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    Sulfonated polyaryletherketone-polyethersulfone block copolymers
    1.
    发明授权
    Sulfonated polyaryletherketone-polyethersulfone block copolymers 失效
    磺化聚芳醚酮 - 聚醚砜嵌段共聚物

    公开(公告)号：US07595373B2

    公开(公告)日：2009-09-29

    申请号：US11314877

    申请日：2005-12-20

    申请人： Joyce Hung ,  Hongyi Zhou ,  Marianne Elisabeth Harmon ,  Daniel Joseph Brunelle ,  Hongwei Liu ,  David Roger Moore ,  Daniel Steiger

    发明人： Joyce Hung ,  Hongyi Zhou ,  Marianne Elisabeth Harmon ,  Daniel Joseph Brunelle ,  Hongwei Liu ,  David Roger Moore ,  Daniel Steiger

    IPC分类号： C08G2/00

    CPC分类号： C08G75/23

    摘要： Sulfonated block copolymer suitable for use as proton exchange membranes for fuel cells comprise sulfonated polyaryletherketone blocks and polyethersulfone blocks. The sulfonated polyaryletherketone blocks comprise structural units of formula the polyethersulfone blocks comprising structural units of formula wherein R1, R2, R3 and R4 are independently C1-C10 alkyl, C3-C12 cycloalkyl, C6-C14 aryl, allyl, alkenyl, alkoxy,halo, or cyano; Z and Z1 are independently a direct bond or O, S, (CH2)r; (CF2)r, C(CH3)2, C(CF3)2, or a combination thereof; M is H, a metal cation, a non-metallic inorganic cation, an organic cation or a mixture thereof a is 0 or an integer from 1 to 3; b, c and d are independently 0 or an integer from 1 to 4; m and n are independently 0 or 1; and r is an integer from 1 to 5.

    摘要翻译： 适用于燃料电池质子交换膜的磺化嵌段共聚物包括磺化聚芳醚酮嵌段和聚醚砜嵌段。 所述磺化聚芳醚酮嵌段包含结构式的结构单元，所述结构单元包括结构单元，其中R 1，R 2，R 3和R 4独立地为C 1 -C 10烷基，C 3 -C 12环烷基，C 6 -C 14芳基，烯丙基，烯基，烷氧基， 或氰基; Z和Z1独立地是直接键或O，S，（CH 2）r; （CF 2）r，C（CH 3）2，C（CF 3）2或其组合; M为H，金属阳离子，非金属无机阳离子，有机阳离子或其混合物a为0或1〜3的整数; b，c和d独立地为0或1〜4的整数; m和n独立地为0或1; r为1〜5的整数。

    Benzimidazole-containing sulfonated polyethersulfones
    2.
    发明授权
    Benzimidazole-containing sulfonated polyethersulfones 失效
    含苯并咪唑的磺化聚醚砜

    公开(公告)号：US07547756B2

    公开(公告)日：2009-06-16

    申请号：US11263166

    申请日：2005-10-31

    申请人： Joyce Hung ,  Hongyi Zhou ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  Daniel Steiger ,  Hongwei Liu ,  David Roger Moore

    发明人： Joyce Hung ,  Hongyi Zhou ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  Daniel Steiger ,  Hongwei Liu ,  David Roger Moore

    IPC分类号： C08G75/23 ,  C08G75/20

    CPC分类号： C08G65/4037 ,  C08G65/4043 ,  C08G65/4056 ,  C08L79/04

    摘要： Sulfonated polyethersulfones and polymer compositions comprising sulfonated polyethersulfones and at least one inorganic heteropolyacid are useful as proton exchange membranes for fuel cells. The polyethersulfones include structural units derived from at least one biphenol monomer and a monomer of formula I wherein X is O, S or NR1; Y is N or CR5; R1, R2, R3 and R4 are independently hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alkylaryl, substituted alkylaryl, arylalkyl or substituted arylalkyl, or R3 and R4, taken together, form a 5- or 6-membered substituted or unsubstituted aliphatic or aromatic ring; R5 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alkylaryl, substituted alkylaryl, arylalkyl or substituted arylalkyl; and L is a direct bond or a divalent aromatic linker containing 6-12 carbons.

    摘要翻译： 包含磺化聚醚砜和至少一种无机杂多酸的磺化聚醚砜和聚合物组合物可用作燃料电池的质子交换膜。 聚醚砜包括衍生自至少一种联苯酚单体的结构单元和式I的单体，其中X是O，S或NR1; Y为N或CR5; R 1，R 2，R 3和R 4独立地为氢，烷基，取代的烷基，芳基，取代的芳基，烷基芳基，取代的烷基芳基，芳烷基或取代的芳基烷基，或者R 3和R 4一起形成5-或6-元取代或未取代的 脂肪族或芳香环; R5是氢，烷基，取代的烷基，芳基，取代的芳基，烷基芳基，取代的烷基芳基，芳基烷基或取代的芳基烷基; L是直接键或含有6-12个碳原子的二价芳族连接体。

    Mixed-sulfonation block copolymers
    4.
    发明授权
    Mixed-sulfonation block copolymers 失效
    混合磺化嵌段共聚物

    公开(公告)号：US07598337B2

    公开(公告)日：2009-10-06

    申请号：US11314337

    申请日：2005-12-20

    申请人： Joyce Hung ,  Hongyi Zhou ,  David Roger Moore ,  Marianne Elisabeth Harmon ,  Daniel Joseph Brunelle ,  Hongwei Liu

    发明人： Joyce Hung ,  Hongyi Zhou ,  David Roger Moore ,  Marianne Elisabeth Harmon ,  Daniel Joseph Brunelle ,  Hongwei Liu

    IPC分类号： C08G2/00

    CPC分类号： C08G65/4012 ,  C08G65/48 ,  C08G75/23

    摘要： Sulfonated block copolymers that may be used as membranes for fuel cells include sulfonated polyaryletherketone blocks and lightly sulfonated polyethersulfone blocks.The sulfonated polyaryletherketone blocks include structural units of formula and the lightly sulfonated polyethersulfone blocks include structural units of formula wherein R1, R2, R3, R4, R5 and R6 are independently C1-C10 alkyl, C3-C12 cycloalkyl, C6-C14 aryl, allyl, alkenyl, alkoxy, halo, or cyano; Z, Z1 and Z2 are independently a direct bond or O, S, (CH2)r, (CF2)r, C(CH3)2, C(CF3)2, or a combination thereof; M is H, a metal cation, a non-metallic inorganic cation, an organic cation or a mixture thereof; a and e are independently 0 or an integer from 1 to 3; b, c, d, and f are independently 0 or an integer from 1 to 4; m, n and p are independently 0 or 1; and r is an integer from 1 to 5.

    摘要翻译： 可用作燃料电池膜的磺化嵌段共聚物包括磺化聚芳醚酮嵌段和轻质磺化聚醚砜嵌段。 磺化的聚芳醚酮嵌段包括式的结构单元，轻度磺化的聚醚砜嵌段包括下式的结构单元：其中R1，R2，R3，R4，R5和R6独立地为C1-C10烷基，C3-C12环烷基，C6-C14芳基，烯丙基 ，烯基，烷氧基，卤素或氰基; Z，Z 1和Z 2独立地为直接键或O，S，（CH 2）r，（CF 2）r，C（CH 3）2，C（CF 3） M是H，金属阳离子，非金属无机阳离子，有机阳离子或其混合物; a和e独立地为0或1〜3的整数; b，c，d和f独立地为0或1〜4的整数; m，n和p独立地为0或1; r为1〜5的整数。

    Polyethersulfone compositions
    5.
    发明授权
    Polyethersulfone compositions 失效
    聚醚砜组合物

    公开(公告)号：US07393914B2

    公开(公告)日：2008-07-01

    申请号：US11193552

    申请日：2005-07-29

    申请人： David Roger Moore ,  Hongyi Zhou ,  Daniel Steiger ,  Joyce Hung ,  Daniel Joseph Brunelle ,  Hongwei Liu ,  Marianne Elisabeth Harmon

    发明人： David Roger Moore ,  Hongyi Zhou ,  Daniel Steiger ,  Joyce Hung ,  Daniel Joseph Brunelle ,  Hongwei Liu ,  Marianne Elisabeth Harmon

    IPC分类号： C08G75/00 ,  C08G8/02

    CPC分类号： G11B7/22 ,  G11B7/1356 ,  G11B7/1362 ,  G11B2007/0006

    摘要： Novel polyethersulfone compositions have been discovered which incorporate structural subunits derived from sulfonated bis(halophenyl)sulfones, dihydroxy terphenyls, and/or bis(hydroxyphenyl)pyridines. The sulfonated polyethersulfones show promise as materials for use in polymer electrolyte membranes (PEMs) in fuel cells owing to their high proton conductivities (0.02-0.07 S/cm at 20° C. and 100 percent humidity). In addition, a novel unsulfonated thermoplastic polyethersulfone comprising structural subunits derived from a non-sulfonated bis(halophenyl)sulfone bis4-fluorophenyl)sulfone and 4,4′-dihydroxyphenyl-2,6-pyridine (CAS No. 171820-16-9) is disclosed.

    摘要翻译： 已经发现新的聚醚砜组合物掺入衍生自磺化双（卤代苯基）砜，二羟基三联苯和/或双（羟基苯基）吡啶的结构亚单位。 磺化聚醚砜由于其高质子电导率（在20℃和100％湿度下为0.02-0.07S / cm），在燃料电池中用作聚合物电解质膜（PEM）的材料显示出希望。 另外，包含衍生自非磺化双（卤代苯基）砜双-4-氟苯基）砜和4,4'-二羟基苯基-2,6-吡啶（CAS号171820-16-9）的结构亚单位的新型未磺化热塑性聚醚砜， 被披露。

    Sulfonated polyaryletherketone-block-polyethersulfone copolymers
    6.
    发明申请
    Sulfonated polyaryletherketone-block-polyethersulfone copolymers 审中-公开
    磺化聚芳醚酮 - 嵌段 - 聚醚砜共聚物

    公开(公告)号：US20080004443A1

    公开(公告)日：2008-01-03

    申请号：US11479202

    申请日：2006-07-03

    申请人： Daniel Joseph Brunelle ,  Hongyi Zhou ,  Hongwei Liu ,  Joyce Hung ,  Marianne Elisabeth Harmon ,  David Roger Moore

    发明人： Daniel Joseph Brunelle ,  Hongyi Zhou ,  Hongwei Liu ,  Joyce Hung ,  Marianne Elisabeth Harmon ,  David Roger Moore

    IPC分类号： C07D295/00

    CPC分类号： H01M8/1025 ,  C08G65/4012 ,  C08G65/48 ,  C08G75/23 ,  C08J5/2256 ,  C08J2371/12 ,  H01M8/1027 ,  H01M2300/0082

    摘要： Sulfonated block copolymer suitable for use as proton exchange membranes for fuel cells comprise sulfonated polyaryletherketone blocks and polyethersulfone blocks. The sulfonated polyaryletherketone blocks comprise structural units of formula I wherein R1 is C1-C10 alkyl, C3-C12 cycloalkyl, C6-C14 aryl, allyl, alkenyl, alkoxy, halo, or cyano; Ar1 and Ar2 are each independently C6-C20 aromatic radicals, or Ar1 and Ar2, taken together with an intervening carbon atom, form a bicyclic C6-C20 aromatic radical or a tricyclic C6-C20 aromatic radical; M is H, a metal cation, a non-metallic inorganic cation, an organic cation or a mixture thereof; and a is 0 or an integer from 1 to 4.

    摘要翻译： 适用于燃料电池质子交换膜的磺化嵌段共聚物包括磺化聚芳醚酮嵌段和聚醚砜嵌段。 磺化的聚芳醚酮嵌段包含式I的结构单元，其中R 1是C 1 -C 10烷基，C 3〜 -C 12 -C 12环烷基，C 6 -C 14芳基，烯丙基，烯基，烷氧基，卤素或氰基; Ar 1和Ar 2各自独立地为C 6 -C 20芳族基团或Ar 1 与其间插入的碳原子一起形成双环C 6 -C 20芳族基团或三环C 1 -C 20芳族基团 C 6 -C 20芳族基团; M是H，金属阳离子，非金属无机阳离子，有机阳离子或其混合物; a为0或1〜4的整数。

    Polymers comprising superacidic groups, and uses thereof
    9.
    发明申请
    Polymers comprising superacidic groups, and uses thereof 审中-公开
    包含超酸基团的聚合物及其用途

    公开(公告)号：US20080114149A1

    公开(公告)日：2008-05-15

    申请号：US11598948

    申请日：2006-11-14

    申请人： David Roger Moore ,  Hongyi Zhou ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  Joyce Hung

    发明人： David Roger Moore ,  Hongyi Zhou ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  Joyce Hung

    IPC分类号： C08G63/688

    CPC分类号： C08G75/23 ,  C08G65/4025 ,  C08G65/4056

    摘要： The invention relates generally to polymers derived from monomers having aromatic superacidic functional groups. The superacidic functional groups comprise fluorinated sulfonate moieties. Polymers provided by the present invention include polyethers, polyesters, polycarbonates, polyestercarbonates, polyetherketones, and polyethersulfones among others. The polymers provided by the present invention include block and random copolymers. In one embodiment, the present invention provides a polyetherketone-polyethersulfone block copolymer comprising superacidic functional groups. Polymers comprising superacidic functional groups are useful materials in membrane applications. The superacidic functional groups present in the new polymer compositions impart excellent proton conductivities. In one embodiment, the present invention provides polymers useful as materials for polymer electrolyte fuel cell membranes.

    摘要翻译： 本发明一般涉及衍生自具有芳族超酸官能团的单体的聚合物。 超酸性官能团包括氟化磺酸盐部分。 本发明提供的聚合物包括聚醚，聚酯，聚碳酸酯，聚酯碳酸酯，聚醚酮和聚醚砜等。 本发明提供的聚合物包括嵌段和无规共聚物。 在一个实施方案中，本发明提供了包含超酸官能团的聚醚酮 - 聚醚砜嵌段共聚物。 包含超酸性官能团的聚合物是膜应用中的有用材料。 存在于新聚合物组合物中的超酸性官能团赋予优异的质子导电性。 在一个实施方案中，本发明提供了可用作聚合物电解质燃料电池膜的材料的聚合物。