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公开(公告)号:US06563004B2
公开(公告)日:2003-05-13
申请号:US09729461
申请日:2000-12-05
申请人: Jan Nouwen , Stefan Käshammer , Arthur Höhn , Frank Funke , Johann-Peter Melder , Frank Gutschoven , Philip Buskens
发明人: Jan Nouwen , Stefan Käshammer , Arthur Höhn , Frank Funke , Johann-Peter Melder , Frank Gutschoven , Philip Buskens
IPC分类号: C07C20926
CPC分类号: C07C209/26 , C07C211/06
摘要: Monoisopropylamine is prepared by reacting acetone with ammonia and with hydrogen at elevated temperature and elevated pressure in the presence of a catalyst, wherein the catalytically active mass of the catalyst comprises, after its preparation and before the treatment with hydrogen, from 20 to 90% by weight of aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2), from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO, from 1 to 70% by weight of oxygen-containing compounds of nickel, calculated as NiO, and from 1 to 70% by weight of oxygen-containing compounds of cobalt, calculated as CoO.
摘要翻译: 通过使丙酮与氨和氢气在升高的温度和升高的压力下在催化剂存在下反应制备单异丙胺,其中催化活性物质在其制备之后和在用氢处理之前包含20-90% 氧化铝(Al 2 O 3),二氧化锆(ZrO 2),二氧化钛(TiO 2)和/或二氧化硅(SiO 2)的重量,1至70重量%的以CuO计的氧含氧化合物,1至 70重量%的以NiO计的含氧化合物的镍和1-70重量%的以CoO计的钴的含氧化合物。
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公开(公告)号:US06525222B2
公开(公告)日:2003-02-25
申请号:US09729458
申请日:2000-12-05
申请人: Jan Nouwen , Arthur Höhn , Horst Neuhauser , Frank Funke , Stephan Andreas Schunk , Johann-Peter Melder , Knut Eger , Michael Hesse , Joachim Wulff-Döring
发明人: Jan Nouwen , Arthur Höhn , Horst Neuhauser , Frank Funke , Stephan Andreas Schunk , Johann-Peter Melder , Knut Eger , Michael Hesse , Joachim Wulff-Döring
IPC分类号: C07C20900
CPC分类号: C07C213/02 , C07C209/26 , C07C2601/08 , C07C2602/08 , C07C2602/10 , C07C211/35 , C07C211/42 , C07C217/58
摘要: Amines are prepared by reacting aldehydes or ketones at elevated temperature under elevated pressure with nitrogen compounds selected from the group of ammonia, primary and secondary amines, and with hydrogen in the presence of a catalyst, wherein the catalytically active mass of the catalyst contains, after its preparation and before the treatment with hydrogen, 22 to 45% by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 5 to 50% by weight of oxygen-containing compounds of nickel, calculated as NiO, where the molar ratio of nickel to copper is greater than 1, 5 to 50% by weight of oxygen-containing compounds of cobalt, calculated as CoO, 0 to 5% by weight of oxygen-containing compounds of molybdenum, calculated as MoO3, and 0 to 10% by weight of oxygen-containing compounds of aluminum and/or manganese, calculated as Al2O3 or MnO2.
摘要翻译: 通过使升高的温度下的醛或酮与选自氨,伯和仲胺的氮化合物和在催化剂存在下与氢气反应的醛或酮进行反应来制备胺,其中催化剂的催化活性物质含有 其制备方法和用氢处理之前,按重量计22%至45%的锆的氧含量化合物,按ZrO2计算,按重量计为CuO的含氧化合物为铜,按CuO计为5〜50% 按NiO计的含镍化合物的重量,其中镍与铜的摩尔比大于1.5至50重量%的以CoO计的含氧化合物的钴,0至5重量% 按MoO3计算的含氧化合物的钼和0至10重量%的按Al2O3或MnO2计算的含铝和/或锰的含氧化合物。
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公开(公告)号:US06417353B1
公开(公告)日:2002-07-09
申请号:US09520908
申请日:2000-03-07
申请人: Frank Funke , Joachim Wulff-Döring , Gerhard Schulz , Wolfgang Siegel , Andreas Kramer , Johann-Peter Melder , Arthur Höhn , Philipp Buskens , Wolfgang Reif , Jan Nouwen
发明人: Frank Funke , Joachim Wulff-Döring , Gerhard Schulz , Wolfgang Siegel , Andreas Kramer , Johann-Peter Melder , Arthur Höhn , Philipp Buskens , Wolfgang Reif , Jan Nouwen
IPC分类号: C07B4304
CPC分类号: C07C209/26 , B01J23/885 , B01J37/03 , C07C213/02 , C07C2601/08 , C07C2602/10 , C07C211/06 , C07C211/07 , C07C211/17 , C07C211/27 , C07C211/30 , C07C211/35 , C07C211/38 , C07C217/58
摘要: Amines are prepared by reacting aldehydes or ketones at elevated temperature under elevated pressure with nitrogen compounds selected from the group of ammonia, primary and secondary amines, and with hydrogen in the presence of a catalyst containing copper, wherein the catalytically active mass of the catalyst contains, before the reduction with hydrogen, 20 to 85% by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 14 to 70% by weight of oxygen-containing compounds of nickel, calculated as NiO, 0 to 5% by weight of oxygen-containing compounds of molybdenum, calculated as MoO3, and 0 to 10% by weight of oxygen-containing compounds of aluminum, calculated as Al2O3.
摘要翻译: 胺在升高的温度下在升高的温度下与选自氨,伯胺和仲胺的氮化合物和氢气在含催化剂的聚合物的存在下反应制备,其中催化剂活性物质含有, 在用氢还原之前,以ZrO 2计为20〜85重量%的含氧化合物,以30重量%计,氧化铝为14〜70重量%,氧化铝为100重量% 以NiO表示的镍化合物,以MoO 3计为0〜5重量%的含氧化合物的钼和0〜10重量%的按Al 2 O 3计算的含氧化合物的铝。
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公开(公告)号:US07053246B2
公开(公告)日:2006-05-30
申请号:US10731095
申请日:2003-12-10
IPC分类号: C07C29/04
CPC分类号: C07C209/64 , C07C211/14
摘要: Process for preparing a symmetrical secondary amine by reaction of a primary amine in the presence of hydrogen and a catalyst whose preparation has involved precipitation of catalytically active components onto monoclinic, tetragonal or cubic zirconium dioxide.
摘要翻译: 通过伯胺在氢气和催化剂的反应下制备对称仲胺的方法,其制备涉及将催化活性组分沉淀到单斜晶,四方晶或立方二氧化锆上。
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公开(公告)号:US07034186B2
公开(公告)日:2006-04-25
申请号:US10731158
申请日:2003-12-10
申请人: Till Gerlach , Frank Funke , Johann-Peter Melder
发明人: Till Gerlach , Frank Funke , Johann-Peter Melder
IPC分类号: C07C209/26 , C07C209/16 , C07C209/18
CPC分类号: C07C209/16 , B01J21/066 , B01J23/002 , B01J23/755 , B01J37/0063 , B01J37/18 , B01J2523/00 , C07C209/26 , B01J2523/17 , B01J2523/48 , B01J2523/845 , B01J2523/847 , C07C211/07
摘要: Process for preparing an amine by reacting a primary or secondary alcohol, aldehyde or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia and primary and secondary amines in the presence of a catalyst whose preparation has involved precipitation of catalytically active components onto monoclinic, tetragonal or cubic zirconium dioxide.
摘要翻译: 通过使伯或仲醇,醛或酮与氢和选自氨和伯胺和仲胺的氮化合物在催化剂的存在下反应制备胺的方法,所述催化剂的制备涉及将催化活性组分沉淀到 单斜晶,四方晶或立方二氧化锆。
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公开(公告)号:US20050107637A1
公开(公告)日:2005-05-19
申请号:US10507602
申请日:2003-03-07
申请人: Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hullmann
发明人: Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hullmann
IPC分类号: C07D295/02 , B01J23/70 , B01J23/755 , B01J23/78 , B01J37/03 , B01J37/06 , C07B61/00 , C07C209/16 , C07C209/26 , C07C209/60 , C07C211/03 , C07C211/07 , C07C213/02 , C07C217/08 , C07D295/023 , C07C29/24 , C07C29/14
CPC分类号: C07C213/02 , B01J23/70 , B01J23/755 , B01J37/03 , B01J37/06 , C07C209/16 , C07C209/26 , C07D295/023 , C07C211/03 , C07C217/08
摘要: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.
摘要翻译: 公开了催化剂,其催化活性物质含有22至40重量%的以ZrO 2计算的含氧化合物的锆,1至30重量%的含氧化合物的铜 ,以CuO计,15至50重量%的含氧化合物的镍,以NiO计算,镍和铜之间的摩尔比大于15重量%,含氧化合物的化合物为15至50重量% 作为CoO,并且在用氢处理之前少于1重量%的碱金属(以碱金属氧化物计)。 还公开了一种通过使伯醇和仲醇,醛或酮与选自氨,伯胺和仲胺的氢和氮化合物在所述催化剂存在下在升高的温度和升高的温度下生产胺的方法 压力。
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公开(公告)号:US06365740B1
公开(公告)日:2002-04-02
申请号:US09811433
申请日:2001-03-20
IPC分类号: C07D23942
CPC分类号: C07D239/42
摘要: 2-Methyl-4-amino-5-aminomethylpyrimidine of the formula 1 is prepared by reacting 2-methyl-4-amino-5-alkoxymethylpyrimidine of the formula 2 where R=C1-C6-alkyl, with ammonia in the presence of a catalyst.
摘要翻译: 将式1的2-甲基-4-氨基-5-氨基甲基嘧啶与催化剂存在下的氨反应制得,其中式2的2-甲基-4-氨基-5-烷氧基甲基嘧啶,其中R = C 1 -C 6 - 烷基。
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公开(公告)号:US6057442A
公开(公告)日:2000-05-02
申请号:US159089
申请日:1998-09-23
申请人: Joachim Wulff-Doring , Michael Hesse , Johann-Peter Melder , Philipp Buskens , Guido Voit , Frank Funke
发明人: Joachim Wulff-Doring , Michael Hesse , Johann-Peter Melder , Philipp Buskens , Guido Voit , Frank Funke
IPC分类号: C07D295/02 , B01J23/755 , B01J23/889 , C07B61/00 , C07C209/16 , C07D295/023
CPC分类号: C07D295/023 , B01J23/755 , B01J23/8892 , C07C209/16 , B01J23/8898 , Y02P20/582
摘要: Amines are prepared from primary or secondary alcohols and nitrogen compounds selected from the group of ammonia, primary and secondary amines, at from 80 to 250.degree. C. under pressures from 0.1 to 40 MPa with hydrogen in the presence of a catalyst comprising zirconium, copper and nickel, wherein the catalytically active composition comprises20-85% by weight of oxygen-containing zirconium compounds, calculated as ZrO.sub.2,1-30% by weight of oxygen-containing copper compounds, calculated as CuO,14-70% by weight of oxygen-containing nickel compounds, calculated as NiO, where the molar ratio of nickel to copper is greater than 1,0-10% by weight of oxygen-containing aluminum and/or manganese compounds, calculated as Al.sub.2 O.sub.3 and/or MnO.sub.2,and no oxygen-containing cobalt or molybdenum compounds.
摘要翻译: 在含有锆,铜和铜的催化剂存在下,在氢气压力为0.1至40MPa的压力下,从伯,仲醇和选自氨,伯胺和仲胺的氮化合物制备胺。 和镍,其中催化活性组合物包含20-85重量%的以ZrO 2计算的含氧锆化合物,1-30重量%的以CuO计的含氧铜化合物,14-70重量% 以NiO计算的含氧镍化合物,其中镍与铜的摩尔比大于1-10重量%,以Al 2 O 3和/或MnO 2计算的含氧铝和/或锰化合物为0-10重量% 含氧钴或钼化合物。
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公开(公告)号:US07183438B2
公开(公告)日:2007-02-27
申请号:US10507602
申请日:2003-03-07
申请人: Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hüllmann
发明人: Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hüllmann
IPC分类号: C07C209/16 , C07C209/18 , C07C209/29 , B01J23/40 , B01J23/42
CPC分类号: C07C213/02 , B01J23/70 , B01J23/755 , B01J37/03 , B01J37/06 , C07C209/16 , C07C209/26 , C07D295/023 , C07C211/03 , C07C217/08
摘要: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.
摘要翻译: 公开了催化剂,其催化活性物质含有22至40重量%的以ZrO 2计算的含氧化合物的锆,1至30重量%的含氧化合物的铜 ,以CuO计,15至50重量%的含氧化合物的镍,以NiO计算,镍和铜之间的摩尔比大于15重量%,含氧化合物的化合物为15至50重量% 作为CoO,并且在用氢处理之前少于1重量%的碱金属(以碱金属氧化物计)。 还公开了一种通过使伯醇和仲醇,醛或酮与选自氨,伯胺和仲胺的氢和氮化合物在所述催化剂存在下在升高的温度和升高的温度下生产胺的方法 压力。
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公开(公告)号:US06576796B1
公开(公告)日:2003-06-10
申请号:US09668458
申请日:2000-09-25
申请人: Frank Funke , Ulrich Steinbrenner , Matthias Frauenkron , Ralf Böhling , Johann-Peter Melder , Thomas Heidemann
发明人: Frank Funke , Ulrich Steinbrenner , Matthias Frauenkron , Ralf Böhling , Johann-Peter Melder , Thomas Heidemann
IPC分类号: C07C20960
CPC分类号: C07C209/60 , C07C209/64 , C07C211/03
摘要: Preparation of alkylamines, where, in a first process stage, an olefin is reacted with ammonia, a primary amine and/or a secondary amine under hydroaminating conditions, and then, in a second process stage, the resulting hydroamination product(s) is/are reacted under transalkylating conditions.
摘要翻译: 烷基胺的制备,其中在第一工艺阶段中,烯烃在水解条件下与氨,伯胺和/或仲胺反应,然后在第二工艺阶段,所得到的水解产物是/ 在烷基转移条件下反应。
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