≦a+b≦4. This fluorine-containing polymerizable monomer can be used as an effective polymerizable monomer, which can exhibit water repellency, oil repellency, low water absorptive property, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index property, low dielectric property, etc., and can be used for advanced polymer material fields.

摘要翻译： A表示单键，氧原子，硫原子，CO，CH 2，SO，SO 2，C（CH 3）2，NHCO，C的式[1]表示的含氟聚合性单体聚合得到的高分子化合物 （CF 3）2，苯基或脂族环; “a”和“b”各自独立地表示0-2的整数，1 <= a + b <= 4。 该含氟聚合性单体可以用作有效的可聚合单体，其可以具有防水性，拒油性，低吸水性，耐热性，耐候性，耐腐蚀性，透明性，光敏性，低折射率性，低介电性 等，可用于高级聚合物材料领域。

公开(公告)号：US20080234460A1

公开(公告)日：2008-09-25

申请号：US10586184

申请日：2005-10-13

申请人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

发明人： Hiroshi Saegusa ,  Satoru Narizuka ,  Kazuhiko Maeda

IPC分类号： C08G63/06 ,  C07C211/56

CPC分类号： C07C217/90 ,  C08G73/1039

摘要： Disclosed is a fluorine-containing polymerizable monomer represented by the formula [1] below. (In the formula, A represents a single bond, an oxygen atom, a sulfur atom, CO, CH2, SO, SO2, C(CH3)2, NHCO, C(CF3)2, a phenyl or an alicyclic ring; a and b independently represent an integer of 0-2; and 1≦a+b≦4.) Such a fluorine-containing polymerizable monomer can be used as an effective polymerizable monomer exhibiting water repellency, oil repellency, low water absorbency, heat re-sistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric properties and the like. Consequently, the fluorine-containing polymeriz-able monomer can be applied to the field of advanced polymer materials.

摘要翻译： 公开了下述式[1]表示的含氟聚合性单体。 （式中，A表示单键，氧原子，硫原子，CO，CH 2，SO，SO 2，C（CH 3） 2，NCO 2，C（CF 3）2，苯基或脂环族环; a和b独立地表示 可以使用这样的含氟聚合性单体作为具有防水性，拒油性，低吸水性，耐热性，耐候性的有效的聚合性单体 电阻，耐腐蚀性，透明性，光敏性，低折射率，低介电性等。 因此，含氟可聚合单体可以应用于先进的聚合物材料领域。

公开(公告)号：US20120064459A1

公开(公告)日：2012-03-15

申请号：US13320871

申请日：2010-05-14

申请人： Kazuhiko Maeda ,  Takamasa Kitamoto ,  Haruhiko Komoriya ,  Satoru Narizuka ,  Yoshimi Isono ,  Kazunori Mori

发明人： Kazuhiko Maeda ,  Takamasa Kitamoto ,  Haruhiko Komoriya ,  Satoru Narizuka ,  Yoshimi Isono ,  Kazunori Mori

IPC分类号： G03F7/039 ,  C08F20/22 ,  G03F7/38

CPC分类号： G03F7/20 ,  C08F20/26 ,  G03F7/0046 ,  G03F7/0397 ,  G03F7/2041

摘要： Disclosed is a water repellent additive for an immersion resist, which is composed of a fluorine-containing polymer that has a repeating unit represented by general formula (1). By adding the water repellent additive to a resist composition, the resist composition can be controlled to have high water repellency during exposure and to exhibit improved solubility in a developing solution during development. [In the formula, R1 represents a hydrogen atom, a fluorine atom, a methyl group or a trifluoromethyl group; R2 represents a heat-labile protecting group; R3 represents a fluorine atom or a fluorine-containing alkyl group; and W represents a divalent linking group.]

摘要翻译： 公开了一种浸渍抗蚀剂的防水添加剂，其由具有由通式（1）表示的重复单元的含氟聚合物组成。 通过将防水添加剂添加到抗蚀剂组合物中，可以将抗蚀剂组合物控制为在曝光期间具有高的拒水性，并且在显影期间在显影液中表现出改善的溶解性。 [式中，R 1表示氢原子，氟原子，甲基或三氟甲基。 R2代表热不稳定保护基; R3表示氟原子或含氟烷基; W表示二价连接基。]

公开(公告)号：US08663903B2

公开(公告)日：2014-03-04

申请号：US13264285

申请日：2010-04-20

申请人： Kazuhiko Maeda ,  Takamasa Kitamoto ,  Haruhiko Komoriya ,  Satoru Narizuka ,  Yoshimi Isono ,  Kazunori Mori

发明人： Kazuhiko Maeda ,  Takamasa Kitamoto ,  Haruhiko Komoriya ,  Satoru Narizuka ,  Yoshimi Isono ,  Kazunori Mori

IPC分类号： G03F7/11 ,  C08F20/22

CPC分类号： C08F20/22 ,  G03F7/11 ,  G03F7/2041

摘要： Disclosed is a top coating composition formed on a resist film, for protecting the resist film, the top coating composition being a top coating composition for photoresist, characterized by containing a fluorine-containing polymer having a repeating unit represented by the following general formula (1). This composition is capable of controlling developing solution solubility and has a high water repellency. [In the formula, R1 represents a hydrogen atom, fluorine atom, methyl group or trifluoromethyl group, R2 represents a heat-labile protecting group, R3 represents a fluorine atom or fluorine-containing alkyl group, and W is a bivalent linking group.]

摘要翻译： 公开了一种形成在抗蚀剂膜上的用于保护抗蚀剂膜的顶部涂料组合物，该顶部涂料组合物是用于光致抗蚀剂的顶部涂料组合物，其特征在于含有具有由以下通式（1）表示的重复单元的含氟聚合物 ）。 该组合物能够控制显影溶液的溶解度并具有高斥水性。 [式中，R1表示氢原子，氟原子，甲基或三氟甲基，R2表示热不稳定保护基，R3表示氟原子或含氟烷基，W表示二价连接基。