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公开(公告)号：US06755963B2
公开(公告)日：2004-06-29
申请号：US10261773
申请日：2002-10-01
Applicant: Jerry L. Haluska , Kenneth Lloyd Riley
Inventor： Jerry L. Haluska , Kenneth Lloyd Riley
IPC: C10G4500
CPC classification number: C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
Abstract: This invention provides a process for hydrotreating hydrocarbon resins, which process comprises contacting a feedstock comprising a hydrocarbon resin or rosin, under suitable hydrotreating conditions, with a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least two Group VIB metals and wherein the ratio of Group VIB metal to Group VIII non-noble metal is from about 10:1 to about 1:10. The process according to the invention can achieve increased hydrocarbon resin productivity through increase in throughput volumes and effective catalyst lifetimes. The process of the invention is desirably practiced with a bulk catalyst consisting of only the combination of the metal species with the active metal components. The absence of carrier substrates largely removes the possibility of halogen accumulation on substrate surfaces that, in turn, can acidify metal catalysts such that additional, progressive cracking of the hydrocarbon resin molecules occurs.
Abstract translation: 本发明提供了加氢处理烃树脂的方法，该方法包括在合适的加氢处理条件下将包含烃树脂或松香的原料与由至少一种VIII族非贵金属和至少两种VIB族组成的本体多金属催化剂 金属，其中VIB族金属与VIII族非贵金属的比率为约10:1至约1:10。 根据本发明的方法可以通过增加生产量和有效的催化剂寿命来实现提高的烃树脂生产率。 本发明的方法理想地用仅由金属物质与活性金属组分的组合组成的本体催化剂来实施。 不存在载体衬底大大地消除了在衬底表面上卤素积聚的可能性，这又可以使金属催化剂酸化，从而发生烃树脂分子的额外的进行性裂化。
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公开(公告)号：US06758963B1
公开(公告)日：2004-07-06
申请号：US09869989
申请日：2001-07-09
Applicant: Slyvain S. Hantzer , Kenneth Lloyd Riley
Inventor： Slyvain S. Hantzer , Kenneth Lloyd Riley
IPC: C10G4504
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41
Abstract: A process for preparing a lubricating oil basestock containing at least about 90% saturates. The process employs a bulk catalyst comprising at least one non-noble Group VIII metal and two Group VIB metals and wherein said metal catalyst further comprises a non-noble Group VIII molybdate in which at least a portion but less than all of molybdenum is replaced by tungsten.
Abstract translation: 一种制备含有至少约90％饱和物的润滑油基础油的方法。 该方法采用包含至少一种非贵金属VIII族金属和两种VIB族金属的本体催化剂，其中所述金属催化剂还包含非贵金属Ⅷ族钼酸盐，其中至少一部分但少于全部钼被 钨。
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公开(公告)号：US06278030B1
公开(公告)日：2001-08-21
申请号：US09483067
申请日：2000-01-14
Applicant: Jose Manuel Vargas , Kenneth Lloyd Riley
Inventor： Jose Manuel Vargas , Kenneth Lloyd Riley
IPC: C07C2916
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41 , C07C31/125
Abstract: An improved process for preparing alcohols by the Oxo process. More particularly this invention relates to an improvement in the hydrogenation step of the Oxo process characterized in the use of certain bulk multimetallic hydrogenation catalysts comprised of at least one Group VIII non-noble metal and at least two Group VIB metals.
Abstract translation: 通过Oxo方法制备醇的改进方法。 更具体地说，本发明涉及Oxo方法的氢化步骤的改进，其特征在于使用由至少一种VIII族非贵金属和至少两种VIB族金属组成的某些本体多金属氢化催化剂。
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公开(公告)号：US07232515B1
公开(公告)日：2007-06-19
申请号：US09869987
申请日：2000-01-14
Applicant: Richard Alan Demmin , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
Inventor： Richard Alan Demmin , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC: C10G45/60
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41
Abstract: A process for hydrofining a lubricating oil feedstock comprising contacting the feedstock with a hydrofining catalyst in a hydrofining zone under hydrofining conditions wherein the hydrofining catalyst comprises a bulk metal catalyst containing non-noble Group VIII metal molybdate in which at least a portion but less than all of the molybdenum is replaced by tungsten.
Abstract translation: 一种用于加氢精炼润滑油原料的方法，包括在加氢精炼条件下在加氢精炼区中将原料与加氢精制催化剂接触，其中加氢精制催化剂包含含有非贵金属VIII族金属钼酸盐的本体金属催化剂，其中至少一部分但少于全部 的钼被钨取代。
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公开(公告)号：US06783663B1
公开(公告)日：2004-08-31
申请号：US09869988
申请日：2001-08-22
Applicant: Kenneth Lloyd Riley , Darryl Patrick Klein , Zhiguo Hou , Stuart Leon Soled , Michael Charles Kerby , Gary Brice McVicker , Edward Stanley Ellis , Michele Sue Touvelle , Sabato Miseo
Inventor： Kenneth Lloyd Riley , Darryl Patrick Klein , Zhiguo Hou , Stuart Leon Soled , Michael Charles Kerby , Gary Brice McVicker , Edward Stanley Ellis , Michele Sue Touvelle , Sabato Miseo
IPC: C10G4504
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41
Abstract: A hydroprocessing process, comprising: contacting a feedstock, at hydrotreating conditions, with a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least two Group VIB metals and wherein the ratio of Group VIB metal to Group VIII non-noble metal is from about 10:1 to about 1:10 to form a hydrotreated product.
Abstract translation: 一种加氢处理方法，包括：在加氢处理条件下使原料与由至少一种第八族非贵金属和至少两种第VIB族金属组成的本体多金属催化剂接触，并且其中VIB族金属与VIII族非金属的比率， 贵金属为约10:1至约1:10以形成加氢处理的产物。
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6.发明授权
公开(公告)号：US06620313B1
公开(公告)日：2003-09-16
申请号：US09869986
申请日：2001-08-22
Applicant: Richard Alan Demmin , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
Inventor： Richard Alan Demmin , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC: C10G7306
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41
Abstract: Hydroconversion process of petroleum and chemical feedstocks using bulk Group VIII/Group VIB catalysts. Preferred catalysts include those comprised of Ni—Mo—W.
Abstract translation: 石油和化学原料的加氢转化工艺使用大量第VIII / VIB族催化剂。 优选的催化剂包括由Ni-Mo-W组成的催化剂。
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公开(公告)号：US07586017B2
公开(公告)日：2009-09-08
申请号：US10582742
申请日：2004-12-16
Applicant: Eddy Theophyle Andrea Van Driessche , Philippe Louis Buess , Raphael Frans Caers , Arie Van Vliet , Ramzi Yanni Saleh , Jose Manuel Vargas , Kenneth Lloyd Riley , Magdiel Agosto
Inventor： Eddy Theophyle Andrea Van Driessche , Philippe Louis Buess , Raphael Frans Caers , Arie Van Vliet , Ramzi Yanni Saleh , Jose Manuel Vargas , Kenneth Lloyd Riley , Magdiel Agosto
IPC: C07C29/141
CPC classification number: C07C29/16 , C07C11/02 , C07C29/141 , C07C29/175 , C07C45/50 , C07C31/125 , C07C47/02
Abstract: The use of a controlled amount of water in a hydrogenation stage of the oxo process for the production of alcohols which uses at least two reactors in series improves the efficiency of the hydrogenation reaction and catalyst life as does a reduction in the amount of sulphur, chlorine and hydroformylation catalyst residues in the feed to hydrogenation.
Abstract translation: 在氧化方法的氢化阶段中使用受控量的水来生产使用至少两个串联的反应器的醇的提高氢化反应和催化剂寿命的效率，同时硫，氯的量的减少 和加氢甲酰化催化剂残余物在进料中进行氢化。
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公开(公告)号：US06652738B2
公开(公告)日：2003-11-25
申请号：US10346018
申请日：2003-01-16
Applicant: Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
Inventor： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC: C10G4504
CPC classification number: B01J35/002 , B01J23/85 , B01J23/8885 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/20 , C10G49/04
Abstract: The invention pertains to a process for the hydroprocessing of a hydrocarbon feedstock wherein said feedstock is contacted at hydroprocessing conditions with a catalyst composition which comprises bulk catalyst particles which comprise at least one Group VIII non-noble metal and at least two Group VIB metals. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of the bulk catalyst particles. The metals are present in the catalyst composition in their oxidic and/or sulfidic state. The catalyst composition has an X-ray diffraction pattern in which the characteristic full width at half maximum does not exceed 2.5° when the Group VIB metals are molybdenum, tungsten, and, optionally, chromium, or does not exceed 4.0° when the Group VIB metals are molybdenum and chromium or tungsten and chromium.
Abstract translation: 本发明涉及烃原料的加氢处理方法，其中所述原料在加氢处理条件下与催化剂组合物接触，所述催化剂组合物包含包含至少一种VIII族非贵金属和至少两种VIB族金属的本体催化剂颗粒。 VIII族和VIB族金属包含约50wt。 ％至约100重量％ 以体积催化剂颗粒的总重量计算的氧化物％。 金属以其氧化和/或硫化态存在于催化剂组合物中。 催化剂组合物具有X射线衍射图，其中当VIB族金属为钼，钨和任选的铬时，半峰的特征全宽度不超过2.5°，当VIB族VIB金属为不超过4.0°时 金属是钼和铬或钨和铬。
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公开(公告)号：US06582590B1
公开(公告)日：2003-06-24
申请号：US09869982
申请日：2001-08-22
Applicant: Kenneth Lloyd Riley , Darryl Patrick Klein , Zhiguo Hou , Stuart Leon Soled , Michael Charles Kerby , Gary Brice McVicker , Edward Stanley Ellis , Michele Sue Touvelle , Sabato Miseo
Inventor： Kenneth Lloyd Riley , Darryl Patrick Klein , Zhiguo Hou , Stuart Leon Soled , Michael Charles Kerby , Gary Brice McVicker , Edward Stanley Ellis , Michele Sue Touvelle , Sabato Miseo
IPC: C10G4500
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41
Abstract: Sulfur content of distillate feedstock, which is greater than 3,000 wppm, is reduced using multi-stage hydrodesulfurization by reacting the feestream in stages with reaction zone(s) containing bulk multimetallic catalyst comprised of Group VIII non-noble metal(s) and at least two group VIB metals. The ratio of Group VIB to Group VIII non-noble metals is 10:1 to 1:10.
Abstract translation: 通过使用多级加氢脱硫，通过使包含阶段的发泡与包含第VIII族非贵金属的多体金属催化剂和至少包含第一组的多元金属催化剂的反应区反应来减少大于3,000wppm的馏出物原料的硫含量 两组VIB金属。 VIB族与VIII族非贵金属的比例为10：1〜1:10。
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公开(公告)号：US07288182B1
公开(公告)日：2007-10-30
申请号：US09869984
申请日：2000-01-14
Applicant: Stuart Leon Soled , Sabato Miseo , Roman Krycak , Hilda B. Vroman , Teh Chung Ho , Kenneth Lloyd Riley
Inventor： Stuart Leon Soled , Sabato Miseo , Roman Krycak , Hilda B. Vroman , Teh Chung Ho , Kenneth Lloyd Riley
CPC classification number: B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41
Abstract: A process for hydroprocessing petroleum and chemical feedstocks by use of a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least one, preferably two Group VIB metal wherein the ratio of Group VIB metal to Group VIII metal is from about 10:1 to 1:10.
Abstract translation: 通过使用由至少一种VIII族非贵金属和至少一种，优选两种VIB族金属组成的本体多金属催化剂加氢处理石油和化学原料的方法，其中VIB族金属与VIII族金属的比例为约 10：1到1:10。
