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公开(公告)号:US06475773B2
公开(公告)日:2002-11-05
申请号:US09726412
申请日:2000-12-01
申请人: Jai Wook Park , Mahn-Joo Kim , Jeong Hwan Koh , Hyun Min Jung
发明人: Jai Wook Park , Mahn-Joo Kim , Jeong Hwan Koh , Hyun Min Jung
IPC分类号: C12P4100
CPC分类号: C12P41/003 , C12P7/62
摘要: The present invention relates to a method for preparing a chiral ester and more particularly, the method for preparing an optically pure chiral ester from an alkenyl ester at a high yield by mixing and reacting: an alkenyl ester; a ruthenium complex to activate reduction reaction of said alkenyl ester and racemization; a lipase to acylate selectively one of enantiomers of said alkenyl ester; and a reducing agent to supply a hydride to said ruthenium complex. Said optically pure chiral ester of the present invention can be prepared by one-step synthesis from various types of alkenyl esters at a high yield.
摘要翻译: 本发明涉及一种制备手性酯的方法,更具体地说,涉及通过混合和反应从链烯基酯以高产率制备光学纯手性酯的方法:烯基酯; 用于活化所述烯基酯的还原反应的钌络合物和外消旋化;选择性地将所述烯基酯的对映异构体中的一种酰化的脂肪酶; 和还原剂,以向所述钌络合物供应氢化物。 本发明的所述光学纯手性酯可以通过以高收率从各种类型的烯基酯进行一步合成来制备。
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公开(公告)号:US06753443B1
公开(公告)日:2004-06-22
申请号:US09786276
申请日:2001-03-02
申请人: Jai Wook Park , Mahn-Joo Kim , Jeong Hwan Koh , Hyun Min Jung
发明人: Jai Wook Park , Mahn-Joo Kim , Jeong Hwan Koh , Hyun Min Jung
IPC分类号: C07C6976
CPC分类号: C12P7/62 , C12P41/004
摘要: The present invention relates to a process for preparing a chiral ester according to the formula (100): by reacting (i) a racemic alcohol, (ii) a selected ruthenium complex to activate racemization of the racemic alcohol, (iii) a lipase to selectively acylate one enantiomer of the racemic alcohol, and (iv) an acyl donor compound to supply an acyl group to the lipase.
摘要翻译: 本发明涉及一种制备根据式(100)的手性酯的方法:通过使(i)外消旋醇,(ii)选择的钌络合物使外消旋醇的外消旋化活化,(iii)脂肪酶 选择性地酰化外消旋醇的一种对映异构体,和(iv)酰基供体化合物以向脂肪酶提供酰基。
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3.
公开(公告)号:US20060094808A1
公开(公告)日:2006-05-04
申请号:US11260330
申请日:2005-10-27
申请人: Youngjin Kim , Bhomri Kim , Chayeon Seo , Jeong Hwan Koh
发明人: Youngjin Kim , Bhomri Kim , Chayeon Seo , Jeong Hwan Koh
CPC分类号: C08F114/06 , C08F14/06 , C08K9/04 , C08F2/18 , C08L27/06
摘要: Provided are a vinyl chloride resin composition containing a vinyl chloride monomer and an organo-modified metal oxide nanoparticle which can be used in exterior construction materials due to markedly improved thermal stability and weather resistance, which are considered weaknesses of vinyl chloride resins, and a method of preparing the same.
摘要翻译: 提供含有氯乙烯单体和有机改性的金属氧化物纳米颗粒的氯乙烯树脂组合物,其可以用于外部结构材料,这是由于显着改善的热稳定性和耐候性,这被认为是氯乙烯树脂的弱点,以及方法 准备相同
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4.
公开(公告)号:US20090280414A1
公开(公告)日:2009-11-12
申请号:US12311121
申请日:2007-09-20
申请人: Jeong Hwan Koh , Yong Joon Ha , Jin Hyun Park , Chul Haeng Lee , Young Min Lim , Jeong Ae Ahn , Dmitry Pogozhev
发明人: Jeong Hwan Koh , Yong Joon Ha , Jin Hyun Park , Chul Haeng Lee , Young Min Lim , Jeong Ae Ahn , Dmitry Pogozhev
CPC分类号: H01M10/0567 , H01M4/13 , H01M10/052 , H01M10/0525 , H01M10/0569
摘要: Disclosed is an electrolyte comprising a compound having both a sulfonate group and a cyclic carbonate group. The electrolyte forms a more stable and dense SEI layer on the surface of an anode, and thus improves the capacity maintenance characteristics and lifespan characteristics of a battery. Also, disclosed is a compound represented by the following Formula 1, and a method for preparing the same by reacting 4-(hydroxyalkyl)-1,3-dioxolan-2-one with a sulfonyl halide compound: wherein each of R1 and R2 independently represents a C1˜C6 alkylene group optionally containing a C1˜C6 alkyl group or C2˜C6 alkenyl group introduced thereto; R3 is selected from the group consisting of a hydrogen atom, C1˜C20 alkyl group, C3˜C8 cyclic alkyl group, C2˜C6 alkenyl group, halo-substituted alkyl group, phenyl group and benzyl group.
摘要翻译: 公开了包含具有磺酸酯基和环状碳酸酯基的化合物的电解质。 电解质在阳极表面形成更稳定和更致密的SEI层,从而提高电池的容量维持特性和寿命特性。 此外,还公开了由下式1表示的化合物及其制备方法,其中4-(羟烷基)-1,3-二氧戊环-2-酮与磺酰卤化合物反应:其中R 1和R 2各自独立地 表示任选地含有引入其中的C 1〜C 6烷基或C 2〜C 6烯基的C 1〜C 6亚烷基; R3选自氢原子,C1〜C20烷基,C3〜C8环状烷基,C2〜C6烯基,卤素取代的烷基,苯基和苄基。
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5.
公开(公告)号:US08349502B2
公开(公告)日:2013-01-08
申请号:US12311121
申请日:2007-09-20
申请人: Jeong Hwan Koh , Yong Joon Ha , Jin Hyun Park , Chul Haeng Lee , Young Min Lim , Jeong Ae Ahn , Dmitry Pogozhev
发明人: Jeong Hwan Koh , Yong Joon Ha , Jin Hyun Park , Chul Haeng Lee , Young Min Lim , Jeong Ae Ahn , Dmitry Pogozhev
IPC分类号: H01M6/16 , C07C303/00 , C07C307/00 , C07C309/00 , C07C311/00 , C07D321/00 , C07D323/00 , C07D407/00 , C07D493/00
CPC分类号: H01M10/0567 , H01M4/13 , H01M10/052 , H01M10/0525 , H01M10/0569
摘要: Disclosed is an electrolyte comprising a compound having both a sulfonate group and a cyclic carbonate group. The electrolyte forms a more stable and dense SEI layer on the surface of an anode, and thus improves the capacity maintenance characteristics and lifespan characteristics of a battery. Also, disclosed is a compound represented by the following Formula 1, and a method for preparing the same by reacting 4-(hydroxyalkyl)-1,3-dioxolan-2-one with a sulfonyl halide compound: wherein each of R1 and R2 independently represents a C1˜C6 alkylene group optionally containing a C1˜C6 alkyl group or C2˜C6 alkenyl group introduced thereto; R3 is selected from the group consisting of a hydrogen atom, C1˜C20 alkyl group, C3˜C8 cyclic alkyl group, C2˜C6 alkenyl group, halo-substituted alkyl group, phenyl group and benzyl group.
摘要翻译: 公开了包含具有磺酸酯基和环状碳酸酯基的化合物的电解质。 电解质在阳极表面形成更稳定和更致密的SEI层,从而提高电池的容量维持特性和寿命特性。 此外,还公开了由下式1表示的化合物及其制备方法,其中4-(羟烷基)-1,3-二氧戊环-2-酮与磺酰卤化合物反应:其中R 1和R 2各自独立地 表示可以含有C1〜C6烷基或C2〜C6链烯基的C1〜C6亚烷基; R 3选自氢原子,C 1〜C 20烷基,C 3〜C 8环烷基,C 2〜C 6烯基,卤代烷基,苯基和苄基。
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