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    Alpha-hydroxyketones
    2.
    发明授权
    Alpha-hydroxyketones 有权
    α-羟基酮

    公开(公告)号：US09199934B2

    公开(公告)日：2015-12-01

    申请号：US12593025

    申请日：2008-03-25

    申请人： Kurt Dietliker ,  Peter Murer ,  Rinaldo Hüsler ,  Tunja Jung

    发明人： Kurt Dietliker ,  Peter Murer ,  Rinaldo Hüsler ,  Tunja Jung

    IPC分类号： G03F7/004 ,  C07C69/95 ,  C07D307/00 ,  C07D211/32 ,  G03F7/38 ,  G03F7/40 ,  C07C49/83 ,  C07C49/835 ,  C07C49/84 ,  C07C62/38 ,  C07C69/757 ,  C07C219/12 ,  C07C235/82 ,  C07D295/185 ,  C07D305/12 ,  C07F7/08 ,  C07F7/18

    CPC分类号： C07D211/32 ,  C07C49/83 ,  C07C49/835 ,  C07C49/84 ,  C07C62/38 ,  C07C69/757 ,  C07C219/12 ,  C07C235/82 ,  C07C2601/14 ,  C07D295/185 ,  C07D305/12 ,  C07F7/0836 ,  C07F7/0838 ,  C07F7/1804 ,  G03F7/004 ,  G03F7/38 ,  G03F7/40

    摘要： Compounds of the Formula (I) wherein x is an integer from 1-4; p is an integer from 1-3; q is an integer from 0-3; Ar is phenyl, naphthyl, anthryl or phenanthryl each of which optionally is substituted by one or more Cl, CN, OR5, C3-C5alkenyl or C1-C6alkyl which optionally is substituted by one or more OR6, COOR or halogen; R1 if x is 1, is OR7, O—X+, NR8R9, C1-C20alkyl optionally substituted by one or more COOR10, or is C2-C20alkyl interrupted by one ore more O, or is C2-C5alkenyl or phenyl-C1-C4alkyl; R1 if x is 2, is for example C1-C20alkylene; R1 if x is 3, is for example a tri-valent radical; R1 if x is 4, is for example a tetravalent radical; R2 and R3 are hydrogen or C1-C8alkyl, or R2 and R3 together are O, C1-C3alkylene or CH═CH; R4 is C1-C4alkyl; R5, R6, R7, R8, R9 and R10 are for example hydrogen or C1-C4alkyl; and X is a x-valent cationic counter ion; are in particular suitable as photoinitiators for the curing with UV-A light (320-450 nm).

    摘要翻译： 式（I）的化合物，其中x为1-4的整数; p是1-3的整数; q是0-3的整数; Ar是苯基，萘基，蒽基或菲基，其各自任选被一个或多个被一个或多个OR 6，COOR或卤素取代的C 1，CN，OR 5，C 3 -C 5链烯基或C 1 -C 6烷基取代; R 1如果x是1，是OR 7，O-X +，NR 8 R 9，任选被一个或多个COOR 10取代的C 1 -C 20烷基，或者是被一个或多个O取代的C 2 -C 20烷基，或者是C 2 -C 5烯基或苯基-C 1 -C 4烷基; R1如果x为2，例如为C 1 -C 20亚烷基; 如果x是3，则R1是例如三价基; R1如果x为4，则为例如四价基团; R 2和R 3是氢或C 1 -C 8烷基，或者R 2和R 3一起是O，C 1 -C 3亚烷基或CH = CH; R4是C1-C4烷基; R5，R6，R7，R8，R9和R10是例如氢或C1-C4烷基; X为x-阳离子抗衡离子; 特别适用于用UV-A光（320-450nm）固化的光引发剂。

    ALPHA-HYDROXYKETONES
    3.
    发明申请
    ALPHA-HYDROXYKETONES 有权
    阿尔法羟基酮

    公开(公告)号：US20100104979A1

    公开(公告)日：2010-04-29

    申请号：US12593025

    申请日：2008-03-25

    申请人： Kurt Dietliker ,  Peter Murer ,  Rinaldo Hüsler ,  Tunja Jung

    发明人： Kurt Dietliker ,  Peter Murer ,  Rinaldo Hüsler ,  Tunja Jung

    IPC分类号： G03F7/20 ,  C07C59/76 ,  C07D307/00 ,  C07D305/12 ,  C07F7/08 ,  C07D265/30 ,  C07C69/95 ,  C07D211/06 ,  C07C233/00 ,  G03F7/004 ,  C08F2/46

    CPC分类号： C07D211/32 ,  C07C49/83 ,  C07C49/835 ,  C07C49/84 ,  C07C62/38 ,  C07C69/757 ,  C07C219/12 ,  C07C235/82 ,  C07C2601/14 ,  C07D295/185 ,  C07D305/12 ,  C07F7/0836 ,  C07F7/0838 ,  C07F7/1804 ,  G03F7/004 ,  G03F7/38 ,  G03F7/40

    摘要： Compounds of the Formula (I) wherein x is an integer from 1-4; p is an integer from 1-3; q is an integer from 0-3; Ar is phenyl, naphthyl, anthryl or phenanthryl each of which optionally is substituted by one or more Cl, CN, OR5, C3-C5alkenyl or C1-C6alkyl which optionally is substituted by one or more OR6, COOR or halogen; R1 if x is 1, is ORS, O—X+, NR8R9, C1-C20alkyl optionally substituted by one or more COOR10, or is C2-C20alkyl interrupted by one ore more O, or is C2-C5alkenyl or phenyl-C1-C4alkyl; R1 if x is 2, is for example C1-C20alkylene; R1 if x is 3, is for example a tri-valent radical; R1if x is 4, is for example a tetravalent radical; R2and R3are hydrogen or C1-C8alkyl, or R2and R3 together are O, C1-C3alkylene or CH═CH; R4 is C1-C4alkyl; R5, R6, R7, R8, R9 and R10 are for example hydrogen or C1-C4alkyl; and X is a x-valent cationic counter ion; are in particular suitable as photoinitiators for the curing with UV-A light (320-450 nm).

    摘要翻译： 式（I）的化合物，其中x是1-4的整数; p是1-3的整数; q是0-3的整数; Ar是苯基，萘基，蒽基或菲基，其各自任选被一个或多个被一个或多个OR 6，COOR或卤素取代的C 1，CN，OR 5，C 3 -C 5链烯基或C 1 -C 6烷基取代; R 1如果x是1，是ORS，O-X +，NR 8 R 9，任选被一个或多个COOR 10取代的C 1 -C 20烷基，或是被一个或多个O取代的C 2 -C 20烷基，或者是C 2 -C 5烯基或苯基-C 1 -C 4烷基; R1如果x为2，例如为C 1 -C 20亚烷基; 如果x是3，则R1是例如三价基; R1if x为4，例如为四价基团; R 2和R 3为氢或C 1 -C 8烷基，或R 2和R 3一起为O，C 1 -C 3亚烷基或CH = CH; R4是C1-C4烷基; R5，R6，R7，R8，R9和R10是例如氢或C1-C4烷基; X为x-阳离子抗衡离子; 特别适用于用UV-A光（320-450nm）固化的光引发剂。

    N-substituted imides as polymerization initiators
    5.
    发明授权
    N-substituted imides as polymerization initiators 有权
    N-取代酰亚胺作为聚合引发剂

    公开(公告)号：US07723399B2

    公开(公告)日：2010-05-25

    申请号：US11666887

    申请日：2005-10-31

    申请人： Peter Nesvadba ,  Johannes Benkhoff ,  Lucienne Bugnon ,  Karin Powell ,  Tunja Jung

    发明人： Peter Nesvadba ,  Johannes Benkhoff ,  Lucienne Bugnon ,  Karin Powell ,  Tunja Jung

    IPC分类号： C08F299/00 ,  C07D221/04 ,  C07D209/56 ,  C07D209/48

    CPC分类号： C07D207/404 ,  B33Y70/00 ,  C07D207/46 ,  C07D209/48 ,  C07D221/14 ,  C08F4/00

    摘要： The invention relates to novel N-substituted imides and polymerizable compositions comprising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R1 and R2 are each, independently of one another, hydrogen, C1-C18alkyl, C1-C-18alkenyl C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxycarbonyl; or R1 and R2 together with the adjacent —CO—N—CO— group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R3 if n is 1, is C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, OR10 or SR11, NR12R13; wherein R3 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene R4 and R5, correspond to R1 and R2; R6 if n is 1, is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, NR14R15; wherein R6 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene; R7 is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxy-carbonyl; or R7 and R14 or R7 and R15 form together with the N-atom attached to R7 a 5-6 membered ring, optionally interrupted by —NH—, —N(C1-C8alkyl)-, —O— and/or S-atoms.

    摘要翻译： 本发明涉及新型的N-取代的酰亚胺和包含这些N-取代的酰亚胺的可聚合组合物。 本发明还涉及N-取代的酰亚胺作为聚合引发剂的用途。 酰亚胺是式（I）和（II）的化合物，其中n为1或2; m为1或2; R 1和R 2各自独立地为氢，C 1 -C 18烷基，C 1 -C 18烯基C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，其各自可被卤素，C 1 -C 4 - 烷基，羟基，C 1 -C 1-6烷氧基，羰基，C 1 -C 6烷氧基羰基; 或R 1和R 2与相邻的-CO-N-CO-基团一起可以形成单环，双环或多环，所述环具有至多50个非氢原子，并且其中所述环可含有结构单元（式III） 一旦; 如果n为1，R 3为C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，OR 10或SR 11，NR 12 R 13; 其中如果n为2，R 3为C 2 -C 12亚烷基，C 6 -C 14亚芳基，亚二甲苯基R4和R 5对应于R 1和R 2; 如果n为1，R 6为氢，C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，NR 14 R 15; 其中如果n为2，R 6为C 2 -C 12亚烷基，C 6 -C 14亚芳基，亚二甲苯基; R 7是氢，C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，其各自可被卤素，C 1 -C 4 - 烷基，羟基，C 1 -C 6烷氧基，羰基，C 1 -C 6烷氧基 - 羰基取代; 或R 7和R 14或R 7和R 15与连接至R 7的N-原子一起形成5-6元环，任选被-NH-，-N（C 1 -C 8烷基） - ， - 和 - 或S-原子 。

    N-Substituted Imides As Polymerization Initiators
    6.
    发明申请
    N-Substituted Imides As Polymerization Initiators 有权

    公开(公告)号：US20080132600A1

    公开(公告)日：2008-06-05

    申请号：US11666887

    申请日：2005-10-31

    申请人： Peter Nesvadba ,  Johannes Benkhoff ,  Lucienne Bugnon ,  Karin Powell ,  Tunja Jung

    发明人： Peter Nesvadba ,  Johannes Benkhoff ,  Lucienne Bugnon ,  Karin Powell ,  Tunja Jung

    IPC分类号： C08L79/08 ,  C07D209/48 ,  C07D221/06 ,  C07D207/46 ,  C07D209/56

    CPC分类号： C07D207/404 ,  B33Y70/00 ,  C07D207/46 ,  C07D209/48 ,  C07D221/14 ,  C08F4/00

    摘要： The invention relates to novel N-substituted imides and polymerizable compositions comprising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R1 and R2 are each, independently of one another, hydrogen, C1-C18alkyl, C1-C18alkenyl C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxycarbonyl; or R1 and R2 together with the adjacent —CO—N—CO— group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R3 if n is 1, is C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, OR10 or SR11, NR12R13; wherein R3 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene R4 and R5, correspond to R1 and R2; R6 if n is 1, is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, NR14R15; wherein R6 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene; R7 is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxy-carbonyl; or R7 and R14 or R7 and R15 form together with the N-atom attached to R7 a 5-6 membered ring, optionally interrupted by —NH—, —N(C1-C8alkyl)-, —O- and/or S-atoms.

    Photoinitiators
    9.
    发明授权
    Photoinitiators 有权
    光引发剂

    公开(公告)号：US07642296B2

    公开(公告)日：2010-01-05

    申请号：US11578595

    申请日：2005-04-11

    申请人： Rinaldo Hüsler ,  Thomas Horni ,  André Fuchs ,  Tunja Jung ,  Reinhard H. Sommerlade

    发明人： Rinaldo Hüsler ,  Thomas Horni ,  André Fuchs ,  Tunja Jung ,  Reinhard H. Sommerlade

    IPC分类号： C08F2/50 ,  C03C25/10 ,  C07C49/84

    CPC分类号： C07C45/46 ,  B33Y70/00 ,  C07C45/58 ,  C07C45/63 ,  C07C45/64 ,  C07C45/71 ,  C07C45/74 ,  C07C49/792 ,  C07C49/82 ,  C07C49/83 ,  C07C49/84 ,  C07C69/96 ,  C07C271/12 ,  C07C317/24 ,  C07D295/108 ,  C07D295/112 ,  C07D493/08 ,  C08F2/50 ,  C07C49/76 ,  C07C49/80 ,  C07C49/813

    摘要： The invention relates to novel photoinitators of formulae (I), (II), (III), (IV), (V) and (VI) wherein R1 and R2 are each independently of the other C1-C8alkyl; C1-C4alkyl substituted by OH, C1-C4alkoxy, —COO(C1-C8alkyl), (C1-C4alkyl)-COO—, —CN, benzyl, phenyl or by —N(R15)(R16); C3-C6alkerlyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; or R1 and R2 together are unbranched or branched C2-C9alkylene or C3-C6-oxa- or -azaalkylene; R3, R4, R5 and R6 are each independently of the others hydrogen, C1-C8alkyl, C3-C6alkenyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; R3 and R4 together and/or R5 and R6 together are unbranched or branched C2-C9alkylene; A is CI, Br, —O—R9, —N(R11)(R12) or —S—R18, A′ is —O—, —NH— or —NR11—; A″ is CI, Br, —O—R9, —N(R11)(R12) or —S—R18 or hydrogen, X is —O—R10 or —N(R13)(R14), n is an integer from 1 to 10, preferably an integer from 1 to 4, especially 1, 2 or 3; R7 is a linker; R8 is a bivalent C2-C3alkylele radical.

    摘要翻译： 本发明涉及式（I），（II），（III），（IV），（V）和（VI）的新型光引发剂，其中R 1和R 2各自独立地为C 1 -C 8烷基; 被OH，C1-C4烷氧基，-COO（C1-C8烷基），（C1-C4烷基）-COO-，-CN，苄基，苯基或-N（R15）（R16）取代的C1-C4烷基; C3-C6链烯基，苄基，-CH2-C6H4-（C1-C4烷基）或苯基; 或R 1和R 2一起是非支链或支链C 2 -C 9亚烷基或C 3 -C 6 - 氧杂 - 或 - 亚烷基; R 3，R 4，R 5和R 6各自独立地为氢，C 1 -C 8烷基，C 3 -C 6烯基，苄基，-CH 2 -C 6 H 4 - （C 1 -C 4烷基）或苯基; R 3和R 4一起和/或R 5和R 6一起是非支链或支链C 2 -C 9亚烷基; A是Cl，Br，-O-R9，-N（R11）（R12）或-S-R18，A'是-O - ， - NH-或-NR11-; A“是Cl，Br，-O-R9，-N（R11）（R12）或-S-R18或氢，X是-O-R10或-N（R13）（R14），n是 1至10，优选1至4的整数，特别是1,2或3; R7是连接体; R8是二价C2-C3烷基基团。