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1.发明授权Nanoscale ordered composites of covalent ceramics for high-temperature structural applications via block-copolymer-assisted assembly and method of making 有权通过嵌段共聚物辅助组装和制备方法，用于高温结构应用的共价陶瓷的纳米级有序复合材料公开(公告)号：US07056849B2
公开(公告)日：2006-06-06
申请号：US10761076
申请日：2004-01-16
申请人： Julin Wan , Azar Alizadeh , Sergio Paulo Martins Loureiro , Mohan Manoharan , Patrick Roland Lucien Malenfant , Eric James Crane Olson , Seth Thomas Taylor
发明人： Julin Wan , Azar Alizadeh , Sergio Paulo Martins Loureiro , Mohan Manoharan , Patrick Roland Lucien Malenfant , Eric James Crane Olson , Seth Thomas Taylor
IPC分类号： C04B35/524 , C04B35/571 , C04B35/589
CPC分类号： C04B35/634 , B01D71/024 , B82Y30/00 , C04B35/524 , C04B35/563 , C04B35/571 , C04B35/583 , C04B35/584 , C04B35/589 , C04B35/597 , C04B35/6267 , C04B38/0022 , C04B2235/3856 , C04B2235/3873 , C04B2235/46 , C04B2235/465 , C04B2235/48 , C04B2235/483 , C04B2235/486 , C04B2235/76 , C04B2235/781 , C04B2235/80 , G03F7/0002 , C04B35/565 , C04B38/0054
摘要： A method of making nanoscale ordered composites of covalent ceramics through block copolymer-assisted assembly. At least one polymeric precursor is mixed with a block copolymer, and self-assembly of the mixture proceeds through an annealing process. During the annealing step, the polymeric precursor cross-links to form a structure robust enough to survive both the order-disorder transition temperature the block copolymer and the pyrolysis process, yielding ordered nanocomposites of high temperature ceramic materials. The method yields a variety of structures and morphologies. A ceramic material having at least one ceramic phase that has an ordered structure on a nanoscale and thermally stable up to a temperature of at least about 800° C. is also disclosed. The ceramic material is suitable for use in hot gas path assemblies, such as turbine assemblies, boilers, combustors, and the like.
摘要翻译： 通过嵌段共聚物辅助组装制备共价陶瓷的纳米级有序复合材料的方法。 将至少一种聚合物前体与嵌段共聚物混合，并且混合物的自组装通过退火工艺进行。 在退火步骤期间，聚合物前体交联以形成足够坚固的结构，以在嵌段共聚物和热解过程的顺序无序转变温度下存活，产生高温陶瓷材料的有序纳米复合材料。 该方法产生各种结构和形态。 还公开了一种陶瓷材料，其具有至少一个陶瓷相，其具有纳米级的有序结构并且至多达到至少约800℃的温度是热稳定的。 陶瓷材料适用于热气路径组件，例如涡轮机组件，锅炉，燃烧器等。
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公开(公告)号：US20080237470A1
公开(公告)日：2008-10-02
申请号：US11728400
申请日：2007-03-26
申请人： Sergio Paulo Martins Loureiro , James Scott Vartuli , Brent Allen Clothier , Steven Jude Duclos , Mohan Manoharan , Patrick Roland Lucien Malenfant , Venkat Subramaniam Venkataramani , Clifford Bueno
发明人： Sergio Paulo Martins Loureiro , James Scott Vartuli , Brent Allen Clothier , Steven Jude Duclos , Mohan Manoharan , Patrick Roland Lucien Malenfant , Venkat Subramaniam Venkataramani , Clifford Bueno
IPC分类号： G01T1/20
摘要： A scintillation detector comprising nano-scale particles of a scintillation compound embedded in a plastic matrix is provided. The nano-scale particles may be made from metal oxides, metal oxyhalides, metal oxysulfides, or metal halides. Methods are provided for preparing the nano-scale particles. The particles may be coated with organic compounds or polymers prior to incorporation in the plastic matrix. A technique for matching the refractive index of the plastic matrix with the nano-scale particles by incorporating nano-scale particles of titanium dioxide is also provided. The scintillator may be coupled with one or more photodetectors to form a scintillation detection system. The scintillation detection system may be adapted for use in X-ray and radiation imaging devices, such as digital X-ray imaging, mammography, CT, PET, or SPECT, or may be used in radiation security detectors or subterranean radiation detectors.
摘要翻译： 提供一种闪烁检测器，其包括嵌入塑料基质中的闪烁化合物的纳米级粒子。 纳米级颗粒可以由金属氧化物，金属卤氧化物，金属氧硫化物或金属卤化物制成。 提供了制备纳米级颗粒的方法。 在掺入塑料基质之前，颗粒可以涂覆有机化合物或聚合物。 还提供了一种通过纳入二氧化钛纳米尺度颗粒来匹配塑料基质与纳米级颗粒的折射率的技术。 闪烁体可以与一个或多个光电检测器耦合以形成闪烁检测系统。 闪烁检测系统可以适用于X射线和放射线成像装置，例如数字X射线成像，乳房X线照相术，CT，PET或SPECT，或可用于辐射安全检测器或地下辐射检测器。
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公开(公告)号：US07608829B2
公开(公告)日：2009-10-27
申请号：US11728400
申请日：2007-03-26
申请人： Sergio Paulo Martins Loureiro , James Scott Vartuli , Brent Allen Clothier , Steven Jude Duclos , Mohan Manoharan , Patrick Roland Lucien Malenfant , Venkat Subramaniam Venkataramani , Clifford Bueno
发明人： Sergio Paulo Martins Loureiro , James Scott Vartuli , Brent Allen Clothier , Steven Jude Duclos , Mohan Manoharan , Patrick Roland Lucien Malenfant , Venkat Subramaniam Venkataramani , Clifford Bueno
IPC分类号： C09K11/02
摘要： A scintillation detector comprising nano-scale particles of a scintillation compound embedded in a plastic matrix is provided. The nano-scale particles may be made from metal oxides, metal oxyhalides, metal oxysulfides, or metal halides. Methods are provided for preparing the nano-scale particles. The particles may be coated with organic compounds or polymers prior to incorporation in the plastic matrix. A technique for matching the refractive index of the plastic matrix with the nano-scale particles by incorporating nano-scale particles of titanium dioxide is also provided. The scintillator may be coupled with one or more photodetectors to form a scintillation detection system. The scintillation detection system may be adapted for use in X-ray and radiation imaging devices, such as digital X-ray imaging, mammography, CT, PET, or SPECT, or may be used in radiation security detectors or subterranean radiation detectors.
摘要翻译： 提供一种闪烁检测器，其包括嵌入塑料基质中的闪烁化合物的纳米级粒子。 纳米级颗粒可以由金属氧化物，金属卤氧化物，金属氧硫化物或金属卤化物制成。 提供了制备纳米级颗粒的方法。 在掺入塑料基质之前，颗粒可以涂覆有机化合物或聚合物。 还提供了一种通过纳入二氧化钛纳米尺度颗粒来匹配塑料基质与纳米级颗粒的折射率的技术。 闪烁体可以与一个或多个光电检测器耦合以形成闪烁检测系统。 闪烁检测系统可以适用于X射线和放射线成像装置，例如数字X射线成像，乳房X线照相术，CT，PET或SPECT，或可用于辐射安全检测器或地下辐射检测器。
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公开(公告)号：US07749425B2
公开(公告)日：2010-07-06
申请号：US11316091
申请日：2005-12-21
IPC分类号： C04B35/64 , C04B35/56 , C04B35/571 , C04B35/577
CPC分类号： C01B21/0828 , B82Y30/00 , C01B32/907 , C01P2004/04 , C01P2004/64 , C01P2004/80 , C04B35/589 , C04B35/6269 , C04B2235/3826 , C04B2235/3856 , C04B2235/3895 , C04B2235/422 , C04B2235/46 , C04B2235/48 , C04B2235/80 , C08L83/16 , G03F7/0002
摘要： A method of forming a nanoscale ceramic composite generally includes modifying a polymeric ceramic precursor, mixing the modified polymeric ceramic precursor with a block copolymer to form a mixture, forming an ordered structure from the mixture, wherein the modified polymeric ceramic precursor selectively associates with a specific type of block of the block copolymer, and heating the ordered structure for a time and at a temperature effective to form the nanoscale ceramic composite.
摘要翻译： 形成纳米级陶瓷复合材料的方法通常包括改性聚合物陶瓷前体，将改性聚合物陶瓷前体与嵌段共聚物混合以形成混合物，从混合物形成有序结构，其中改性聚合物陶瓷前体选择性地与特定的 类型的嵌段共聚物的嵌段，并且在有效形成纳米级陶瓷复合材料的温度下加热有序结构一段时间。
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5.发明授权Inorganic block co-polymers and other similar materials as ceramic precursors for nanoscale ordered high-temperature ceramics 有权无机嵌段共聚物和其他类似材料作为纳米级有序高温陶瓷的陶瓷前体公开(公告)号：US07709574B2
公开(公告)日：2010-05-04
申请号：US11488521
申请日：2006-07-18
IPC分类号： C04B35/56 , C08F293/00
CPC分类号： C08L53/00 , C08F293/00 , C08F293/005 , C08F297/00 , C08L2666/02
摘要： The present invention is generally directed to methods of making ceramics with nanoscale/microscale structure involving self-assembly of precursor materials such as, but not limited to, inorganic-based block co-polymers, inorganic-/organic-based hybrid block co-polymers, and other similar materials, and to the structures made by such methods. Where such precursor materials are themselves novel, the present invention is also generally directed to those materials and their synthesis.
摘要翻译： 本发明一般涉及制造具有纳米尺度/微米结构的陶瓷的方法，其涉及前体材料的自组装，例如但不限于无机基嵌段共聚物，基于无机/有机的杂化嵌段共聚物 ，和其他类似的材料，以及由这些方法制成的结构。 当这些前体材料本身是新颖的时，本发明也通常涉及这些材料及其合成。
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公开(公告)号：US07893165B2
公开(公告)日：2011-02-22
申请号：US11464125
申请日：2006-08-11
IPC分类号： C04B35/56 , C08F293/00 , C08F275/00
CPC分类号： C08F297/02 , C04B35/563 , C04B35/571 , C04B35/583 , C04B35/589 , C04B35/63488 , C04B38/0032 , C04B2103/0066 , C04B2235/3232 , C04B2235/3244 , C04B2235/3256 , C04B2235/3821 , C04B2235/3826 , C04B2235/3856 , C04B2235/386 , C04B2235/3873 , C04B2235/3886 , C04B2235/408 , C04B2235/441 , C04B2235/465 , C04B2235/483 , C04B2235/486 , C04B2235/6562 , C04B2235/6567 , C04B2235/80 , C04B38/0054
摘要： There are provided in accordance with embodiments of the invention metal-containing inorganic block copolymers, structures formed by self-assembly of such copolymers, and metal-containing ceramics which may be formed from such copolymers and/or structure. Methods for making such copolymers, structures and ceramics are also provided. Other embodiments are also disclosed.
摘要翻译： 根据本发明的实施方案提供了含金属的无机嵌段共聚物，通过这种共聚物的自组装形成的结构和可以由这种共聚物和/或结构形成的含金属陶瓷。 还提供了制备这种共聚物，结构和陶瓷的方法。 还公开了其他实施例。
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公开(公告)号：US07745362B2
公开(公告)日：2010-06-29
申请号：US11464142
申请日：2006-08-11
CPC分类号： C04B35/6325 , C04B35/486 , C04B35/495 , C04B35/5607 , C04B35/563 , C04B35/571 , C04B35/58007 , C04B35/58014 , C04B35/58064 , C04B35/583 , C04B35/589 , C04B2235/3232 , C04B2235/3826 , C04B2235/3852 , C04B2235/3856 , C04B2235/386 , C04B2235/3873 , C04B2235/408 , C04B2235/441 , C04B2235/48 , C04B2235/483 , C04B2235/486 , C04B2235/762
摘要： There are provided in accordance with embodiments of the invention metal-containing inorganic block copolymers, structures formed by self-assembly of such copolymers, and metal-containing ceramics which may be formed from such copolymers and/or structure. Methods for making such copolymers, structures and ceramics are also provided. Other embodiments are also disclosed.
摘要翻译： 根据本发明的实施方案提供了含金属的无机嵌段共聚物，通过这种共聚物的自组装形成的结构和可以由这种共聚物和/或结构形成的含金属陶瓷。 还提供了制备这种共聚物，结构和陶瓷的方法。 还公开了其他实施例。
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公开(公告)号：US20080039311A1
公开(公告)日：2008-02-14
申请号：US11464142
申请日：2006-08-11
IPC分类号： C04B35/56
CPC分类号： C04B35/6325 , C04B35/486 , C04B35/495 , C04B35/5607 , C04B35/563 , C04B35/571 , C04B35/58007 , C04B35/58014 , C04B35/58064 , C04B35/583 , C04B35/589 , C04B2235/3232 , C04B2235/3826 , C04B2235/3852 , C04B2235/3856 , C04B2235/386 , C04B2235/3873 , C04B2235/408 , C04B2235/441 , C04B2235/48 , C04B2235/483 , C04B2235/486 , C04B2235/762
摘要： There are provided in accordance with embodiments of the invention metal-containing inorganic block copolymers, structures formed by self-assembly of such copolymers, and metal-containing ceramics which may be formed from such copolymers and/or structure. Methods for making such copolymers, structures and ceramics are also provided. Other embodiments are also disclosed.
摘要翻译： 根据本发明的实施方案提供了含金属的无机嵌段共聚物，通过这种共聚物的自组装形成的结构和可以由这种共聚物和/或结构形成的含金属陶瓷。 还提供了制备这种共聚物，结构和陶瓷的方法。 还公开了其他实施例。
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公开(公告)号：US20080039589A1
公开(公告)日：2008-02-14
申请号：US11464125
申请日：2006-08-11
IPC分类号： C08F297/02
CPC分类号： C08F297/02 , C04B35/563 , C04B35/571 , C04B35/583 , C04B35/589 , C04B35/63488 , C04B38/0032 , C04B2103/0066 , C04B2235/3232 , C04B2235/3244 , C04B2235/3256 , C04B2235/3821 , C04B2235/3826 , C04B2235/3856 , C04B2235/386 , C04B2235/3873 , C04B2235/3886 , C04B2235/408 , C04B2235/441 , C04B2235/465 , C04B2235/483 , C04B2235/486 , C04B2235/6562 , C04B2235/6567 , C04B2235/80 , C04B38/0054
摘要： There are provided in accordance with embodiments of the invention metal-containing inorganic block copolymers, structures formed by self-assembly of such copolymers, and metal-containing ceramics which may be formed from such copolymers and/or structure. Methods for making such copolymers, structures and ceramics are also provided. Other embodiments are also disclosed.
摘要翻译： 根据本发明的实施方案提供了含金属的无机嵌段共聚物，通过这种共聚物的自组装形成的结构和可以由这种共聚物和/或结构形成的含金属陶瓷。 还提供了制备这种共聚物，结构和陶瓷的方法。 还公开了其他实施例。
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公开(公告)号：US08043418B2
公开(公告)日：2011-10-25
申请号：US11608292
申请日：2006-12-08
申请人： James Anthony Ruud , Michael John Bowman , Kalya Vijaya Sarathy , Mohan Manoharan , Anthony Yu-Chung Ku , Vidya Ramaswamy , Patrick Roland Lucien Malenfant
发明人： James Anthony Ruud , Michael John Bowman , Kalya Vijaya Sarathy , Mohan Manoharan , Anthony Yu-Chung Ku , Vidya Ramaswamy , Patrick Roland Lucien Malenfant
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D61/38 , B01D67/0088 , B01D67/0093 , B01D69/10 , B01D69/141 , B01D71/024 , B01D71/027 , B01D71/028 , B01D71/40 , B01D71/44 , B01D2257/504 , B01D2325/10 , B01D2325/22 , Y02C10/10
摘要： An apparatus for separating at least one component from a mixture of a plurality of chemical species is provided. The apparatus comprises a membrane structure comprising a plurality of pores disposed within a matrix material to allow mass transport from a first surface of the membrane structure to a second surface of the membrane structure. The matrix material has a thermal conductivity of at least about 10 W/m/K; and a functional material disposed within at least a portion of the plurality of pores. The functional material has the property of promoting selective transport of at least one species through the membrane structure from the first surface to the second surface.
摘要翻译： 提供了一种用于从多种化学物质的混合物中分离至少一种组分的装置。 该装置包括膜结构，其包括设置在基质材料内的多个孔，以允许质量从膜结构的第一表面传输到膜结构的第二表面。 基质材料具有至少约10W / m / K的热导率; 以及设置在所述多个孔的至少一部分中的功能材料。 功能材料具有促进至少一种物质通过膜结构从第一表面到第二表面的选择性输送的性质。
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