摘要:
A porous carbon material for electrodes of energy storage devices comprising: a porous carbon material; 0.5 to 5 parts by mass of an insulating material having a boiling point of 150° C. or more based on 100 parts by mass of the porous carbon material; and 0.25 to 15 parts by mass of a conductive additive based on 100 parts by mass of the insulating material, wherein the insulating material and the conductive additive are carried on the porous carbon material in combination, and the porous carbon material has a BET specific surface area of 1300 to 2050 m2/g.
摘要:
The object of the present invention is to provide a carbonaceous material which is obtainable from plant-derived char and has a decreased specific surface area. Further, the object of the present invention is to provide a non-aqueous electrolyte secondary battery having excellent dedoping capacity (discharge capacity), non-dedoping capacity (irreversible capacity), and charge-discharge efficiency.The object can be solved by a carbonaceous material for non-aqueous electrolyte secondary batteries characterized in that the carbonaceous material is obtained by heat-treating plant-derived char which is demineralized in gas-phase, and carbon precursor (i.e. non-graphitizable carbon precursor, graphitizable carbon, or mixture thereof) or volatile organic compound under a non-oxidizing gas atmosphere; and a specific surface area determined by a BET method is 10 m2/g or less. Further, the object can be solved by a carbonaceous material for non-aqueous electrolyte secondary batteries characterized in that the carbonaceous material is obtained by heating plant-derived char, and hydrocarbon compound having 1 to 20 carbon atoms; and a specific surface area determined by a BET method is 15 m2/g or less.
摘要:
A carbonaceous material for electric double-layer capacitors that is based on a plant-derived carbon precursor, in which carbonaceous material: a BET specific surface area is 1,900 to 2,500 m2/g; an average pore size is 2.2 to 2.6 nm as determined by a nitrogen adsorption method; a volume of micropores having a pore size of 2 nm or smaller is 0.84 to 1.30 cm3/g as determined by the MP method; a ratio of a volume of micropores having a pore size of 1 to 2 nm with respect to the volume of the micropores having a pore size of 2 nm or smaller is 25 to 50% as determined by the MP method; and a volume of mesopores having a pore size of 2 to 50 nm is 0.16 to 0.4 cm3/g as determined by the BJH method; and a method of producing same.
摘要:
The object of the present invention is to provide a carbonaceous material which is obtainable from plant-derived char and has a decreased specific surface area. Further, the object of the present invention is to provide a non-aqueous electrolyte secondary battery having excellent dedoping capacity, non-dedoping capacity, and charge-discharge efficiency. The object can be solved by a carbonaceous material for non-aqueous electrolyte secondary batteries characterized in that the carbonaceous material is obtained by heat-treating plant-derived char which is demineralized in gas-phase, and carbon precursor or volatile organic compound under a non-oxidizing gas atmosphere; and a specific surface area determined by a BET method is 10 m2/g or less.
摘要:
The object of the present invention is to provide a manufacturing method of carbonaceous material for a negative electrode of lithium ion capacitors, wherein the carbonaceous material is obtained from plant-derived char as a source, potassium and iron are sufficiently removed, and an average particle diameter thereof is small; and a carbonaceous material for a negative electrode of lithium ion capacitors.The object can be solved by a method for manufacturing a carbonaceous material having an average diameter of 3 to 30 μm, for a negative electrode of lithium ion capacitors comprising the steps of: (1) heating plant-derived char having an average particle diameter of 100 to 10000 μm at 500° C. to 1250° C. under an inert gas atmosphere containing a halogen compound to demineralize in a gas-phase, (2) pulverizing a carbon precursor obtained by the demineralization in a gas-phase, (3) calcining the pulverized carbon precursor at less than 1100° C. under a non-oxidizing gas atmosphere.
摘要:
Provided is a manufacturing method of carbonaceous material for a negative electrode of non-aqueous electrolyte secondary batteries, wherein the carbonaceous material is obtained from plant-derived char as a source, potassium is sufficiently removed, and an average particle diameter thereof is small; and a carbonaceous material for a negative electrode of non-aqueous electrolyte secondary batteries. The method for manufacturing a carbonaceous material having an average particle diameter of 3 to 30 μm, for a negative electrode of non-aqueous electrolyte secondary batteries includes the steps of: (1) heating plant-derived char having an average particle diameter of 100 to 10000 μm at 500° C. to 1250° C. under an inert gas atmosphere containing halogen compound to demineralize in a gas-phase, (2) pulverizing a carbon precursor obtained by demineralization in a gas-phase, (3) calcining the pulverized carbon precursor at 1000° C. to 1600° C. under an non-oxidizing gas atmosphere.
摘要:
The object of the present invention is to provide a manufacturing method of carbonaceous material for a negative electrode of lithium ion capacitors, wherein the carbonaceous material is obtained from plant-derived char as a source, potassium and iron are sufficiently removed, and an average particle diameter thereof is small; and a carbonaceous material for a negative electrode of lithium ion capacitors.The object can be solved by a method for manufacturing a carbonaceous material having an average diameter of 3 to 30 μm, for a negative electrode of lithium ion capacitors comprising the steps of: (1) heating plant-derived char having an average particle diameter of 100 to 10000 μm at 500° C. to 1250° C. under an inert gas atmosphere containing a halogen compound to demineralize in a gas-phase, (2) pulverizing a carbon precursor obtained by the demineralization in a gas-phase, (3) calcining the pulverized carbon precursor at less than 1100° C. under a non-oxidizing gas atmosphere.