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公开(公告)号:US10323143B2
公开(公告)日:2019-06-18
申请号:US14779220
申请日:2014-03-13
申请人: KURARAY CO., LTD.
发明人: Yoshiaki Asanuma , Koichiro Isoue
摘要: An object is to provide a polyvinyl acetal composition which includes polyvinyl acetals having different average amounts of remaining hydroxyl groups and from which a sheet having excellent transparency can be molded.A polyvinyl acetal composition comprising 3 to 100 parts by mass of polyvinyl acetal (B) with respect to 100 parts by mass of polyvinyl acetal (A), and 0.05 to 0.75 times by mass of compound (C) with respect to the total mass of polyvinyl acetal (A) and polyvinyl acetal (B). The polyvinyl acetal (A) has an average amount of remaining hydroxyl groups of X mol % (X is a positive number), the polyvinyl acetal (B) has an average amount of remaining hydroxyl groups of Y mol % (Y is a positive number), and |X−Y|≥3 is satisfied. The compound (C) is selected from a group consisting of a polyester containing a hydroxyl group, a polyalkylene oxide, and an ester compound containing a hydroxyl group, the ester compound containing a hydroxyl group being an ester compound of one molecule of an m-valent alcohol (m represents an integer of 1 to 3) and n molecules (n represents an integer of 1 to m) of a monovalent carboxylic acid.
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公开(公告)号:US10016959B2
公开(公告)日:2018-07-10
申请号:US15031315
申请日:2013-10-25
申请人: KURARAY CO., LTD.
发明人: Takeshi Kusudou , Yoshiaki Asanuma
IPC分类号: B32B17/10 , C08L29/14 , C08F216/38 , B29B17/00 , B29C43/02 , C08J5/18 , B29C43/20 , B29K31/00 , B29K61/00 , B29K105/00 , B29K105/26 , B29L7/00 , B29L9/00
CPC分类号: B32B17/10761 , B29B17/0005 , B29C43/02 , B29C43/203 , B29K2031/04 , B29K2061/00 , B29K2105/0038 , B29K2105/0085 , B29K2105/26 , B29K2995/0018 , B29K2995/0026 , B29L2007/008 , B29L2009/00 , B32B17/10036 , B32B17/10605 , B32B2307/412 , B32B2419/00 , B32B2605/08 , C08F216/38 , C08J5/18 , C08J2329/14 , C08L29/14 , C08L2205/025 , C08F218/08
摘要: There is provided a multilayer film comprising a layer (X) containing a polyvinyl acetal (I) having an acetalization degree of 55 to 80 mol %, a content of a vinyl ester monomer unit of 0.1 to 1.5 mol % and a viscosity-average degree of polymerization of 1,400 to 5,000; and a layer (Y) containing a polyvinyl acetal (II) having an acetalization degree of 70 to 85 mol %, a content of a vinyl ester monomer unit of 5 to 15 mol % and a viscosity-average degree of polymerization of 1,400 to 5,000, wherein the multilayer film satisfies formulas (1) and (2): (A−B)/A
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公开(公告)号:US10913843B2
公开(公告)日:2021-02-09
申请号:US16336369
申请日:2017-09-26
申请人: KURARAY CO., LTD.
发明人: Yasushi Senda , Shinya Oshita , Yoshiaki Asanuma
IPC分类号: C08L53/02 , B32B17/10 , C08F297/04 , G10K11/162
摘要: Provided are a resin composition, a pellet, a veil, a vibration damping material, a sound insulator, and an intermediate film for laminated glass, each of which is much more excellent in damping properties. Specifically, the resin composition is a resin composition containing the following block copolymer or hydrogenation product thereof (X); and a tackifier resin (Y) having a glass transition temperature of −50 to 45° C., wherein when a glass transition temperature of a polymer block (B) of the block copolymer or hydrogenation product thereof (X) is designated as Tg(X), and a glass transition temperature of the tackifier resin (Y) is designated as Tg(Y), an absolute value of a difference between Tg(X) and Tg(Y) is 50° C. or lower, the block copolymer or hydrogenation product thereof (X) being a block copolymer or a hydrogenation product thereof having a polymer block (A) containing more than 70 mol % of a structural unit derived from an aromatic vinyl compound and a polymer block (B) containing 30 mol % or more of a structural unit derived from at least one selected from the group consisting of a conjugated diene compound and isobutylene, and the content of the polymer block (A) in the block copolymer being 25% by mass or less.
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公开(公告)号:US10519295B2
公开(公告)日:2019-12-31
申请号:US14779256
申请日:2013-03-22
申请人: KURARAY CO., LTD.
发明人: Yoshiaki Asanuma
IPC分类号: C08L29/14 , C08K5/10 , C08K5/06 , C08L71/02 , B32B17/06 , B32B27/06 , B32B27/30 , C08L29/04 , B32B17/10
摘要: To provide a laminated product of a layer including a polyvinyl acetal and a layer including a hydrocarbon-based polymer, having excellent adhesion between the layers.A composition including, with respect to 100 parts by mass of a polyvinyl acetal satisfying definition 1 and/or definition 2, 30 to 70 parts by mass of a plasticizer including 0.5 to 100% by mass of a plasticizer containing a polar group and 0 to 99.5% of a plasticizer containing no polar group.Definition 1: When 1 g of a polyvinyl acetal is dissolved in 100 g of methanol, an undissolved content is 2.5 to 90% by mass.Definition 2: When 1 g of a polyvinyl acetal is dissolved in 100 g of chloroform, an undissolved content is 5 to 70% by mass.
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公开(公告)号:US10029448B2
公开(公告)日:2018-07-24
申请号:US14892915
申请日:2013-05-22
申请人: KURARAY CO., LTD.
发明人: Yoshiaki Asanuma
IPC分类号: B32B27/08 , B32B27/30 , B32B27/22 , B32B7/00 , B32B7/02 , B32B7/04 , B32B7/10 , B32B27/00 , B32B27/06 , B32B27/18 , B32B27/28 , B32B27/36 , B32B17/10
摘要: A laminate contains a layer A and a layer B. The layer A includes a polyvinyl acetal (A), a plasticizer (Ap), and a dispersant (Ad). The layer B includes a polyvinyl acetal (B) and a plasticizer (Bp) and optionally a dispersant (Bd). A mass ratio of (Ad) to (Ap) is larger than a mass ratio of (Bd) to (Bp). The plasticizer (Ap) and the plasticizer (Bp) are an ester compound of an m-valent alcohol with m molecules of a monovalent carboxylic acid having 8 to 16 carbon atoms, where m is a number of 2 to 4; and an ester compound of an n-valent alcohol with n molecules of a monovalent carboxylic acid having 8 to 16 carbon atoms, where n is a number of 2 to 4, respectively. The dispersant (Ad) and the dispersant (Bd) are obtained by hydrolyzing the plasticizer (Ap) and the plasticizer (Bp), respectively.
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公开(公告)号:US11623985B2
公开(公告)日:2023-04-11
申请号:US17279427
申请日:2019-09-25
申请人: KURARAY CO., LTD.
发明人: Yoshiaki Asanuma , Koichiro Isoue
摘要: The present invention relates to a polyvinyl acetal resin film, comprising a polyvinyl acetal resin material, wherein the polyvinyl acetal resin film has a thickness of 5 to 350 μm, and satisfies the following Formulae (1) and (2) where, comparing one surface and the other surface, a mean value of the 10-point average roughness of a rougher surface A and a mean value of the 10-point average roughness of a smoother surface B are defined as Rz1(a) μm and Rz2(a) μm, respectively: Rz1(a)>1.1×Rz2(a) (1) 3>Rz2(a) (2), a value obtained by dividing the standard deviation of the 10-point average roughness of the surface A by Rz1(a) and a value obtained by dividing the standard deviation of the 10-point average roughness of the surface B by Rz2(a) are each 0 to 0.30, a viscosity of a toluene/ethanol (1:1, mass ratio) solution containing 10%-by-mass of a polyvinyl acetal resin contained in the polyvinyl acetal resin material, which is measured at 20° C. and 30 rpm using a Brookfield-type (B-type) viscometer, is 100 to 1,000 mPa·s, and the amount of a plasticizer in the polyvinyl acetal resin film is 0 to 20% by mass based on a total mass of the polyvinyl acetal resin film.
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公开(公告)号:US11325354B2
公开(公告)日:2022-05-10
申请号:US16089055
申请日:2017-03-24
申请人: KURARAY CO., LTD.
发明人: Yoshiaki Asanuma , Takeshi Kusudou
IPC分类号: B32B17/10 , B32B27/30 , C08F116/38 , C08J5/18 , C08K5/01 , C08K5/03 , C08K5/05 , C08K5/053 , C08K5/12 , B32B7/02
摘要: Provided is an interlayer film for laminated glass which is excellent in sound insulation property and has improved sound insulation performance not only in a coincidence region but also in a mass-dominated region. The interlayer film for laminated glass includes a sound insulating layer which is formed from a composition (A) containing at least one resin (a1) selected from a thermoplastic resin and a thermosetting resin, wherein a tan δ obtained when a dynamic viscoelasticity of a sheet, which is obtained by molding the composition (A) to have a thickness of 0.8 mm, is measured at a frequency of 0.3 Hz in a tension mode has a maximal value at a temperature TA (° C.), TA (° C.) is in a range of −50 to 50° C., and the tan δ at TA (° C.) is 2.5 or more.
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公开(公告)号:US10392495B2
公开(公告)日:2019-08-27
申请号:US14779179
申请日:2013-03-22
申请人: KURARAY CO., LTD.
发明人: Yoshiaki Asanuma , Yoko Nakano
摘要: A composition including 100 parts by mass of a polyvinyl acetal and 30 to 70 parts by mass of a plasticizer including 0.5 to 100% by mass of a plasticizer containing a polar group and 0 to 99.5% by mass of a plasticizer containing no polar group, a total of the plasticizer containing a polar group and the plasticizer containing no polar group being 100% by mass. When the polyvinyl acetal is analyzed by HPLC using an ODS column having an inner diameter of 4 mm and a length of 1 cm, the polyvinyl acetal exhibits a first peak and a second peak derived from polyvinyl acetals. In addition, a laminated product of a layer including a polyvinyl acetal and a layer including a hydrocarbon-based polymer.
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公开(公告)号:US09988507B2
公开(公告)日:2018-06-05
申请号:US15589362
申请日:2017-05-08
申请人: KURARAY CO., LTD.
发明人: Koichiro Isoue , Yoshiaki Asanuma
CPC分类号: C08J5/18 , B32B17/10036 , B32B17/10605 , B32B17/10678 , B32B17/10688 , B32B17/10761 , B32B17/10871 , B32B2307/202 , B32B2307/412 , C08F6/26 , C08F16/38 , C08J2329/14 , C08K5/10 , C08K5/103 , C08K5/11 , C08K5/13 , C08L29/14 , H01L31/0481 , Y02E10/50
摘要: Provided is a polyvinyl acetal film which, when used as an intermediate film for a laminated glass, can provide a laminated glass that exhibits a low degree of yellowness and excellent surface appearance, and which is thus useful as a sealing material or intermediate film that can prolong the life of a laminated glass provided with a solar cell or a functional unit. Further, the content of corrosion-causing substance in the polyvinyl acetal film is low, so that the polyvinyl acetal film permits high-temperature lamination and thus ensures excellent productivity. Also provided are a solar cell module and a laminated glass prepared using the polyvinyl acetal film. A plasticized polyvinyl acetal film which comprises 15 to 60 parts by mass of a plasticizer having a total number of 28 or more of carbon atoms and oxygen atoms constituting a molecule based on 100 parts by mass of a polyvinyl acetal resin, and which has an acid value of 5.0 meq/kg or less.
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