公开(公告)号：US06899974B2

公开(公告)日：2005-05-31

申请号：US09985272

申请日：2001-11-02

申请人： Hiroyuki Kamisuki ,  Toshihiko Nishiyama ,  Gaku Harada ,  Shinya Yoshida ,  Masato Kurosaki ,  Yuuji Nakagawa ,  Tomoki Nobuta ,  Masaya Mitani

发明人： Hiroyuki Kamisuki ,  Toshihiko Nishiyama ,  Gaku Harada ,  Shinya Yoshida ,  Masato Kurosaki ,  Yuuji Nakagawa ,  Tomoki Nobuta ,  Masaya Mitani

IPC分类号： H01M2/16 ,  H01M4/60 ,  H01M10/36

CPC分类号： H01M10/36 ,  H01M2/1653 ,  H01M4/60 ,  H01M4/602

摘要： A secondary battery of a proton conductive polymer, wherein a positive electrode 2 and a negative electrode 4 are arranged facing to each other via a separator in an electrolytic solution and only a proton in a π conjugated polymer or a proton of a hydroxyl group in a hydroxyl-containing macromolecular as an active material of an electrode in the positive and negative electrodes participates in a charge/discharge; the secondary battery uses a membrane, which has acid resistance, oxidation resistance and a functional group having cation exchange function, as the separator 3.

摘要翻译： 质子传导性聚合物的二次电池，其中正电极2和负电极4经电解液中的隔膜相互排列，仅在π共轭聚合物中的质子或羟基的质子 含羟基的大分子作为正极和负极中的电极的活性材料参与充电/放电; 二次电池使用具有耐酸性，抗氧化性的膜和具有阳离子交换功能的官能团作为隔膜3。

公开(公告)号：US07057880B2

公开(公告)日：2006-06-06

申请号：US10834005

申请日：2004-04-29

申请人： Masato Kurosaki ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Tomoki Nobuta ,  Masaya Mitani

发明人： Masato Kurosaki ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Tomoki Nobuta ,  Masaya Mitani

IPC分类号： H01G9/04 ,  H01G9/145

CPC分类号： H01G9/155 ,  H01G9/22 ,  H01G11/02 ,  H01G11/42 ,  H01M4/137 ,  H01M4/60 ,  H01M4/606 ,  H01M4/608 ,  H01M10/05 ,  H01M10/36 ,  Y02E60/13

摘要： The present invention provides a secondary battery and a capacitor which may provide an excellent high rate and cycle characteristic as well as sufficient electromotive force and capacity. The secondary battery and a capacitor have an active material of an electrode comprising a trimer compound comprising three units of indole or indole derivatives in condensed ring form, wherein the second position and the third position of each unit form a six-membered ring, and a proton which can be utilized as a charge carrier of the trimer compound.

公开(公告)号：US06800395B2

公开(公告)日：2004-10-05

申请号：US09986791

申请日：2001-11-13

申请人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Masaya Mitani

发明人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Masaya Mitani

IPC分类号： H01M460

CPC分类号： H01M4/608 ,  H01M4/137 ,  H01M4/60 ,  H01M4/62 ,  H01M4/622 ,  H01M10/36 ,  H01M2300/0005 ,  H01M2300/0011

摘要： A secondary battery of a proton conductive polymer, wherein a positive electrode and a negative electrode are arranged facing to each other via a separator in an electrolyte and only a proton or a proton of a hydroxyl group in an indole trimer and a &pgr; conjugated polymer, i.e., an active material of electrode in the positive electrode and in the negative electrode participates in a charge/discharge, and a proton concentration is 5 to 40% and an anion concentration is 30 to 60% in the solution, respectively, and the anion concentration is at least higher than the proton concentration.

摘要翻译： 质子传导性聚合物的二次电池，其中正电极和负极通过电解质中的隔膜彼此面对，并且仅吲哚三聚体中的羟基的质子或质子和π共轭聚合物， 即，正极和负极中的电极的活性物质分别参与充放电，溶液中的质子浓度为5〜40％，阴离子浓度为30〜60％，阴离子 浓度至少高于质子浓度。

公开(公告)号：US06749963B2

公开(公告)日：2004-06-15

申请号：US09942991

申请日：2001-08-31

申请人： Masato Kurosaki ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Tomoki Nobuta ,  Masaya Mitani

发明人： Masato Kurosaki ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Tomoki Nobuta ,  Masaya Mitani

IPC分类号： H01M460

CPC分类号： H01G9/155 ,  H01G9/22 ,  H01G11/02 ,  H01G11/42 ,  H01M4/137 ,  H01M4/60 ,  H01M4/606 ,  H01M4/608 ,  H01M10/05 ,  H01M10/36 ,  Y02E60/13

摘要： The present invention provides a secondary battery and a capacitor which may provide an excellent high rate and cycle characteristic as well as sufficient electromotive force and capacity. The secondary battery and a capacitor have an active material of an electrode comprising a trimer compound comprising three units of indole or indole derivatives in condensed ring form, wherein the second position and the third position of each unit form a six-membered ring, and a proton which can be utilized as a charge carrier of the trimer compound.

摘要翻译： 本发明提供二次电池和电容器，其可以提供优异的高速率和循环特性以及足够的电动势和容量。 二次电池和电容器具有包含三聚体化合物的电极的活性材料，所述三聚体化合物包含三个单位的稠环形吲哚或吲哚衍生物，其中每个单元的第二位置和第三位置形成六元环， 可用作三聚体化合物的电荷载体的质子。

公开(公告)号：US07082027B2

公开(公告)日：2006-07-25

申请号：US11050958

申请日：2005-02-04

申请人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

发明人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

IPC分类号： H01G9/00

CPC分类号： H01G9/038 ,  H01G9/028 ,  H01G11/48 ,  H01G11/58 ,  H01G11/64 ,  H01M4/60 ,  H01M4/602 ,  H01M6/045 ,  H01M10/36 ,  H01M10/4235 ,  H01M2300/0011 ,  Y02E60/13

摘要： A proton-conducting electric double layer capacitor comprising a electrolytic solution containing an aqueous solution of an organic or inorganic acid whereto a water-soluble N-containing heterocyclic compound is added.

摘要翻译： 包含含有水溶性含N杂环化合物的有机或无机酸水溶液的电解液的质子传导双电层电容器。

公开(公告)号：US06869731B2

公开(公告)日：2005-03-22

申请号：US10271636

申请日：2002-10-15

申请人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

发明人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

IPC分类号： H01G9/02 ,  H01G11/02 ,  H01G11/08 ,  H01G11/22 ,  H01G11/48 ,  H01G11/52 ,  H01G11/54 ,  H01G11/58 ,  H01M4/60 ,  H01M6/04 ,  H01M10/05 ,  H01M10/36 ,  H01M10/42

CPC分类号： H01G9/038 ,  H01G9/028 ,  H01G11/48 ,  H01G11/58 ,  H01G11/64 ,  H01M4/60 ,  H01M4/602 ,  H01M6/045 ,  H01M10/36 ,  H01M10/4235 ,  H01M2300/0011 ,  Y02E60/13

摘要： The present invention relates to an electrolytic solution comprising an aqueous solution of an organic or inorganic acid whereto a water-soluble N-containing heterocyclic compound is added, and an electrochemical cell such as a secondary battery and an electric double layer capacitor that uses such an electrolytic solution.

摘要翻译： 本发明涉及一种电解液，其包含添加了水溶性含氮杂环化合物的有机或无机酸的水溶液，以及使用这样的二价电池和双电层电容器的电化学电池 电解液。

公开(公告)号：US20050135045A1

公开(公告)日：2005-06-23

申请号：US11050958

申请日：2005-02-04

申请人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

发明人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

IPC分类号： H01G9/02 ,  H01G11/02 ,  H01G11/08 ,  H01G11/22 ,  H01G11/48 ,  H01G11/52 ,  H01G11/54 ,  H01G11/58 ,  H01M4/60 ,  H01M6/04 ,  H01M10/05 ,  H01M10/36 ,  H01M10/42 ,  H01G9/038

CPC分类号： H01G9/038 ,  H01G9/028 ,  H01G11/48 ,  H01G11/58 ,  H01G11/64 ,  H01M4/60 ,  H01M4/602 ,  H01M6/045 ,  H01M10/36 ,  H01M10/4235 ,  H01M2300/0011 ,  Y02E60/13

摘要： A proton-conducting electric double layer capacitor comprising a electrolytic solution containing an aqueous solution of an organic or inorganic acid whereto a water-soluble N-containing heterocyclic compound is added.

摘要翻译： 包含含有水溶性含N杂环化合物的有机或无机酸水溶液的电解液的质子传导双电层电容器。

公开(公告)号：US06998190B2

公开(公告)日：2006-02-14

申请号：US10346102

申请日：2003-01-17

申请人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Masaya Mitani

发明人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Masaya Mitani

IPC分类号： H01M6/46

CPC分类号： H01G9/155 ,  H01G9/10 ,  H01M2/0212 ,  H01M6/12 ,  H01M10/0436 ,  Y02E60/13

摘要： A small battery and an electric double layer capacitor exhibit adequate cell voltage and capacitor withstand voltage. Specifically, the battery or electric double layer capacitor includes basic cells having a pair of electrodes oppositely laminated via the separator, and an electrolyte are packaged in a resin sheet package. The basic cells are laminated in series via a sheet current collector. The sheet current collector extends to an edge of the resin sheet package around the periphery of the basic cells laminated on both sides of the current collector. The sheet current collector is glued or fused to the resin sheet in its edge. The adjacent basic cells via the sheet current collector are fluid-tightly separated within the resin sheet package.

摘要翻译： 小电池和双电层电容器表现出足够的电池电压和电容器耐受电压。 具体地，电池或双电层电容器包括具有通过隔板相对地层叠的一对电极的碱性电池，并且将电解质包装在树脂片封装中。 碱性电池通过片状集电器串联层叠。 片状集电体延伸到层叠在集电体两侧的基本电池的周围的树脂片包装的边缘。 片状集电器在其边缘上胶合或熔合到树脂片。 通过片状集电器的相邻基本电池在树脂片封装内流体密封地分离。

公开(公告)号：US06875541B2

公开(公告)日：2005-04-05

申请号：US10286692

申请日：2002-11-01

申请人： Masaya Mitani ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Tomoki Nobuta ,  Shinako Kaneko

发明人： Masaya Mitani ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Tomoki Nobuta ,  Shinako Kaneko

IPC分类号： H01G9/00 ,  H01G11/02 ,  H01G11/08 ,  H01G11/22 ,  H01G11/24 ,  H01G11/30 ,  H01G11/54 ,  H01G11/58 ,  H01M4/36 ,  H01M4/60 ,  H01M10/0566 ,  H01M10/36 ,  H01M4/58

CPC分类号： H01G9/155 ,  H01M4/02 ,  H01M4/364 ,  H01M4/60 ,  H01M4/602 ,  H01M2300/0011 ,  Y02E60/13

摘要： An electrochemical cell contains, as an electrode active material, a mixture of trimer compounds each in the form of indoles or indole derivatives coupled to each other in second and third positions thereof, and tetramer compounds each of indoles or indole derivatives. In the cell, protons are used as charge carriers.

摘要翻译： 电化学电池包含作为电极活性材料的三聚体化合物的混合物，其各自以其第二和第三位置彼此偶联的吲哚或吲哚衍生物的形式，以及每种吲哚或吲哚衍生物的四聚体化合物。 在电池中，质子被用作电荷载体。

公开(公告)号：US06875244B2

公开(公告)日：2005-04-05

申请号：US10153631

申请日：2002-05-24

申请人： Masato Kurosaki ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Yuji Nakagawa ,  Tomoki Nobuta ,  Masaya Mitani

发明人： Masato Kurosaki ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Yuji Nakagawa ,  Tomoki Nobuta ,  Masaya Mitani

IPC分类号： H01M2/08 ,  H01G9/00 ,  H01M2/00 ,  H01M2/02 ,  H01M2/36 ,  H01M4/04 ,  H01M6/00 ,  H01M6/02 ,  H01M10/04 ,  H01M10/34 ,  H01M10/40

CPC分类号： H01M2/36 ,  H01M2/0257 ,  H01M2/08 ,  H01M10/04 ,  H01M2002/0297 ,  H01M2300/0005 ,  Y10T29/4911 ,  Y10T29/49115

摘要： The object of the present invention is to provide a method of producing electric cells which can improve the production yield, and for that purpose there is provided a method of producing an electric cell, wherein an acidic solution as an electrolytic solution and electrically conductive rubber as an exterior material are used, characterized in that sealing both of the positive electrode and the negative electrode piled via the separator with both of the gasket, through which the stainless needle is inserted, and the electrically conductive rubber, performing a vulcanization binding, after said vulcanization binding, forming a hole by pulling off the stainless needle from the gasket, injecting the electrolytic solution through said hole and sealing said hole; thus obtaining electric cells at high production yield.

摘要翻译： 本发明的目的是提供一种能够提高制造成品率的电池的制造方法，为此目的提供一种电池的制造方法，其中将作为电解液的酸性溶液和导电性橡胶作为 使用外部材料，其特征在于，在所述正极和负极之间通过隔板堆积通过不锈钢针插入的垫圈和导电橡胶两者，在所述密封件之后进行硫化结合 硫化结合，通过从垫圈拉出不锈钢针孔形成孔，通过所述孔注入电解液并密封所述孔; 从而以高产量获得电池。