公开(公告)号：US20060021647A1

公开(公告)日：2006-02-02

申请号：US10900624

申请日：2004-07-28

申请人： John Gui ,  James Spivack ,  Anil Duggal ,  James Cella ,  Azar Alizadeh ,  Aharon Yakimov

发明人： John Gui ,  James Spivack ,  Anil Duggal ,  James Cella ,  Azar Alizadeh ,  Aharon Yakimov

IPC分类号： H01L21/00 ,  H01L31/00

CPC分类号： H01L51/4253 ,  B82Y10/00 ,  B82Y30/00 ,  H01L51/0034 ,  H01L51/0045 ,  H01L51/005 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0595 ,  H01L51/4206 ,  H01L51/426 ,  Y02E10/549 ,  Y02P70/521

摘要： Disclosed herein is a photovoltaic cell comprising an absorber that can absorb electromagnetic radiation; a first substrate comprising a first conductive surface; a second substrate comprising a second conductive surface that is opposed to the first conductive surface and faces the first conductive surface of the first substrate; an electron transporter that is in electrical communication with the second conductive surface of the second substrate, but is electrically insulated from the first substrate; a hole transporter that is in electrical communication with the first conductive surface of the first substrate, but is electrically insulated from the second substrate; wherein the hole transporter and/or the electron transporter are chemically bonded to an electrically insulating sheath; and wherein the hole transporter and/or the electron transporter are chemically bonded to the absorber.

摘要翻译： 本文公开了一种光伏电池，其包括可吸收电磁辐射的吸收体; 第一基板，包括第一导电表面; 第二基板，包括与第一导电表面相对并面向第一基板的第一导电表面的第二导电表面; 电子输送器，其与第二基板的第二导电表面电连通，但与第一基板电绝缘; 孔传送器，其与第一基板的第一导电表面电连通，但与第二基板电绝缘; 其中所述空穴传输体和/或电子转运体化学键合到电绝缘鞘; 并且其中所述空穴传输体和/或电子转运体化学键合到所述吸收体。

公开(公告)号：US20070215879A1

公开(公告)日：2007-09-20

申请号：US11384769

申请日：2006-03-20

申请人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

发明人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

IPC分类号： H01L33/00 ,  C09K9/00

CPC分类号： C09K9/02 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1044 ,  H01G9/2059 ,  H01L51/4206 ,  H01L51/5032 ,  H01L51/5221 ,  Y02E10/542

摘要： Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic ammonium salt. In certain embodiments, the organic ammonium salt has structure (I) wherein R1-R4 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical is disclosed and wherein X+ is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.

摘要翻译： 本文描述的是一种有机光电子器件，其包括：包含至少一种零价金属的阴极; 阳极; 光电活性有机材料; 其中所述阴极与至少一种有机铵盐接触。 在某些实施方案中，有机铵盐具有结构（I），其中R 1至R 4各自独立地为C 1 -C 3 20脂肪族基团，C 3 -C 20脂环族基团或C 3 -C 20脂肪族基团， 20芳族基团，其中X +选自一价无机阴离子，一价有机阴离子，多价无机阴离子，多价有机阴离子及其混合物。

公开(公告)号：US20070215865A1

公开(公告)日：2007-09-20

申请号：US11384770

申请日：2006-03-20

申请人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

发明人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

IPC分类号： H01L51/00 ,  H01L51/54

CPC分类号： H05B33/14 ,  H01G9/2004 ,  H01L51/0037 ,  H01L51/5032 ,  H01L51/5231 ,  Y02E10/542

摘要： Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic phosphonium salt. In certain embodiments, the organic phosphonium salt has structure (I) wherein R1-R4 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical is disclosed and wherein X− is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.

摘要翻译： 本文描述的是一种有机光电子器件，其包括：包含至少一种零价金属的阴极; 阳极; 光电活性有机材料; 其中所述阴极与至少一种有机鏻盐接触。 在某些实施方案中，有机鏻盐具有结构（I），其中R 1至R 4各自独立地为C 1 -C 3 20脂肪族基团，C 3 -C 20脂环族基团或C 3 -C 20脂肪族基团， 20芳族基团，其中X - 选自一价无机阴离子，一价有机阴离子，多价无机阴离子，多价有机阴离子及其混合物。

公开(公告)号：US20060131567A1

公开(公告)日：2006-06-22

申请号：US11110276

申请日：2005-04-19

申请人： Jie Liu ,  Larry Lewis ,  Anil Duggal ,  Kyle Litz ,  James Cella ,  Joseph Shiang ,  Tami Faircloth

发明人： Jie Liu ,  Larry Lewis ,  Anil Duggal ,  Kyle Litz ,  James Cella ,  Joseph Shiang ,  Tami Faircloth

IPC分类号： H01B1/12 ,  H01L51/50 ,  H05B33/26

CPC分类号： H01L51/0043 ,  H01L51/0021 ,  H01L51/0035 ,  H01L51/0039 ,  H01L51/0094 ,  H01L51/5092 ,  H01L51/5221 ,  Y02E10/549 ,  Y10T428/31504 ,  Y10T428/31663

摘要： An electrooptic device and a surface modified electrode comprising a reduced organic material are provided. The reduced organic materials lower the work function of an electrode surface; they are also electro-active. These capabilities facilitate their use in production of more efficient electrooptic devices. The electrooptic device has at least a first conductive layer, a second conductive layer, and an electro-active layer comprising the reduced organic material disposed between the first and second conductive layers. The surface modified electrode comprises at least one conductive layer and at least one reduced organic material disposed upon a surface of said conductive layer. Methods for using the organic electro-active material for producing electrooptic devices, and operating the electrooptic devices are also disclosed. Coating compositions and coated articles comprising the reduced organic materials are also provided.

摘要翻译： 提供电光装置和包含还原有机材料的表面改性电极。 还原的有机材料降低了电极表面的功函数; 它们也是电活动的。 这些功能便于其在生产更高效的电光设备中使用。 电光装置具有至少第一导电层，第二导电层和包含设置在第一和第二导电层之间的还原有机材料的电活性层。 表面改性电极包括至少一个导电层和设置在所述导电层的表面上的至少一个还原的有机材料。 还公开了使用有机电活性材料制造电光装置和操作电光装置的方法。 还提供了包含还原的有机材料的涂料组合物和涂层制品。

公开(公告)号：US20050256290A1

公开(公告)日：2005-11-17

申请号：US11170423

申请日：2005-06-29

申请人： James Cella ,  Joseph Shiang ,  Christian Heller ,  Kyle Litz ,  Jie Liu ,  Larry Lewis ,  Gautam Parthasarathy ,  Anil Duggal ,  David Simon

发明人： James Cella ,  Joseph Shiang ,  Christian Heller ,  Kyle Litz ,  Jie Liu ,  Larry Lewis ,  Gautam Parthasarathy ,  Anil Duggal ,  David Simon

IPC分类号： C07C29/40 ,  C07C29/44 ,  C07C39/17 ,  C08G61/02 ,  C08G61/12 ,  C09K11/06 ,  H01L51/00 ,  H05B33/14 ,  C08G61/00 ,  C08G64/00 ,  C08G65/00 ,  C08G77/00

CPC分类号： H01L51/0039 ,  C07C29/40 ,  C07C37/18 ,  C07C37/20 ,  C07C39/17 ,  C07C39/42 ,  C07C2603/18 ,  C07C2603/24 ,  C07C2603/94 ,  C08G61/02 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1416 ,  H01L51/0058 ,  H01L51/5036 ,  H01L51/5048 ,  H05B33/14 ,  Y02E10/549 ,  C07C35/52

摘要： Disclosed is a polymer composition derived from a bis-phenol comprising a conjugated aromatic radical, optionally comprising nitrogen. Suitable bis-phenols as well as methods for making said polymer are also disclosed. Also disclosed are electroactive layers comprising said polymer and electroactive devices comprising said layer.

摘要翻译： 公开了衍生自包含共轭芳族基团，任选地包含氮的双酚的聚合物组合物。 还公开了合适的双酚以及制备所述聚合物的方法。 还公开了包含所述聚合物和包含所述层的电活性器件的电活性层。

公开(公告)号：US20050164019A1

公开(公告)日：2005-07-28

申请号：US10761696

申请日：2004-01-22

申请人： Jie Liu ,  Anil Duggal ,  Larry Lewis ,  Daniel Colombo ,  James Cella ,  Joseph Shiang

发明人： Jie Liu ,  Anil Duggal ,  Larry Lewis ,  Daniel Colombo ,  James Cella ,  Joseph Shiang

IPC分类号： H01L51/50 ,  B32B15/08 ,  C07C15/28 ,  C07F1/04 ,  C07F7/18 ,  C09K11/06 ,  H01B1/00 ,  H05B33/00 ,  H05B33/14 ,  H05B33/22

CPC分类号： C07F7/1804 ,  Y10T428/31529 ,  Y10T428/31663 ,  Y10T428/31678

摘要： A charge transfer-promoting material comprises a material having a formula selected from the group consisting of AM, An−Mn+ and {A-R3}n−Mn+; wherein A is a fused ring radical having from 2 to 4 rings, inclusive; crown ethers; cryptands; or macrocyclic polyamines; M is a metal; R3 is selected from the group consisting of alkoxy silane, carboxylic acid, thiol, amine, phosphine, amide, imine, ester, anhydride, and epoxy, and is covalently attached to A; and n is an integer number selected from the group consisting of 1, 2, and 3. Electronic devices comprise such a charge transfer-promoting material for enhancing the charge injection or transport between an electrode and an electronically active material.

摘要翻译： 电荷转移促进材料包括具有选自AM，A，N，N，N +和/ n M + n + 其中A是具有2至4个环的稠环基团，包括端值; 冠醚; 穴居人 或大环多胺; M是金属; R 3选自烷氧基硅烷，羧酸，硫醇，胺，膦，酰胺，亚胺，酯，酸酐和环氧基，并且共价连接到A上; 并且n是选自1,2和3的整数。电子器件包括用于增强电极和电子活性材料之间的电荷注入或传输的这种电荷转移促进材料。

公开(公告)号：US20070128465A1

公开(公告)日：2007-06-07

申请号：US11295768

申请日：2005-12-05

申请人： Jie Liu ,  James Cella ,  Min Yan ,  Anil Duggal ,  Gautam Parthasarathy ,  Svetlana Rogojevic ,  Michael Herzog

发明人： Jie Liu ,  James Cella ,  Min Yan ,  Anil Duggal ,  Gautam Parthasarathy ,  Svetlana Rogojevic ,  Michael Herzog

IPC分类号： B32B9/00 ,  H01B5/00 ,  H01L51/50

CPC分类号： H01L51/5048 ,  H01B1/06 ,  H01L51/0059 ,  H01L51/5221 ,  H01L2251/5323 ,  H05B33/28 ,  Y10T428/31938

摘要： Described herein is a transparent electrode comprising at least one optically transparent electrically conductive layer; and at least one optically transparent intermediate layer, wherein said optically transparent conductive layer is in contact with said optically intermediate layer, and wherein said optically transparent conductive layer and said optically transparent intermediate layer together transmit at least 50 percent of incident light having a wavelength in a range between about 200 and about 1200 nanometers, said optically transparent conductive layer having a bulk conductivity at least 100 Siemens per centimeter (S/cm), said optically transparent intermediate layer being comprised of a material having a bulk electrical conductivity at room temperature less than 10−12 Siemens per centimeter and a band gap of 3.5 eV. Described herein are also methods for forming a transparent electrode, and transparent electronic devices comprising at least one transparent electrode.

摘要翻译： 本文描述的是包括至少一个光学透明导电层的透明电极; 以及至少一个光学透明中间层，其中所述光学透明导电层与所述光学中间层接触，并且其中所述光学透明导电层和所述光学透明中间层一起将具有波长的入射光的至少50％ 在约200和约1200纳米之间的范围内，所述光学透明导电层的体积电导率至少为100西门子每厘米（S / cm），所述光学透明中间层由在室温下具有体积电导率的材料组成 每厘米超过10西门子，3.5V的带隙。 这里也描述了形成透明电极的方法和包括至少一个透明电极的透明电子器件。

公开(公告)号：US20060152149A1

公开(公告)日：2006-07-13

申请号：US11326949

申请日：2006-01-06

申请人： Kyle Litz ,  James Cella ,  Qing Ye

发明人： Kyle Litz ,  James Cella ,  Qing Ye

IPC分类号： H01J1/62 ,  C08F230/04 ,  C07F15/00

CPC分类号： C07D487/22

摘要： Novel metal porphyrin compositions useful as organic phosphors are provided. The novel compositions are prepared from commercially available porphyrin-containing starting materials. In one instance a novel palladium-containing porphyrin composition having a number average molecular weight of greater than 12,000 grams per mole was prepared from 5,10,15,20-tetrakis(3′,5′-di(hydroxy)phenyl)-21H-23H-porphyrin by reaction first with palladium(II) acetylacetonate, followed by reaction with 2-bromo-2-methylpropionyl bromide, and subsequent group transfer reaction of the alpha-bromo ester groups with 9,9-dioctyl-2-vinylfluorene in the presence of CuBr as a radical initiator. The product polymer exhibited a number average molecular weight of 12,884 grams per mole, a weight average molecular weight of 14,338 grams per mole, and a robust red phosphorescent emission. Porphyrin containing copoylmers comprising structural units derived from 9,9-dioctyl-2-vinylfluorene and 9-anthracenylmethyl methacrylate were prepared in a similar fashion.

摘要翻译： 提供了可用作有机磷光体的新型金属卟啉组合物。 该新型组合物由市售的含卟啉原料制备。 在一种情况下，从5,10,15,20-四（3'，5'-二（羟基）苯基）-21H（5'）中制备数均分子量大于12,000克/摩尔的新颖的含钯卟啉组合物 -23H-卟啉通过首先与乙酰丙酮钯（II）反应，随后与2-溴-2-甲基丙酰溴反应，随后将α-溴酯基与9,9-二辛基-2-乙烯基芴的组转移反应 存在CuBr作为自由基引发剂。 产物聚合物的数均分子量为12,884克/摩尔，重均分子量为14,338克/摩尔，并具有坚固的红色磷光发射。 含有衍生自9,9-二辛基-2-乙烯基芴和9-蒽基甲基甲基丙烯酸酯的结构单元的含卟啉的共聚酰基酯以类似的方式制备。

公开(公告)号：US20050258407A1

公开(公告)日：2005-11-24

申请号：US11189911

申请日：2005-07-26

申请人： James Cella ,  Rachid Kerboua

发明人： James Cella ,  Rachid Kerboua

IPC分类号： C08G64/04 ,  F21V9/00

CPC分类号： C08G64/045

摘要： Crosslinking between polymer chains having olefin groups occurs by heating the polymer chains in the presence of a catalyst. Mixtures of polymer and catalyst can be dried and cast into films at ambient temperatures and remain non-crosslinked and soluble for extended periods. However, upon heating of the polymer to temperatures of about 300° C. or greater in the presence of a catalyst, the polymer chains of the film are cured to produce an insoluble crosslinked matrix. The sudden and relatively complete nature of the crosslinking between the polymers under specific conditions is particularly useful to allow chromophores poled in a noncrosslinked polymer mixture to retain their uniform orientation after crosslinking has occurred.

摘要翻译： 在具有烯烃基团的聚合物链之间的交联通过在催化剂存在下加热聚合物链而发生。 聚合物和催化剂的混合物可以在环境温度下干燥并浇注成膜，并保持非交联并长时间溶解。 然而，当在催化剂存在下将聚合物加热到约300℃或更高的温度时，该膜的聚合物链被固化以产生不溶的交联基质。 在特定条件下聚合物之间交联的突然且相对完整的性质特别有用，以使非交联聚合物混合物中的发色团保持其交联发生后的均匀取向。

公开(公告)号：US20070225464A1

公开(公告)日：2007-09-27

申请号：US11748195

申请日：2007-05-14

申请人： Larry Lewis ,  Kelly Chichak ,  James Cella ,  Joseph Shiang

发明人： Larry Lewis ,  Kelly Chichak ,  James Cella ,  Joseph Shiang

IPC分类号： C08G77/04 ,  C08L83/04

CPC分类号： C08G77/58 ,  G02B1/043 ,  C08L83/04

摘要： Optoelectronic devices include polysiloxanes derived from hydrosilation of an organometallic compound of formula L2MZ, wherein L and Z are independently bidentate ligands; at least one of L and Z comprises alkenyl, alkenylaryl, alkenyloxy, alkenyloxyaryl, alkynyl, alkynylaryl, alkynyloxy, alkynyloxyaryl, substituted alkenyl, substituted alkenylaryl, substituted alkenyloxy, substituted alkenyloxyaryl, substituted alkynyl, substituted alkynylaryl, substituted alkynyloxy, substituted alkynyloxyaryl, acrylate, methacrylate, or a combination thereof; and M is Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Ga, Ge, In, Sn, Sb, Tl, Pd, Bi, Po, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu.

摘要翻译： 光电器件包括衍生自式L 2 MZ的有机金属化合物的硅氢化的聚硅氧烷，其中L和Z独立地是二齿配体; L和Z中的至少一个包括烯基，烯基芳基，烯氧基，烯基氧基芳基，炔基，炔基芳基，炔氧基，炔氧基芳基，取代的烯基，取代的烯基芳基，取代的烯氧基，取代的烯基氧基芳基，取代的炔基，取代的炔基芳基，取代的炔氧基，取代的炔氧基芳基，丙烯酸酯， 甲基丙烯酸酯或其组合; 并且M是Zr，Nb，Mo，Tc，Ru，Rh，Pd，Ag，Cd，Hf，Ta，W，Re，Os，Ir，Pt，Au，Hg，Ga，Ge，In，Sn，Sb， ，Pd，Bi，Po，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb或Lu。