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1.发明授权
公开(公告)号：US5334350A
公开(公告)日：1994-08-02
申请号：US861810
申请日：1992-06-19
CPC分类号： G01N27/12
摘要： A resistance probe is proposed for detecting gas compositions, particularly in the exhaust gases of internal combustion engines. This resistance probe has the advantage over prior art resistance probes that, with a short response time, it is considerably more aging resistant. This is accomplished in that the resistance layer configured as a semiconductor layer is introduced or sintered into recesses or slits provided for this purpose in the prefabricated sensor carrier body and above it is applied a porous, electrically non-conductive engobe or a protective layer structure in the form of a grid or raster. These measures enable the measuring gas to gain access to the semiconductor layer, but the semiconductor layer is simultaneously protected against corrosive, erosive and/or cavitative attacks from the exhaust gas.
摘要翻译： PCT No.PCT / DE90 / 00909 Sec。 371日期：1992年6月19日 102（e）日期1992年6月19日PCT提交1990年11月24日PCT公布。 出版物WO91 / 09301 日期：1991年6月27日。提出了用于检测气体组成的电阻探针，特别是在内燃机的废气中。 该电阻探针具有优于现有技术的电阻探针的优点，其具有较短的响应时间，其耐老化性更强。 这是通过将构造为半导体层的电阻层引入或烧结到预制传感器载体本体中为此而设置的凹部或狭缝中，并且在其上施加多孔，非导电性或者保护层结构 网格或栅格的形式。 这些措施使得测量气体能够进入半导体层，但同时保护半导体层免受来自废气的腐蚀性，侵蚀性和/或空穴化攻击。
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2.发明授权Sensor element for limit current sensors to determine the .lambda.-value of gas mixtures 失效用于限制电流传感器的传感器元件，以确定气体混合物的λ值
公开(公告)号：US5314604A
公开(公告)日：1994-05-24
申请号：US39135
申请日：1993-04-12
IPC分类号： G01N27/419 , B01D53/86 , F02D41/14 , G01N27/26 , G01N27/406 , G01N27/41 , G01N27/417
CPC分类号： G01N27/417
摘要： A sensor element for broad band sensors to determine the .lambda.-value of gas mixtures is suggested. This sensor element can be manufactured in ceramic-sheet and screen-printing technology and is provided in the diffusion gap (7) downstream from a pair of pump electrodes (8,8"), arranged on both sides of the diffusion gasp (7), with a Nernst electrode (9) which functions as an exhaust gas electrode. Due to this arrangement of the Nernst electrode (9), it is possible in a simple manner to effectively protect the pump cell formed by the interior pump electrodes (8,8') from overload and to prevent falsification of the sensor signal.
摘要翻译： PCT No.PCT / DE91 / 00752 Sec。 371日期：1993年4月12日 102（e）日期1993年4月12日PCT 1991年9月21日PCT PCT。 公开号WO92 / 07252 日期：1992年4月30日。建议用于确定气体混合物的λ值的宽带传感器的传感器元件。 该传感器元件可以以陶瓷片和丝网印刷技术制造，并且设置在布置在扩散气体（7）的两侧的一对泵电极（8,8“）下游的扩散间隙（7）中 ），其具有用作排气电极的能斯特电极（9）。 由于能斯特电极（9）的这种布置，可以以简单的方式有效地保护由内部泵电极（8,8'）形成的泵电池免于过载并且防止传感器信号的伪造。
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公开(公告)号：US5846391A
公开(公告)日：1998-12-08
申请号：US836425
申请日：1997-04-29
IPC分类号： G01N27/409 , G01N27/407
CPC分类号： G01N27/4078
摘要： A seal for a sensor element for a gas sensor for determining the oxygen content in a gas to be measured including exhaust gases of internal combustion engines, the seal including a metallic housing having defined therein a longitudinal bore; a sensor element inserted into the longitudinal bore; and a sealing arrangement provided in the longitudinal bore, surrounding at least a portion of the sensor element, and comprised of at least one seal element comprised of steatite and an additional seal element comprised of boron nitride arranged in contact with one another and in a stack having a side near the gas to be measured so that, when there is one seal element comprised of steatite, the one seal element comprised of steatite is positioned on the side of the stack near the gas to be measured, and so that, when there are two seal elements comprised of steatite, the additional seal element is positioned between the two seal elements comprised of steatite, wherein the at least one seal element comprised of steatite and the additional seal element comprised of boron nitride are inserted into the longitudinal bore of the housing as deformable rings and are pressed-in therein, and wherein, during the pressing-in, the deformable rings are deformed in such a way that the at least one seal element comprised of steatite and the additional seal element comprised of boron nitride are pushed against the sensor element and the housing.
摘要翻译： PCT No.PCT / DE96 / 00567 Sec。 371日期1997年04月29日 102（e）日期1997年4月29日PCT 1996年3月21日PCT公布。 公开号WO97 / 08542 日期1997年3月6日用于气体传感器的传感器元件的密封件，用于确定包括内燃机废气的待测气体中的氧含量，所述密封件包括金属壳体，其中限定有纵向孔; 插入纵向孔中的传感器元件; 以及设置在所述纵向孔中的密封装置，围绕所述传感器元件的至少一部分，并且包括至少一个由滑石组成的密封元件和由氮化硼组成的另外的密封元件，所述氮化硼彼此接触并且在堆叠 具有靠近要测量的气体的一侧，使得当存在由滑石组成的一个密封元件时，由滑石组成的一个密封元件位于靠近待测量气体的堆叠侧，并且当那里 是由滑石组成的两个密封元件，附加的密封元件位于由滑石组成的两个密封元件之间，其中由滑石组成的至少一个密封元件和由氮化硼组成的另外的密封元件被插入到 壳体作为可变形环并被压入其中，并且其中，在压入期间，可变形环以这样的方式变形，使得至少一个 由滑石组成的气体元件和由氮化硼组成的另外的密封元件被推靠在传感器元件和壳体上。
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公开(公告)号：US5795454A
公开(公告)日：1998-08-18
申请号：US569074
申请日：1995-12-04
IPC分类号： G01N27/409 , G01N27/12 , G01N27/407 , F16J15/14
CPC分类号： G01N27/4078 , G01N27/407 , G01N27/4077 , Y10S277/936 , Y10S277/938 , Y10S277/939 , Y10S277/941 , Y10S277/943
摘要： A seal for a sensor element of a gas sensor for determining the oxygen content in gases including exhaust gases of an internal combustion engine, which seal seals the sensor element in a longitudinal bore of a housing, the seal including a sealing stack which is positioned within the longitudinal bore of the housing and around the sensor element in use and which is comprised of two sealing bodies and an additional seal positioned between the two sealing bodies. The two sealing bodies are comprised of a pre-sintered ceramic material. The additional seal is comprised of a pre-pressed powder material and has a porosity which is lower than that of the two sealing bodies. The two sealing bodies and the additional seal are compressed together within the longitudinal bore in use, whereby at least the additional seal is deformed so that the sensor element is sealed in a gap-free manner within the longitudinal bore. The pre-pressed powder material of the additional seal may consist essentially of a ductile metal, which may be one of nickel or copper, or graphite which may be fiber-reinforced.
摘要翻译： PCT No.PCT / DE94 / 00537 Sec。 371 1995年12月4日第 102（e）日期1995年12月4日PCT 1994年5月11日PCT公布。 公开号WO94 / 29710 日期1994年12月22日用于确定包括内燃机的废气在内的气体中的氧含量的气体传感器的传感器元件的密封件，该密封件将传感器元件密封在壳体的纵向孔中，所述密封件包括密封件 堆叠，其位于壳体的纵向孔内并且在使用中围绕传感器元件，并且由两个密封体和位于两个密封体之间的附加密封件组成。 两个密封体由预烧结的陶瓷材料组成。 附加密封件由预压粉末材料组成，并且具有低于两个密封体的孔隙率。 两个密封体和附加密封件在使用中在纵向孔内压缩在一起，由此至少附加的密封件变形，使得传感器元件以无间隙的方式密封在纵向孔内。 附加密封件的预压粉末材料可以由可以是镍或铜之一的延性金属或可以是纤维增强的石墨组成。
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5.发明授权Process for producing PTC temperature sensor elements for PTC temperature sensor 失效用于生产PTC温度传感器PTC温度传感器元件的工艺
公开(公告)号：US5172466A
公开(公告)日：1992-12-22
申请号：US715798
申请日：1991-06-14
IPC分类号： G01K7/16 , G01J5/02 , G01J5/20 , G01K7/18 , G01K7/22 , G01N27/416 , G01N27/417 , H01C1/024 , H01C1/034 , H01C7/02
CPC分类号： G01K7/183 , H01C7/021 , Y10T29/49085
摘要： A PTC temperature sensor and a process for producing PTC temperature sensing elements from ceramic films for a PTC temperature sensor are proposed. The PTC temperature sensing elements are so designed that the PTC resistor track is hermetically encapsulated with respect to the gas being measured and the ambient air. Ceramic films based on an insulator ceramic, in particular based on Al.sub.2 O.sub.3, and ceramic films based on a solid electrolyte can be used to produce the temperature sensing elements. The PTC temperature sensor according to the invention is distinguished, in particular, by the fact that, while the manufacturing procedure is cheap, it is not subject to aging due to the effect of varying O.sub.2 partial pressures, has a high resistance to aging of the resistance characteristic in rich and lean gas mixtures, for example in motor vehicle exhaust gases, at 300.degree.-1000.degree. C. and has a construction free from extraneous potential, is characterized by short response times owning to its low heat capacity and is suitable for incorportion in very narrow housing as a consequence of small dimensions.
摘要翻译： 提出了一种用于PTC温度传感器的PTC温度传感器和用于从陶瓷膜生产PTC温度传感元件的工艺。 PTC温度感测元件被设计成使得PTC电阻轨道相对于被测量的气体和环境空气被气密地封装。 可以使用基于绝缘体陶瓷，特别是基于Al 2 O 3的陶瓷膜和基于固体电解质的陶瓷膜来制造温度感测元件。 根据本发明的PTC温度传感器的特征在于，特别是由于制造过程便宜，由于变化的O2分压的影响，其不会老化，因此具有高耐老化性 富含和贫气混合物的阻力特性，例如在机动车排气中，在300°-1000℃，具有无外力的结构，其特征在于具有低热容量的响应时间短，适用于 由于小尺寸，狭窄房屋的配额不合。
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6.发明授权NTC temperature sensor and process for producing NTC temperature sensing elements 失效NTC温度传感器和生产NTC温度传感元件的工艺
公开(公告)号：US5142266A
公开(公告)日：1992-08-25
申请号：US466286
申请日：1990-03-26
IPC分类号： G01K7/16 , G01K7/22 , G01N27/406 , G01N27/416 , H01C7/04
CPC分类号： H01C7/043 , G01K7/223 , G01N27/4067
摘要： The NTC temperature sensor includes a NTC temperature sensing element having an NTC resistor and made of a laminated composite of ceramic films, which is so designed that the ambient air or oxygen supplied by electrolytic pumping has free access, via a channel in the laminated composite, to the NTC resistor. The NTC resistor is hermetically sealed from a gas being measured. Solid electrolyte films which conduct O.sup.-2 ions, and films based on Al.sub.2 O.sub.3 can be used to make the laminated composite. The NTC resistor characteristic curve is independent of the composition of the gas being measured. The laminated composite can be formed of at least three solid electrolyte ceramic films including a base film provided with punched-out interconnection holes and conductor tracks printed by thick film technology, an intermediate film having a punched-out channel and a channel enlargement around the ends of the conductor tracks forming the electrodes of the NTC resistor, and a covering film.
摘要翻译： PCT No.PCT / DE88 / 00528 Sec。 371 1990年3月26日第 102（e）1990年3月26日PCT PCT公布1988年8月30日PCT。 出版物WO89 / 03115 日期2004年4月6日。NTC温度传感器包括NTC温度感测元件，其具有NTC电阻器并由陶瓷膜的层压复合材料制成，其被设计成使得通过电解泵送供应的环境空气或氧气可以自由通过， 一个通道在叠层复合材料中，到NTC电阻。 NTC电阻器与被测气体气密密封。 可以使用导电O-2离子的固体电解质膜和基于Al2O3的膜来制备层压复合材料。 NTC电阻特性曲线与被测气体的组成无关。 层压复合体可以由至少三个固体电解质陶瓷膜形成，该固体电解质陶瓷膜包括设置有冲孔互连孔的底膜和通过厚膜技术印刷的导体轨迹，具有冲压通道的中间膜和在端部周围的通道放大 的形成NTC电阻器的电极的导体轨迹以及覆盖膜。
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公开(公告)号：US06408680B1
公开(公告)日：2002-06-25
申请号：US09171717
申请日：1999-04-08
IPC分类号： G01N2712
摘要： A sensor for determining an oxygen content in an exhaust gas of an internal combustion engine includes a receptacle, arranged in a longitudinal bore of a metal housing, for a sensing element. The sensing element is received in the receptacle in a gas-tight fashion via a sensing element seal, which includes a glass seal. The receptacle has a measured-gas-side ceramic shaped element and a connector-side ceramic shaped element, which are arranged axially one behind the other. A cavity into which the glass seal is pressed while hot is configured between the two ceramic shaped elements.
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公开(公告)号：US6164120A
公开(公告)日：2000-12-26
申请号：US171688
申请日：1999-02-22
IPC分类号： G01N27/409 , G01N27/12 , G01N27/407
CPC分类号： G01N27/4078 , G01N27/407
摘要： A sensor for determining an oxygen level in an exhaust gas of an internal combustion engine includes a receptacle arranged in a longitudinal bore of a metallic enclosure for a sensor element. The sensor element is accommodated in a gas-tight manner using a sensor element seal. The receptacle has a measured gas-side ceramic molded component and a connection-side ceramic molded component, which are arranged one behind the other axially. A hollow space is formed between the measured gas-side ceramic molded component and the connection-side ceramic molded component, in which a metallic sealing element is hot-pressed.
摘要翻译： PCT No.PCT / DE97 / 02916 Sec。 一九九九年二月二十二日 102（e）1999年2月22日PCT 1997年12月16日PCT公布。 第WO98 / 38500号公报 日期1998年9月3日用于确定内燃机排气中的氧气含量的传感器包括布置在用于传感器元件的金属外壳的纵向孔中的容器。 使用传感器元件密封件以气密方式容纳传感器元件。 容器具有一个沿轴向布置的测量气体侧陶瓷成型部件和连接侧陶瓷成形部件。 在被测量的气体侧陶瓷成型部件和连接侧陶瓷成型部件之间形成中空空间，其中金属密封元件被热压。
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公开(公告)号：US5698267A
公开(公告)日：1997-12-16
申请号：US728797
申请日：1996-10-10
IPC分类号： B22F7/00 , C04B35/486 , C04B41/52 , C04B41/89 , C23C26/00 , G01N27/407 , B05D1/18 , G01N27/406
CPC分类号： C04B41/009 , B22F7/002 , C04B35/486 , C04B41/52 , C04B41/89 , C23C26/00 , G01N27/4075 , C04B2111/00844 , Y10S264/36
摘要： A method for fabricating a high-activity cermet electrode which is applied on an exhaust gas sensor including an oxygen ion conducting solid electrolyte, which is composed of a cermet material composed of at least one catalytically active material and at least one oxygen ion conducting ceramic material, which is bonded to the solid electrolyte of the exhaust sensor by co-sintering the cermet electrode and the solid electrolyte at a temperature ranging from 1300.degree. to 1600.degree. C. to provide a porous cermet electrode, and which contains at least one further catalytically active material which is embedded in the pores of the porous cermet electrode after co-sintering, the method including bonding together an unsintered solid electrolyte which conducts oxygen ions and a cermet electrode by co-sintering at from 1300.degree. to 1600.degree. C. to provide a porous cermet electrode; and subsequently introducing at least one further catalytically active material into pores of the porous cermet electrode.
摘要翻译： 一种制造高活性金属陶瓷电极的方法，其应用于包括氧离子传导固体电解质的废气传感器，所述废气传感器由由至少一种催化活性材料和至少一种氧离子导电陶瓷材料构成的金属陶瓷材料组成 ，其通过在1300℃至1600℃的温度下共烧烧金属陶瓷电极和固体电解质而结合到排气传感器的固体电解质，以提供多孔金属陶瓷电极，并且其至少包含一个催化剂 共烧结后嵌入多孔金属陶瓷电极的孔隙中的活性物质，该方法包括在1300℃〜1600℃下共烧结而将导电氧离子的未烧结固体电解质和金属陶瓷电极结合在一起，以提供 多孔金属陶瓷电极; 随后将至少一种其它催化活性材料引入多孔金属陶瓷电极的孔中。
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10.发明授权Electro-chemical measuring sensor with a potential-free sensor element and method for producing it 失效具有无电位传感器元件的电化学测量传感器及其制造方法
公开(公告)号：US5670032A
公开(公告)日：1997-09-23
申请号：US592381
申请日：1996-01-25
IPC分类号： G01N27/409 , G01N27/407 , G01N27/26
CPC分类号： G01N27/407 , G01N27/4078
摘要： An electro-chemical measuring sensor (10) for determining the oxygen content of gases, in particular for determining the oxygen content in exhaust gases of internal combustion engines, with a potential-free disposed sensor element (14). The sensor element (14) has an oxygen-ion-conducting solid electrolyte body (23), preferably in the shape of a pipe or tube closed at one end, which has an exterior electrode (25) disposed on the exterior surface with a strip conductor (27) on the side toward the contact and also extending on the exterior surface, and which is inserted by means of a sealing ring (20) in a metal housing (11). The sensor element (14) has an electrically insulating layer (21) at least in the area of the sealing ring (20), which covers at least the strip conductor (27) in the direction toward the housing (11). The insulating layer (21) is formed from a mixture of a crystalline, non-metallic material and a glass-forming material. In the course of production the insulating layer (21) is subjected to a thermal treatment above the melting temperature of the glass-forming material, in the course of which the insulating layer (21) forms a glaze filled with the crystalline, non-metallic material.
摘要翻译： PCT No.PCT / DE94 / 00791 Sec。 371日期：1996年1月25日 102（e）日期1996年1月25日PCT 1994年7月9日PCT公布。 公开号WO95 / 04273 日期1995年2月9日，一种用于确定气体氧含量的电化学测量传感器（10），特别是用于确定内燃机排气中氧含量的电化学测量传感器（10）。 传感器元件（14）具有氧离子传导固体电解质体（23），优选地为在一端封闭的管或管的形状，其具有设置在外表面上的外部电极（25） 导体（27），并且还在外表面上延伸，并且通过密封环（20）插入到金属外壳（11）中。 传感器元件（14）至少在密封环（20）的区域中具有电绝缘层（21），其至少在朝向壳体（11）的方向上覆盖带状导体（27）。 绝缘层（21）由结晶，非金属材料和玻璃形成材料的混合物形成。 在制造过程中，将绝缘层（21）进行高于玻璃形成材料的熔化温度的热处理，其中绝缘层（21）形成填充有结晶非金属的釉料 材料。
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