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    Thermoplastic molding material
    1.
    发明授权
    Thermoplastic molding material 失效

    公开(公告)号：US4634734A

    公开(公告)日：1987-01-06

    申请号：US580220

    申请日：1984-02-15

    申请人： Juergen Hambrecht ,  Burghard Schmitt ,  Johann Swoboda ,  Georg Wassmuth ,  Claus Bernhard ,  Rudolf Stephan

    发明人： Juergen Hambrecht ,  Burghard Schmitt ,  Johann Swoboda ,  Georg Wassmuth ,  Claus Bernhard ,  Rudolf Stephan

    IPC分类号： C08L25/08 ,  C08L25/12 ,  C08L51/00 ,  C08L33/08

    CPC分类号： C08L25/08 ,  C08L25/12 ,  C08L51/003 ,  C08L51/00

    摘要： The invention relates to a thermoplastic molding material of an elastomeric polymer A, a shell B grafted to the polymer A, and a copolymer C as rigid matrix. The amount of polymer A is 1 to 25 percent by weight based on the weight of A+B+C. It has a glass transition temperature, Tg, of less than 0.degree. C. and an average particle size of 200 to 750 nanometers (d.sub.50 value of the integral mass distribution) and is composed of: 50 to 99.9 percent by weight of at least one alkylacrylate with 1 to 8 carbon atoms in the alkyl radical and 0.1 to 5 percent by weight of a polyfunctional monomer which has a crosslinking action. Grafting shell B represents 5 to 40 percent by weight based on A+B+C and is composed of at least one of the monomers of the group of(b.sub.1) vinylaromatic monomers, and(b.sub.2) the ethylenically unsaturated monomers.Grafting shell B is prepared in two stages with 30 to 70 percent by weight of the monomers b.sub.1 being used in the first stage, and 30 to 70 percent by weight of a mixture of monomers b.sub.1 and b.sub.2 in a weight ratio of 90:10 to 60:40 being used in the second stage.Copolymer C is added in an amount of 35 to 94 percent by weight based on A+B+C and consists of a vinylaromatic monomer and an ethylenically unsaturated monomer.The molding material may contain commonly used additives in effective amounts and is used for the preparation of molded parts.

    Thermoplastic molding material
    2.
    发明授权
    Thermoplastic molding material 失效
    热塑性成型材料

    公开(公告)号：US4788253A

    公开(公告)日：1988-11-29

    申请号：US627

    申请日：1987-04-17

    申请人： Juergen Hambrecht ,  Burghard Schmitt ,  Johann Swoboda ,  Georg Wassmuth ,  Claus Bernhard ,  Rudolf Stephan

    发明人： Juergen Hambrecht ,  Burghard Schmitt ,  Johann Swoboda ,  Georg Wassmuth ,  Claus Bernhard ,  Rudolf Stephan

    IPC分类号： C08L25/08 ,  C08L25/12 ,  C08L51/00 ,  C08L33/08

    CPC分类号： C08L25/08 ,  C08L25/12 ,  C08L51/003 ,  C08L51/00

    摘要： The invention relates to a thermoplastic molding material of an elastomeric polymer A, a shell B grafted to the polymer A, and a copolymer C as rigid matrix. The amount of polymer A is 1 to 25 percent by weight based on the weight of A+B+C. It has a glass transition temperature, Tg, of less than 0.degree. C. and an average particle size of 200 to 750 nanometers (d.sub.50 value of the integral mass distribution) and is composed of: 50 to 99.9 percent by weight of at least one alkylacrylate with 1 to 8 carbon atoms in the alkyl radical and 0.1 to 5 percent by weight of a polyfunctional monomer which has a crosslinking action. Grafting shell B represents 5 to 40 percent by weight based on A+B+C and is composed of at least one of the monomers of the group of(b.sub.1) vinylaromatic monomers, and(b.sub.2) the ethylenically unsaturated monomers.Grafting shell B is prepared in two stages with 30 to 70 percent by weight of the monomers b.sub.1 being used in the first stage, and 30 to 70 percent by weight of a mixture of monomers b.sub.1 and b.sub.2 in a weight ratio of 90:10 to 60:40 being used in the second stage.Copolymer C is added in an amount of 35 to 94 percent by weight based on A+B+C and consists of a vinylaromatic monomer and an ethylenically unsaturated monomer.The molding material may contain commonly used additives in effective amounts and is used for the preparation of molded parts.

    摘要翻译： 本发明涉及弹性体聚合物A的热塑性模塑材料，接枝到聚合物A上的壳B和作为刚性基质的共聚物C. 基于A + B + C的重量，聚合物A的量为1〜25重量％。 玻璃化转变温度Tg小于0℃，平均粒度为200〜750纳米（d50整体质量分布值），由以下组成：50〜99.9重量％的至少1个 在烷基中具有1至8个碳原子的丙烯酸烷基酯和具有交联作用的多官能单体0.1至5重量％。 接枝壳B以A + B + C为5〜40重量％，由（b1）乙烯基芳族单体组中的至少一种单体和（b2）烯属不饱和单体构成。 接枝壳B分两步制备，在第一阶段使用的单体b1为30〜70重量％，单体b1和b2的混合物的重量比为90:10〜30重量％，重量比为90:10〜 60:40在第二阶段使用。 共聚物C的添加量为35〜94重量％，基于A + B + C，由乙烯基芳族单体和烯属不饱和单体构成。 成型材料可以含有有效量的常用添加剂，并用于制备模制件。

    Thermoplastic molding materials
    5.
    发明授权
    Thermoplastic molding materials 失效
    热塑性成型材料

    公开(公告)号：US4433102A

    公开(公告)日：1984-02-21

    申请号：US399208

    申请日：1982-07-19

    申请人： Franz Brandstetter ,  Juergen Hambrecht ,  Rudolf Stephan

    发明人： Franz Brandstetter ,  Juergen Hambrecht ,  Rudolf Stephan

    IPC分类号： C08L25/12 ,  C08L51/00

    CPC分类号： C08L25/12 ,  C08L51/003

    摘要： A thermoplastic molding material contains 50-90% by weight of a hard component A comprising one or more copolymers of styrene and/or .alpha.-methylstyrene with acrylonitrile, and 50-10% by weight of a graft copolymer B comprising 40-80% by weight of a crosslinked acrylate polymer which has a mean particle size greater than 0.8 .mu.m (d.sub.50 value of the cumulative mass distribution) and onto which 20-60% by weight of a mixture of styrene and acrylonitrile in a weight ratio of from 88:12 to 65:35 is grafted.The novel molding material is used for the production of moldings.

    摘要翻译： 热塑性成型材料含有50-90重量％的包含苯乙烯和/或α-甲基苯乙烯与丙烯腈的一种或多种共聚物的硬组分A和50-10重量％的接枝共聚物B，其包含40-80％ 平均粒度大于0.8μm的交联丙烯酸酯聚合物的重量（累积质量分布的d50值），其中以重量比为88:20的苯乙烯和丙烯腈的混合物的20-60重量％ 12至65:35接枝。 该新型成型材料用于生产模制品。

    Impact resistant thermoplastic molding compositions
    6.
    发明授权
    Impact resistant thermoplastic molding compositions 失效
    耐冲击热塑性成型组合物

    公开(公告)号：US4104328A

    公开(公告)日：1978-08-01

    申请号：US646602

    申请日：1976-01-05

    申请人： Johann Swoboda ,  Rudolf Stephan ,  Gerhard Heinz

    发明人： Johann Swoboda ,  Rudolf Stephan ,  Gerhard Heinz

    IPC分类号： C08F36/06 ,  C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02

    CPC分类号： C08L25/12 ,  C08F36/06 ,  C08L51/04 ,  C08L55/02 ,  C08L51/003

    摘要： Impact-resistant thermoplastic molding compositions having a hard component comprising a styrene/acrylonitrile copolymer and a soft component comprising a graft copolymer of styrene and acrylonitrile on a rubbery polymer containing butadiene. The rubbery polymer serving as base for the graft copolymer is produced by polymerization or the monomer of monomers forming said polymer in aqueous emulsion and in the presence of a small amount of an alkanol of from 1 to 4 carbon atoms. The compositions have improved color and color stability and may be processed by conventional methods to form shaped articles.

    摘要翻译： 具有包含苯乙烯/丙烯腈共聚物的硬组分和包含苯乙烯和丙烯腈的接枝共聚物的软组分的耐冲击热塑性模塑组合物在含有丁二烯的橡胶状聚合物上。 作为接枝共聚物的基质的橡胶状聚合物是通过聚合法或在水乳液中形成所述聚合物的单体的单体和少量的具有1至4个碳原子的链烷醇的存在下制备的。 组合物具有改善的颜色和颜色稳定性，并且可以通过常规方法加工以形成成型制品。