公开(公告)号：US20080061686A1

公开(公告)日：2008-03-13

申请号：US11687057

申请日：2007-03-16

申请人： Jie Liu ,  Anil Duggal ,  Qing Ye ,  Kyle Litz

发明人： Jie Liu ,  Anil Duggal ,  Qing Ye ,  Kyle Litz

IPC分类号： H01J63/04 ,  C08F4/72 ,  C08G65/34 ,  C09K11/06

CPC分类号： C09K11/06 ,  C09K2211/1029 ,  C09K2211/185 ,  H01L51/004 ,  H01L51/0043 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14

摘要： An organic composite comprising an electroactive material and an organic phosphorescent dye. The electroactive material and organic phosphorescent dye have been functionalized in order that when they are mixed together and a curing amount of radiation or heat is applied, the phosphorescent dye is covalently bonded to the crosslinked electroactive material. The method to prepare the organic composite is given. The invention is suitable for the mass production of any light management system. In one embodiment light emitting diodes are described.

摘要翻译： 一种包含电活性材料和有机磷光染料的有机复合材料。 电活性材料和有机磷光染料已经被官能化，以便当将它们混合在一起并施加固化量的辐射或热时，磷光染料共价键合到交联的电活性材料上。 给出了制备有机复合材料的方法。 本发明适用于批量生产任何光管理系统。 在一个实施例中描述了发光二极管。

公开(公告)号：US20070215865A1

公开(公告)日：2007-09-20

申请号：US11384770

申请日：2006-03-20

申请人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

发明人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

IPC分类号： H01L51/00 ,  H01L51/54

CPC分类号： H05B33/14 ,  H01G9/2004 ,  H01L51/0037 ,  H01L51/5032 ,  H01L51/5231 ,  Y02E10/542

摘要： Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic phosphonium salt. In certain embodiments, the organic phosphonium salt has structure (I) wherein R1-R4 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical is disclosed and wherein X− is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.

摘要翻译： 本文描述的是一种有机光电子器件，其包括：包含至少一种零价金属的阴极; 阳极; 光电活性有机材料; 其中所述阴极与至少一种有机鏻盐接触。 在某些实施方案中，有机鏻盐具有结构（I），其中R 1至R 4各自独立地为C 1 -C 3 20脂肪族基团，C 3 -C 20脂环族基团或C 3 -C 20脂肪族基团， 20芳族基团，其中X - 选自一价无机阴离子，一价有机阴离子，多价无机阴离子，多价有机阴离子及其混合物。

公开(公告)号：US20070215879A1

公开(公告)日：2007-09-20

申请号：US11384769

申请日：2006-03-20

申请人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

发明人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

IPC分类号： H01L33/00 ,  C09K9/00

CPC分类号： C09K9/02 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1044 ,  H01G9/2059 ,  H01L51/4206 ,  H01L51/5032 ,  H01L51/5221 ,  Y02E10/542

摘要： Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic ammonium salt. In certain embodiments, the organic ammonium salt has structure (I) wherein R1-R4 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical is disclosed and wherein X+ is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.

摘要翻译： 本文描述的是一种有机光电子器件，其包括：包含至少一种零价金属的阴极; 阳极; 光电活性有机材料; 其中所述阴极与至少一种有机铵盐接触。 在某些实施方案中，有机铵盐具有结构（I），其中R 1至R 4各自独立地为C 1 -C 3 20脂肪族基团，C 3 -C 20脂环族基团或C 3 -C 20脂肪族基团， 20芳族基团，其中X +选自一价无机阴离子，一价有机阴离子，多价无机阴离子，多价有机阴离子及其混合物。

公开(公告)号：US20060152149A1

公开(公告)日：2006-07-13

申请号：US11326949

申请日：2006-01-06

申请人： Kyle Litz ,  James Cella ,  Qing Ye

发明人： Kyle Litz ,  James Cella ,  Qing Ye

IPC分类号： H01J1/62 ,  C08F230/04 ,  C07F15/00

CPC分类号： C07D487/22

摘要： Novel metal porphyrin compositions useful as organic phosphors are provided. The novel compositions are prepared from commercially available porphyrin-containing starting materials. In one instance a novel palladium-containing porphyrin composition having a number average molecular weight of greater than 12,000 grams per mole was prepared from 5,10,15,20-tetrakis(3′,5′-di(hydroxy)phenyl)-21H-23H-porphyrin by reaction first with palladium(II) acetylacetonate, followed by reaction with 2-bromo-2-methylpropionyl bromide, and subsequent group transfer reaction of the alpha-bromo ester groups with 9,9-dioctyl-2-vinylfluorene in the presence of CuBr as a radical initiator. The product polymer exhibited a number average molecular weight of 12,884 grams per mole, a weight average molecular weight of 14,338 grams per mole, and a robust red phosphorescent emission. Porphyrin containing copoylmers comprising structural units derived from 9,9-dioctyl-2-vinylfluorene and 9-anthracenylmethyl methacrylate were prepared in a similar fashion.

摘要翻译： 提供了可用作有机磷光体的新型金属卟啉组合物。 该新型组合物由市售的含卟啉原料制备。 在一种情况下，从5,10,15,20-四（3'，5'-二（羟基）苯基）-21H（5'）中制备数均分子量大于12,000克/摩尔的新颖的含钯卟啉组合物 -23H-卟啉通过首先与乙酰丙酮钯（II）反应，随后与2-溴-2-甲基丙酰溴反应，随后将α-溴酯基与9,9-二辛基-2-乙烯基芴的组转移反应 存在CuBr作为自由基引发剂。 产物聚合物的数均分子量为12,884克/摩尔，重均分子量为14,338克/摩尔，并具有坚固的红色磷光发射。 含有衍生自9,9-二辛基-2-乙烯基芴和9-蒽基甲基甲基丙烯酸酯的结构单元的含卟啉的共聚酰基酯以类似的方式制备。

公开(公告)号：US08101699B2

公开(公告)日：2012-01-24

申请号：US12326115

申请日：2008-12-02

申请人： Qing Ye ,  Jie Liu ,  James Anthony Cella ,  Eisaku Katoh

发明人： Qing Ye ,  Jie Liu ,  James Anthony Cella ,  Eisaku Katoh

IPC分类号： C08F26/06

CPC分类号： C08F12/26 ,  C08F12/32 ,  C08F112/14 ,  H01L51/0003 ,  H01L51/004 ,  H01L51/0042 ,  H01L51/5012

摘要： The invention relates to polymers useful in optoelectronic devices and comprising structural unit of formula I: wherein R1 and R2 are independently at each occurrence, hydrogen, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; R3 is H or alkyl; a and b are, independently at each occurrence 0, or an integer ranging from 1 to 3; and Ar is a direct bond or aryl.

摘要翻译： 本发明涉及可用于光电子器件的聚合物，其包含式I的结构单元：其中R 1和R 2在每次出现时独立地为氢，C 1 -C 20脂族基，C 3 -C 20芳族基或C 3 -C 20环脂族基 ; R3是H或烷基; a和b各自独立地为0或1至3的整数; 并且Ar是直接键或芳基。

公开(公告)号：US08062768B2

公开(公告)日：2011-11-22

申请号：US12125296

申请日：2008-05-22

申请人： Yangang Liang ,  Shengxia Liu ,  Kelly Scott Chichak ,  Qing Ye ,  Jie Liu

发明人： Yangang Liang ,  Shengxia Liu ,  Kelly Scott Chichak ,  Qing Ye ,  Jie Liu

IPC分类号： H01L51/54 ,  C09K11/06 ,  C07D213/02 ,  C07D401/10 ,  C07D401/14 ,  C07D405/14

CPC分类号： C07D405/10 ,  C07D213/06 ,  C07D213/127 ,  C07D213/30 ,  C07D213/643 ,  C07D401/10 ,  Y10S428/917

摘要： Organic compounds of formula I may be used in optoelectronic devices wherein R1 is, independently at each occurrence, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; R2 is, independently at each occurrence, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; b is, independently at each occurrence, an integer ranging from 0-3; Ar1 is a direct bond or heteroaryl, aryl, or alkyl or cycloalkyl; Ar2 is heteroaryl, aryl, or alkyl or cycloalkyl; c is 0, 1 or 2; and n is an integer ranging from 2-4.

摘要翻译： 式I的有机化合物可用于光电子器件，其中R 1在每次出现时独立地为C 1 -C 20脂族基，C 3 -C 20芳族基或C 3 -C 20脂环族基; R 2在每次出现时独立地为C 1 -C 20脂族基团，C 3 -C 20芳族基团或C 3 -C 20脂环族基团; a在每次出现时独立地为0-4的整数; b在每次出现时独立地为0-3的整数; Ar1是直接键或杂芳基，芳基或烷基或环烷基; Ar 2是杂芳基，芳基或烷基或环烷基; c为0,1或2; n为2-4的整数。

公开(公告)号：US07955720B2

公开(公告)日：2011-06-07

申请号：US12810197

申请日：2008-12-06

申请人： Qing Ye ,  Jie Liu ,  Yangang Liang ,  Shengxia Liu

发明人： Qing Ye ,  Jie Liu ,  Yangang Liang ,  Shengxia Liu

IPC分类号： C09K11/02

CPC分类号： H01L51/0085 ,  C08F26/06 ,  C08F126/06 ,  C08F226/06 ,  C09K11/06 ,  C09K2211/1466 ,  H01L51/004 ,  H01L51/0043 ,  H05B33/14

摘要： The invention relates to a polymer comprising structural unit of formula II: wherein R1, R2, R3, R4, R5, R6 and R7 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; a, b, d, e and f are independently at each occurrence 0, or an integer ranging from 1 to 4; c and g are independently at each occurrence 0, or an integer ranging from 1 to 3. In another aspect, the invention relates to monomers for preparing the polymers. In yet another aspect, the invention relates to an optical electronic device comprising a polymer comprising structural unit of formula II.

摘要翻译： 本发明涉及包含式II结构单元的聚合物：其中R1，R2，R3，R4，R5，R6和R7在每次出现时独立地为C1-C20脂族基团，C3-C20芳族基团或C3- C20脂环族基; a，b，d，e和f各自独立地为0或1〜4的整数; c和g在每次出现时独立地为0，或整数为1至3.在另一方面，本发明涉及用于制备聚合物的单体。 在另一方面，本发明涉及一种光学电子器件，其包括含有式II结构单元的聚合物。

公开(公告)号：US20110121235A1

公开(公告)日：2011-05-26

申请号：US13055121

申请日：2009-06-05

申请人： Qing Ye ,  Jie Liu

发明人： Qing Ye ,  Jie Liu

IPC分类号： C09K11/06 ,  C07F5/02

CPC分类号： C07F5/027 ,  Y10S428/917

摘要： Compounds of formula I may be used in optoelectronic devices wherein R1 is, independently at each occurrence, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; b is 0, 1 or 2; Ar1 is a direct bond or heteroaryl, aryl, or alkyl or cycloalkyl; Ar2 is heteroaryl, aryl, or alkyl or cycloalkyl; c is an integer ranging from 1-7; and n is an integer ranging from 2-4.

摘要翻译： 式I化合物可用于光电器件，其中R 1在每次出现时独立地为C 1 -C 20脂族基团，C 3 -C 20芳族基团或C 3 -C 20脂环族基团; a在每次出现时独立地为0-4的整数; b为0,1或2; Ar1是直接键或杂芳基，芳基或烷基或环烷基; Ar 2是杂芳基，芳基或烷基或环烷基; c为1-7的整数; n为2-4的整数。

公开(公告)号：US07740942B2

公开(公告)日：2010-06-22

申请号：US11610076

申请日：2006-12-13

申请人： Qing Ye ,  Jie Liu ,  Joyce Hung

发明人： Qing Ye ,  Jie Liu ,  Joyce Hung

IPC分类号： B29C39/00

CPC分类号： H01L51/0035 ,  C08F226/02 ,  H01L51/0043 ,  H01L51/5088 ,  Y10S428/917 ,  Y10T428/24 ,  Y10T428/31533 ,  Y10T428/31721

摘要： The invention provides an opto-electronic device comprising at least one sulfonated aromatic condensation copolymer or at least one phosphonated aromatic condensation copolymer. The at least one sulfonated aromatic condensation copolymer is selected from sulfonated polyarylethers, sulfonated polyimides, sulfonated polyphenylene oxides, sulfonated polyarylenes, sulfonated polyphosphazenes, and the at least one phosphonated aromatic condensation copolymer is selected from phosphonated polyarylethers, phosphonated polyimides, phosphonated polyphenylene oxides, phosphonated polyarylenes, phosphonated polyphosphazenes and combinations thereof. The sulfonated polyarylether is a sulfonated polyarylether block copolymer having sulfonated polyaryletherketone blocks, sulfonated polyethersulfone blocks, or combinations thereof.

摘要翻译： 本发明提供了包含至少一种磺化芳族缩合共聚物或至少一种膦酸化芳族缩合共聚物的光电装置。 所述至少一种磺化芳族缩合共聚物选自磺化聚芳基醚，磺化聚酰亚胺，磺化聚苯醚，磺化聚亚芳基，磺化聚磷腈，并且所述至少一种膦酸化芳族缩合共聚物选自膦酸化的聚芳基醚，膦酸化的聚酰亚胺，膦酸化的聚苯醚，磷酸化的 聚亚芳基，膦酸化聚磷腈及其组合。 磺化聚芳基醚是具有磺化聚芳醚酮嵌段，磺化聚醚砜嵌段或其组合的磺化聚芳醚嵌段共聚物。

公开(公告)号：US20080145665A1

公开(公告)日：2008-06-19

申请号：US11610032

申请日：2006-12-13

申请人： Qing Ye ,  Jie Liu ,  James Anthony Cella ,  Kyle Erik Litz ,  Joseph John Shiang

发明人： Qing Ye ,  Jie Liu ,  James Anthony Cella ,  Kyle Erik Litz ,  Joseph John Shiang

IPC分类号： B32B27/36 ,  B32B27/00 ,  C08F26/12

CPC分类号： C07D209/88 ,  C08G63/6854 ,  C08G64/12 ,  C08G73/1046 ,  C08G73/1085 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5012 ,  Y10T428/31507 ,  Y10T428/31721 ,  Y10T428/31786

摘要： The invention relates to compounds of formula I wherein R1, R2, and R4 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; R3 and R5 are independently at each occurrence hydrogen, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; and a, b and d are independently 0 or an integer ranging from 1 to 3. The invention further relates to polymers derived from compounds of formula I. The polymers may be polyesters, polyethers, polycarbonates, polyestercarbonates, polyetherketones, or polyethersulfones. Compounds and polymers of the invention find use in light emitting devices.

摘要翻译： 本发明涉及式I化合物，其中R 1，R 2，R 4和R 4各自独立地为C 1 C 20 -C 20脂肪族基团，C 3 -C 20芳族基团或C 3 H 3 -C 20脂环族基团; R 3和R 5在每次出现时独立地为氢，C 1 -C 20脂族基团， C 3 -C 20芳族基团或C 3 -C 20脂环族基团; C 3 -C 20芳族基团或C 3 -C 20 -C 20脂环族基团; 并且a，b和d独立地为0或1至3的整数。本发明还涉及衍生自式I化合物的聚合物。聚合物可以是聚酯，聚醚，聚碳酸酯，聚酯碳酸酯，聚醚酮或聚醚砜。 本发明的化合物和聚合物可用于发光器件。