公开(公告)号：US4568732A

公开(公告)日：1986-02-04

申请号：US689828

申请日：1985-01-09

申请人： Joseph P. Kennedy ,  Rudolf Faust ,  Agota Fehervari

发明人： Joseph P. Kennedy ,  Rudolf Faust ,  Agota Fehervari

IPC分类号： C08F2/14 ,  C08F2/38 ,  C08F10/10

CPC分类号： C08F10/10

摘要： Novel telechelic halogenated polymers of cationically polymerized olefin monomers are formed carrying from 2 to about 6 terminal halogens by a continuous polymerization method. The continuous polymerization method being achieved by feeding to a stirred reactor a first stream composed of a solvent solution of at least one monomer and an inifer and another stream composed of a solvent solution of boron chloride to effect the polymerization of said monomer to a telechelic halogenated polymer product and withdrawing the reaction product from said reactor essentially in amounts equal to that of the sum of the two streams with the feeds to said reactor being simultaneously and continuously fed thereto while maintaining the temperature in the range of minus 10.degree. to minus 80.degree. C.

摘要翻译： 通过连续聚合法形成携带2至约6个末端卤素的阳离子聚合烯烃单体的新型遥爪卤化聚合物。 连续聚合方法是通过向搅拌反应器中加入由至少一种单体和未反应物的溶剂溶液组成的第一流和由氯化硼的溶剂溶液组成的另一流来实现的，以使所述单体聚合成远端卤代 聚合物产物，并且基本上以等于两种料流之和的量与所述反应器的进料同时并连续地进料到所述反应器中的反应产物，同时保持温度在-10°至-80°的范围内 C。