公开(公告)号：US20080075686A1

公开(公告)日：2008-03-27

申请号：US11879205

申请日：2007-07-16

申请人： Hiroyuki Fujii ,  Yoko Yamada ,  Mitsuyoshi Kanno

发明人： Hiroyuki Fujii ,  Yoko Yamada ,  Mitsuyoshi Kanno

IPC分类号： B01D11/00

CPC分类号： A61L9/01 ,  A43B1/0045 ,  A43B7/00 ,  A61L9/14 ,  D06M13/12 ,  D06M13/256

摘要： A deodorizer is disclosed which is superior both in odor elimination effect eliminating an already existing odor and in odor prevention effect preventing odor occurrence, without leaving a colored trace on an application site. The deodorizer of the present invention comprises a salt of copper (II) ion and/or zinc ion; at least one acid component selected from the group consisting of alkylsulfonic acids having 1 to 6 carbon atoms, arylsulfonic acids having 5 to 14 carbon atoms, amidosulfuric acids, and derivatives thereof; and water being a solvent. The acid component may be substituted by at least one selected from the group consisting of amine groups, imine groups, and hydroxyl group. The deodorizer comprises the salt in an amount of more than 0.001 mM and less than 10 mM.

摘要翻译： 公开了一种除臭效果，除去已经存在的气味和防止气味发生的防止气味的除臭效果，而不会在施用部位留下有色痕迹。 本发明的除臭剂包括铜（II）离子和/或锌离子的盐; 至少一种选自碳原子数1〜6的烷基磺酸，碳原子数5〜14的芳基磺酸，酰氨基磺酸及其衍生物的酸成分; 水为溶剂。 酸组分可以被选自胺基，亚胺基和羟基中的至少一种取代。 除臭剂包含大于0.001mM且小于10mM的盐。

公开(公告)号：US20080004195A1

公开(公告)日：2008-01-03

申请号：US11732716

申请日：2007-04-04

申请人： Hiroyuki Fujii ,  Satoru Kitazaki ,  Chikara Endo ,  Mitsuyoshi Kanno

发明人： Hiroyuki Fujii ,  Satoru Kitazaki ,  Chikara Endo ,  Mitsuyoshi Kanno

IPC分类号： C11D3/37

CPC分类号： C09D5/1668 ,  C08K3/28 ,  C08K5/09 ,  C09D129/04

摘要： The present invention provides a gradually soluble coating film to be applied to instruments for waterworks. In a conventional polyvinyl alcohol solution not containing metal salt, there is formed a coating film in which polyvinyl alcohol molecules are piled up as shown in FIG. 2(a). In such coating film, water contacting with a surface thereof penetrates rapidly to the interface between the coating film and a base material, so that when water flows away, the coating film flows out and vanishes completely. On the other hand, in a coating film of the present invention, there are formed polyvinyl alcohol inclusion metal hydroxide clusters derived from the kind of metal in the solution as shown in FIG. 2(b). Although polyvinyl alcohol is dissolved or swollen to allow water to penetrate therein when water contacts with the coating film surface, the penetration speed of water in the direction of film thickness is controlled since the metal hydroxide clusters exist in the film. Therefore, when water flows away, only the film in a water penetrated portion in the vicinity of the coating film surface flows and the entire coating film does not vanish at one time.

摘要翻译： 本发明提供一种适用于水厂设备的逐渐溶解的涂膜。 在不含金属盐的常规聚乙烯醇溶液中，形成如图1所示的聚乙烯醇分子堆积的涂膜。 2（a）。 在这种涂膜中，与其表面接触的水迅速渗透到涂膜和基材之间的界面，使得当水流出时，涂膜流出并完全消失。 另一方面，在本发明的涂膜中，如图1所示，在溶液中形成衍生自金属种类的聚乙烯醇夹杂金属氢氧化物簇。 2（b）。 虽然当水与涂膜表面接触时，聚乙烯醇溶解或溶胀以允许水渗入其中，但是由于金属氢氧化物簇存在于膜中，因此控制水在膜厚度方向上的渗透速度。 因此，当水流走时，只有在涂膜表面附近的水中渗透部分的膜流动，并且整个涂膜一次不会消失。

公开(公告)号：US08216959B2

公开(公告)日：2012-07-10

申请号：US13034336

申请日：2011-02-24

申请人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

发明人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

IPC分类号： B01J31/06

CPC分类号： B01J35/004 ,  B01J21/063 ,  B01J37/0009 ,  B01J37/0217 ,  B01J37/0219 ,  B01J37/0244 ,  C03C17/007 ,  C03C17/008 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/477 ,  C03C2217/478 ,  C03C2217/48 ,  C03C2217/71 ,  C08K3/22 ,  C09D1/00 ,  C09D7/61 ,  C09D7/67 ,  C09D183/04

摘要： A photocatalyst-coated body includes a substrate with an organic material as a surface thereof, a photocatalyst layer with interstices between the particles in the layer and an intermediate layer provided between the substrate and the photocatalyst layer. The photocatalyst layer includes photocatalyst particles in a range of 1 part≦x

摘要翻译： 光催化剂涂覆体包括具有有机材料作为其表面的基材，在该层中的颗粒之间具有间隙的光催化剂层和设置在该基材和该光催化剂层之间的中间层。 光催化剂层包括1份＆lt; NlE; x <20质量份的光催化剂颗粒，70质量％以下的无机氧化物粒子，y <99质量份，可水解硅氧烷的干燥物质为0 只要光催化剂颗粒，无机氧化物颗粒和可水解硅氧烷的干燥物质的总量相对于二氧化硅为100质量份，z <10质量份即可。 包含硅氧烷改性树脂的中间层，其中硅氧烷改性树脂包含0.2质量％以上且小于16.5质量％的硅原子。

公开(公告)号：US20080254975A1

公开(公告)日：2008-10-16

申请号：US12079417

申请日：2008-03-26

申请人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

发明人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

IPC分类号： B01J21/06

CPC分类号： C09D1/00 ,  B01J35/004 ,  B01J37/0009 ,  B01J37/0219 ,  C03C17/007 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/477 ,  C03C2217/478 ,  C03C2217/48 ,  C03C2217/71 ,  C08K3/22 ,  C09D7/61 ,  C09D7/67 ,  C09D183/04

摘要： There is disclosed a photocatalyst-coated body which is superior in weather resistance, noxious gas decomposability, and various coating properties (such as ultraviolet absorptivity, transparency and film strength) while preventing corrosion of a substrate (in particular an organic substrate), and a photocatalyst coating liquid therefor. The photocatalyst-coated body comprises a substrate and a photocatalyst layer provided on the substrate. The photocatalyst layer comprises photocatalyst particles of 1 part or more by mass and less than 20 parts by mass; inorganic oxide particles of 70 parts or more by mass and less than 99 parts by mass; and a hydrolyzable silicone of zero parts or more by mass and less than 10 parts by mass, provided that a total amount of the photocatalyst particles, the inorganic oxide particles and the hydrolyzable silicone is 100 parts by mass.

摘要翻译： 公开了一种防止基板（特别是有机基板）的腐蚀的耐候性，有害气体分解性和各种涂布性（例如紫外线吸收率，透明性和膜强度）的光催化剂涂布体， 光催化剂涂布液体。 光催化剂涂覆体包括基材和设置在基材上的光催化剂层。 光催化剂层包含1质量％以上且小于20质量份的光催化剂粒子， 无机氧化物粒子为70质量份以上且小于99质量份; 以及零质量以上且小于10质量份的可水解硅氧烷，只要光催化剂颗粒，无机氧化物颗粒和可水解硅氧烷的总量为100质量份即可。

公开(公告)号：US20090286673A1

公开(公告)日：2009-11-19

申请号：US12383840

申请日：2009-03-27

申请人： Koji Omoshiki ,  Junji Kameshima ,  Yoji Takaki ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

发明人： Koji Omoshiki ,  Junji Kameshima ,  Yoji Takaki ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

IPC分类号： B01J31/06 ,  B01J21/08 ,  B01J21/06

CPC分类号： B01J35/004 ,  B01J21/063 ,  B01J37/0009 ,  B01J37/0217 ,  B01J37/0219 ,  B01J37/0244 ,  C03C17/007 ,  C03C17/008 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/477 ,  C03C2217/478 ,  C03C2217/48 ,  C03C2217/71 ,  C08K3/22 ,  C09D1/00 ,  C09D7/61 ,  C09D7/67 ,  C09D183/04

摘要： A photocatalyst-coated body and a photocatalytic coating liquid which exert an excellent weather resistance, harmful gas decomposability, and other desired characteristics (such as transparency and film strength), while preventing erosion of the substrate are provided. The photocatalyst-coated body comprises a substrate and a photocatalytic layer provided on the substrate. The photocatalytic layer comprises photocatalytic particles and inorganic oxide particles, and has interstices between the particles in the layer.

摘要翻译： 提供光催化剂涂覆体和光催化涂布液，其在防止基材侵蚀的同时，具有优异的耐候性，有害的气体分解性和其它期望的特性（如透明度和膜强度）。 光催化剂涂覆体包括基材和设置在基材上的光催化层。 光催化层包含光催化颗粒和无机氧化物颗粒，并且在层中的颗粒之间具有间隙。

公开(公告)号：US06319390B1

公开(公告)日：2001-11-20

申请号：US08793630

申请日：1997-02-18

申请人： Shuhei Kono ,  Nobuhiro Shono ,  Kenji Tabata ,  Masakatsu Kiyohara ,  Makoto Hayakawa ,  Mitsuyoshi Kanno ,  Nobuhiko Kanekuni

发明人： Shuhei Kono ,  Nobuhiro Shono ,  Kenji Tabata ,  Masakatsu Kiyohara ,  Makoto Hayakawa ,  Mitsuyoshi Kanno ,  Nobuhiko Kanekuni

IPC分类号： C02F1461

CPC分类号： C11D3/3953 ,  A61L2/035 ,  C02F1/32 ,  C02F1/46104 ,  C02F1/4672 ,  C02F1/4674 ,  C02F1/50 ,  C02F1/78 ,  C02F2001/46185 ,  C02F2201/46115 ,  C02F2201/4612 ,  C02F2201/46145 ,  C02F2201/4615 ,  C02F2209/42 ,  C02F2303/04 ,  C11D3/48 ,  C11D11/0023 ,  E03D9/00 ,  E03D9/005 ,  E03D9/02 ,  E03D13/00 ,  Y02W10/37

摘要： A method of and system for cleansing a toilet or urinal are proposed which require less maintenance work and are safer to users than conventional methods using acid substances, and which can prevent the formation of stain on the toilet or urinal effectively and suppress the generation of ammonia sufficiently, thus accomplishing a sufficient countermeasure to the stench. A urinal (A1) is provided with a continuous electrolytic cell (1) having at least a pair of electrodes, a passage formed between the electrodes, and an inlet and an outlet that lead to the passage. Tap water is electrolyzed by the continuous electrolytic cell (1), whereby free chlorine is produced. Then the water containing free chlorine produced is supplied to the urinal (A1), and the water containing free chlorine sterilizes the inside of the urinal, thus preventing urease, an enzyme carried by bacteria, from acting to decompose urea. By this method, the deposition of uric stone and the generation of the stain and stench are suppressed on the surface of the urinal and in the trap of the urinal.

摘要翻译： 提出了一种清洁厕所或小便器的方法和系统，其需要较少的维护工作，并且比使用酸性物质的常规方法更安全，并且可以有效地防止马桶或小便器上的污渍形成并抑制氨的产生 足以使臭气达到充分的对策。 小便器（A1）设置有具有至少一对电极，形成在电极之间的通道和导通通道的入口和出口的连续电解槽（1）。 自来水由连续电解池（1）电解，由此产生游离氯。 然后将含有游离氯的水供应到小便池（A1），含有游离氯的水对小便池内部灭菌，从而防止细菌携带的尿素脲酶分解尿素。 通过这种方法，在小便池的表面和小便器的陷阱中抑制尿石的沉积和污渍和恶臭的产生。

公开(公告)号：US6165256A

公开(公告)日：2000-12-26

申请号：US232494

申请日：1999-01-15

申请人： Makoto Hayakawa ,  Mitsuyoshi Kanno

发明人： Makoto Hayakawa ,  Mitsuyoshi Kanno

IPC分类号： B01J31/02 ,  B01J35/00 ,  B01J37/02 ,  C03C17/00 ,  C09D1/00 ,  C09D5/00 ,  C09D5/02 ,  C09D183/02 ,  C09D183/04 ,  C09K3/18 ,  F21V7/22

CPC分类号： C09D1/00 ,  B01J31/0272 ,  B01J35/004 ,  B01J37/0219 ,  C03C17/007 ,  C03C2217/45 ,  C03C2217/477 ,  C03C2217/478 ,  C03C2217/71 ,  C09D5/00 ,  C09D5/021 ,  C09D183/02 ,  C09D183/04 ,  C08L2666/54

摘要： A composition is disclosed which can hydrophilify the surface of a member to impart an antifogging property to the surface of the member. The composition for hydrophilifying the surface of the member comprises at least (a) photocatalytic particles of a metallic oxide, (b) a precursor capable of forming a silicone resin film or a precursor capable of forming a silica film, and (c) a solvent, the total content of the photocatalytic particle and the solid matter of the precursor in the composition being 0.01 to 5% by weight. The hydrophilic property can be imparted simply by applying the composition onto a member and drying or heating the composition applied to the member. The resultant hydrophilic thin film is transparent and, hence, does not sacrifice the transparency and appearance of a member required to be transparent. Further, the surface of a member with the above composition applied thereto has such a property that water droplets adhered thereon can be immediately removed by vaporization and the surface is less likely to be soiled and, even when a contaminant is adhered thereon, can easily release the contaminant therefrom.

摘要翻译： 公开了一种组合物，其可以使构件的表面亲水化以赋予该构件表面防雾性能。 用于使构件的表面亲水化的组合物至少包含（a）金属氧化物的光催化颗粒，（b）能够形成硅树脂膜的前体或能够形成二氧化硅膜的前体，和（c）溶剂 ，组合物中的光催化剂粒子和前体的固体成分的总含量为0.01〜5重量％。 可以简单地通过将组合物施用到构件上并干燥或加热施加到构件上的组合物来赋予亲水性。 所得的亲水性薄膜是透明的，因此不会牺牲要透明的构件的透明度和外观。 此外，具有上述组成的构件的表面具有这样的性质，即可以通过蒸发立即除去附着在其上的水滴，并且表面不太可能被弄脏，并且即使当污染物附着在其上时，也可以容易地释放 来自其的污染物。

公开(公告)号：US08207079B2

公开(公告)日：2012-06-26

申请号：US12965487

申请日：2010-12-10

申请人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

发明人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

IPC分类号： B01J31/06

CPC分类号： B01J35/004 ,  B01J21/063 ,  B01J37/0009 ,  B01J37/0217 ,  B01J37/0219 ,  B01J37/0244 ,  C03C17/007 ,  C03C17/008 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/477 ,  C03C2217/478 ,  C03C2217/48 ,  C03C2217/71 ,  C08K3/22 ,  C09D1/00 ,  C09D7/61 ,  C09D7/67 ,  C09D183/04

摘要： A photocatalyst-coated body comprises a substrate and a photocatalyst layer provided on the substrate, the photocatalyst layer comprising photocatalyst particles of 1 part or more by mass and less than 20 parts by mass, inorganic oxide particles of 70 parts or more by mass and less than 99 parts by mass, and the dried substance of a hydrolyzable silicone of zero parts or more by mass and less than 10 parts by mass, provided that a total amount of the photocatalyst particles, the dried substance of the inorganic oxide particles and the hydrolyzable silicone is 100 parts by mass in terms of silica, wherein the photocatalyst layer has a film thickness of 3.0 μm or less.

摘要翻译： 光催化剂涂覆体包括基材和设置在基材上的光催化剂层，所述光催化剂层包含1质量％以上且小于20质量份的光催化剂粒子，70质量份以上的无机氧化物粒子 99质量份以下的水分子性硅酮的干燥物质为零质量以上且小于10质量份的水解性硅酮的干燥物质，条件是光催化剂粒子，无机氧化物粒子的干燥物质和可水解的 硅氧烷以二氧化硅计为100质量份，其中光催化剂层的膜厚为3.0μm以下。

公开(公告)号：US07977270B2

公开(公告)日：2011-07-12

申请号：US12079417

申请日：2008-03-26

申请人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

发明人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

IPC分类号： B01J31/06

CPC分类号： C09D1/00 ,  B01J35/004 ,  B01J37/0009 ,  B01J37/0219 ,  C03C17/007 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/477 ,  C03C2217/478 ,  C03C2217/48 ,  C03C2217/71 ,  C08K3/22 ,  C09D7/61 ,  C09D7/67 ,  C09D183/04

摘要： There is disclosed a photocatalyst-coated body which is superior in weather resistance, noxious gas decomposability, and various coating properties (such as ultraviolet absorptivity, transparency and film strength) while preventing corrosion of a substrate (in particular an organic substrate), and a photocatalyst coating liquid therefor. The photocatalyst-coated body comprises a substrate and a photocatalyst layer provided on the substrate. The photocatalyst layer comprises photocatalyst particles of 1 part or more by mass and less than 20 parts by mass; inorganic oxide particles of 70 parts or more by mass and less than 99 parts by mass; and a hydrolyzable silicone of zero parts or more by mass and less than 10 parts by mass, provided that a total amount of the photocatalyst particles, the inorganic oxide particles and the hydrolyzable silicone is 100 parts by mass.

摘要翻译： 公开了一种防止基板（特别是有机基板）的腐蚀的耐候性，有害气体分解性和各种涂布性（例如紫外线吸收率，透明性和膜强度）的光催化剂涂布体， 光催化剂涂布液体。 光催化剂涂覆体包括基材和设置在基材上的光催化剂层。 光催化剂层包含1质量％以上且小于20质量份的光催化剂粒子， 无机氧化物粒子为70质量份以上且小于99质量份; 以及零质量以上且小于10质量份的可水解硅氧烷，只要光催化剂颗粒，无机氧化物颗粒和可水解硅氧烷的总量为100质量份即可。

公开(公告)号：US08372774B2

公开(公告)日：2013-02-12

申请号：US13396759

申请日：2012-02-15

申请人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

发明人： Satoru Kitazaki ,  Junji Kameshima ,  Koji Omoshiki ,  Yoji Takaki ,  Yuki Tanaka ,  Hironaga Iwata ,  Makoto Hayakawa ,  Mitsuyoshi Kanno

IPC分类号： B01J31/06

CPC分类号： B01J35/004 ,  B01J21/063 ,  B01J37/0009 ,  B01J37/0217 ,  B01J37/0219 ,  B01J37/0244 ,  C03C17/007 ,  C03C17/008 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/477 ,  C03C2217/478 ,  C03C2217/48 ,  C03C2217/71 ,  C08K3/22 ,  C09D1/00 ,  C09D7/61 ,  C09D7/67 ,  C09D183/04

摘要： A photocatalyst-coated body comprises a substrate and a photocatalyst layer provided on the substrate, the photocatalyst layer comprising photocatalyst particles of 1 part or more by mass and less than 20 parts by mass, inorganic oxide particles of 70 parts or more by mass and less than 99 parts by mass, and the dried substance of a hydrolyzable silicone of zero parts or more by mass and less than 10 parts by mass, provided that a total amount of the photocatalyst particles, the dried substance of the inorganic oxide particles and the hydrolyzable silicone is 100 parts by mass in terms of silica. The inorganic oxide particles have a number average particle diameter ranging from 10 nm or more to less than 40 nm calculated by measuring lengths of 100 particles randomly selected from particles located within a visible field magnified 200,000 times by a scanning electron microscope.

摘要翻译： 光催化剂涂覆体包括基材和设置在基材上的光催化剂层，所述光催化剂层包含1质量％以上且小于20质量份的光催化剂粒子，70质量份以上的无机氧化物粒子 99质量份以下的水分子性硅酮的干燥物质为零质量以上且小于10质量份的水解性硅酮的干燥物质，条件是光催化剂粒子，无机氧化物粒子的干燥物质和可水解的 硅氧烷以二氧化硅计为100质量份。 无机氧化物粒子的数均粒径在10nm以上且小于40nm的范围内，通过扫描电子显微镜测定从位于可见场内的粒子的粒子的100个粒子的长度测定的长度。