Method for preparing chiral esters
    1.
    发明授权
    Method for preparing chiral esters 失效
    手性酯的制备方法

    公开(公告)号:US06475773B2

    公开(公告)日:2002-11-05

    申请号:US09726412

    申请日:2000-12-01

    IPC分类号: C12P4100

    CPC分类号: C12P41/003 C12P7/62

    摘要: The present invention relates to a method for preparing a chiral ester and more particularly, the method for preparing an optically pure chiral ester from an alkenyl ester at a high yield by mixing and reacting: an alkenyl ester; a ruthenium complex to activate reduction reaction of said alkenyl ester and racemization; a lipase to acylate selectively one of enantiomers of said alkenyl ester; and a reducing agent to supply a hydride to said ruthenium complex. Said optically pure chiral ester of the present invention can be prepared by one-step synthesis from various types of alkenyl esters at a high yield.

    摘要翻译: 本发明涉及一种制备手性酯的方法,更具体地说,涉及通过混合和反应从链烯基酯以高产率制备光学纯手性酯的方法:烯基酯; 用于活化所述烯基酯的还原反应的钌络合物和外消旋化;选择性地将所述烯基酯的对映异构体中的一种酰化的脂肪酶; 和还原剂,以向所述钌络合物供应氢化物。 本发明的所述光学纯手性酯可以通过以高收率从各种类型的烯基酯进行一步合成来制备。

    Preparing method of chiral ester
    2.
    发明授权
    Preparing method of chiral ester 失效
    手性酯的制备方法

    公开(公告)号:US06753443B1

    公开(公告)日:2004-06-22

    申请号:US09786276

    申请日:2001-03-02

    IPC分类号: C07C6976

    CPC分类号: C12P7/62 C12P41/004

    摘要: The present invention relates to a process for preparing a chiral ester according to the formula (100): by reacting (i) a racemic alcohol, (ii) a selected ruthenium complex to activate racemization of the racemic alcohol, (iii) a lipase to selectively acylate one enantiomer of the racemic alcohol, and (iv) an acyl donor compound to supply an acyl group to the lipase.

    摘要翻译: 本发明涉及一种制备根据式(100)的手性酯的方法:通过使(i)外消旋醇,(ii)选择的钌络合物使外消旋醇的外消旋化活化,(iii)脂肪酶 选择性地酰化外消旋醇的一种对映异构体,和(iv)酰基供体化合物以向脂肪酶提供酰基。

    Additive for non-aqueous electrolyte and secondary battery using the same
    4.
    发明申请
    Additive for non-aqueous electrolyte and secondary battery using the same 有权
    用于非水电解质和二次电池的添加剂

    公开(公告)号:US20090280414A1

    公开(公告)日:2009-11-12

    申请号:US12311121

    申请日:2007-09-20

    IPC分类号: H01M6/18 H01M6/16

    摘要: Disclosed is an electrolyte comprising a compound having both a sulfonate group and a cyclic carbonate group. The electrolyte forms a more stable and dense SEI layer on the surface of an anode, and thus improves the capacity maintenance characteristics and lifespan characteristics of a battery. Also, disclosed is a compound represented by the following Formula 1, and a method for preparing the same by reacting 4-(hydroxyalkyl)-1,3-dioxolan-2-one with a sulfonyl halide compound: wherein each of R1 and R2 independently represents a C1˜C6 alkylene group optionally containing a C1˜C6 alkyl group or C2˜C6 alkenyl group introduced thereto; R3 is selected from the group consisting of a hydrogen atom, C1˜C20 alkyl group, C3˜C8 cyclic alkyl group, C2˜C6 alkenyl group, halo-substituted alkyl group, phenyl group and benzyl group.

    摘要翻译: 公开了包含具有磺酸酯基和环状碳酸酯基的化合物的电解质。 电解质在阳极表面形成更稳定和更致密的SEI层,从而提高电池的容量维持特性和寿命特性。 此外,还公开了由下式1表示的化合物及其制备方法,其中4-(羟烷基)-1,3-二氧戊环-2-酮与磺酰卤化合物反应:其中R 1和R 2各自独立地 表示任选地含有引入其中的C 1〜C 6烷基或C 2〜C 6烯基的C 1〜C 6亚烷基; R3选自氢原子,C1〜C20烷基,C3〜C8环状烷基,C2〜C6烯基,卤素取代的烷基,苯基和苄基。