摘要:
A partially sulfonated polybenzimidazole based polymer for fuel cell membrane is prepared by copolymerizing monomers of 3,3′-diaminobenzidine, isophthalic acid and 5-sulfoisophthalic acid to obtain a partially sulfonated polybenzimidazole, and doping the partially sulfonated polybenzimidazole with inorganic acid.
摘要:
A partially sulfonated polybenzimidazole based polymer for fuel cell membrane is prepared by copolymerizing monomers of 3,3′-diaminobenzidine, isophthalic acid and 5-sulfoisophthalic acid to obtain a partially sulfonated polybenzimidazole, and doping the partially sulfonated polybenzimidazole with inorganic acid.
摘要:
A separator for cooling an MCFC has a cooling gas flow path provided in the separator, a cooling anode gas or a cooling cathode gas flowing through the cooling gas flow path, the cooling anode gas or the cooling cathode gas having a temperature lower than that of a general anode gas or a general cathode gas which is supplied to an anode or a cathode of the MCFC.
摘要:
Disclosed is a method for in-situ preparation of a polybenzimidazole-based electrolyte membrane, including: polymerizing a polybenzimidazole polymer in a solution; casting a solution containing the polymerized polymer onto a substrate and drying the solution in air to form a membrane; washing the dried membrane with water or alcohol; and allowing water or alcohol to evaporate from the membrane containing water or alcohol, while maintaining the shape of the membrane. The method for in-situ preparation of a polybenzimidazole-based electrolyte membrane allows easy preparation of a polybenzimidazole-based electrolyte membrane having a desired area without any complicated processes, and thus contributes to simplification of an overall process for fabricating a fuel cell.
摘要:
An internal reforming molten carbonate fuel cell having a membrane for intercepting carbonate vapor and hydrated vapor is disclosed. The intercepting membrane is made from nickel or nickel alloy which has a high electrical conductivity, corrosion resistant property in an anode environment, and a low affinity for the carbonate vapor. Due to the presence of the intercepting membrane, the transfer of the carbonate vapors and hydrated vapors to the internal reforming catalyst is markedly retarded to prolong the catalytic activity. As a result, a longer operating molten carbonate fuel cell can be obtained.
摘要:
A LiCoO2-coated NiO cathode for molten carbonate fuel cell is provided, wherein the cathode is prepared by dissolving a stoichiometric amount of lithium salts and cobalt salts in a solvent with or without adding a chelating agent to give a sol or a mixed solution, impregnating a NiO electrode for MCFC into the sol or the mixed solution, and drying and calcining the resulting electrode. By using the cathode of the invention, lifetime of the cell can be extended by two or more times while maintaining cell performance.
摘要:
The present invention relates to a cathode, which can be used in molten carbonate fuel cells (hereinafter, referred to as an "MCFC"), and a process for preparing the same. In such a cathode, NiO, which is inexpensive and has relatively good electrochemical performance, has been mainly used. However, NiO has a relatively large solubility in electrolytes of an MCFC which causes the cells to be short circuited, thereby shortening the life of the cells. However, according to the present invention, a cathode having a longer life than common cathodes for MCFC can be prepared by adding alkaline earth metal oxides, which are basic substances, to NiO, the main material of the cathodes, or impregnating an Ni plate with a solution of the alkaline earth metal oxides, to reduce the solubility of the NiO while maintaining its performance as the cathode.
摘要:
In a method for manufacturing Ni—Al alloy powders for electrode materials of fuel cells, in which, using aluminum chloride (AlCl3) as a catalyst, powders of Ni and Al, that have been used as electrode materials, are chemically reacted with each other to diffuse the Al into the Ni powders, so that Ni—Al alloy powders can be manufactured at a low temperature below fusion points of Ni and Al while maintaining a shape and a size of the existing Ni powders as they are, thus providing a manufacturing process of Ni—Al alloy powders that is simple, economical, compatible in working, and ready for scale-up, and in which a conventional manufacturing process of electrode based on Ni is used as it is, so that large sized electrode is manufactured.
摘要:
In a method for manufacturing Ni—Al alloy anode for fuel cells, in which, using nickel powders, Ni powders are mixed with Ni—Al alloy powders, which are hardly sintered in themselves, to assist a sintering of Ni—Al alloy, whereby Ni—Al alloy anode can be manufactured simply, economically and compatibly with mass production even by a conventional manufacturing process for an electrode.
摘要:
Provided are a method of preparing an electrocatalyst for fuel cells in a core-shell structure, an electrocatalyst for fuel cells having a core-shell structure, and a fuel cell including the electrocatalyst for fuel cells. The method may be useful in forming a core and a shell layer without performing a subsequent process such as chemical treatment or heat treatment and forming a core support in which core particles having a nanosize diameter are homogeneously supported, followed by selectively forming shell layers on surfaces of the core particles in the support. Also, the electrocatalyst for fuel cells has a high catalyst-supporting amount and excellent catalyst activity and electrochemical property.