Silica supported ziegler-natta catalysts useful for preparing polyolefins
    4.
    发明申请
    Silica supported ziegler-natta catalysts useful for preparing polyolefins 审中-公开
    用于制备聚烯烃的二氧化硅负载的齐格勒 - 纳塔催化剂

    公开(公告)号:US20060252636A1

    公开(公告)日:2006-11-09

    申请号:US11122920

    申请日:2005-05-05

    IPC分类号: C08F4/02 B01J31/00

    摘要: A silica supported catalyst system can be prepared that includes the product of admixing a magnesium alkoxide with a group 4, 5, or 6 transition metal complex to form a magnesium transition metal alkoxide adduct having the general formula: MgM(OR)2(OR1)pClq wherein M is a group 4, 5, or 6 transition metal; R is an alkyl or aryl moiety; R1 is a alkyl or aryl moiety having from 1 to 10 carbons, and p and q are 0 or an integer such that p+q equals the highest formal oxidation state of M; contacting the magnesium transition metal alkoxide adduct with a silica template to form a silica supported catalyst precursor; contacting the silica supported catalyst precursor chlorinating agent to form a chlorinated catalyst precursor; and contacting the chlorinated catalyst precursor with an aluminum alkyl to form a silica supported catalyst.

    摘要翻译: 可以制备二氧化硅负载的催化剂体系,其包括将烷氧基镁与基团4,5,5或6过渡金属络合物混合以形成具有以下通式的镁过渡金属醇盐加合物的产物: =“在线公式”end =“lead”?> MgM(OR)2(或<1>) <?in-line-formula description =“In-line Formulas”end =“tail”?>其中M是4,5或6族过渡金属; R是烷基或芳基部分; R 1是具有1至10个碳的烷基或芳基部分,p和q是0或整数,使得p + q等于M的最高形式氧化态; 使镁过渡金属醇盐加合物与二氧化硅模板接触以形成二氧化硅负载的催化剂前体; 使二氧化硅负载的催化剂前体氯化剂接触以形成氯化催化剂前体; 并使氯化催化剂前体与烷基铝接触以形成二氧化硅负载的催化剂。

    Ziegler-Natta catalyst for particle size control
    5.
    发明授权
    Ziegler-Natta catalyst for particle size control 失效
    齐格勒 - 纳塔催化剂用于粒度控制

    公开(公告)号:US07655590B2

    公开(公告)日:2010-02-02

    申请号:US12004814

    申请日:2007-12-20

    IPC分类号: B01J37/16 B01J37/22

    摘要: Catalyst components, methods of forming catalyst compositions, polymerization processes utilizing the catalyst compositions and polymers formed thereby are described herein. The methods generally include providing a magnesium dialkoxide compound, contacting the magnesium dialkoxide compound with a first agent to form a solution of a reaction product “A1”, contacting the solution of reaction product “A1” with a reducing agent to form a reduced reaction product “A2”, contacting reduced reaction product “A2” with a second agent to form a solid reaction product “A3”, contacting solid reaction product “A3” with a metal halide to form reaction product “B” and contacting reaction product “B” with an organoaluminum compound to form a catalyst component.

    摘要翻译: 本文描述了催化剂组分,形成催化剂组合物的方法,利用催化剂组合物的聚合方法和由此形成的聚合物。 所述方法通常包括提供二烷氧基镁化合物,使二烷氧基镁化合物与第一试剂接触以形成反应产物“A1”的溶液,使反应产物“A1”的溶液与还原剂接触以形成还原反应产物 “A2”,将还原的反应产物“A2”与第二试剂接触以形成固体反应产物“A3”,使固体反应产物“A3”与金属卤化物接触以形成反应产物“B”并使反应产物“B” 与有机铝化合物形成催化剂组分。

    Ziegler-Natta catalyst for particle size control
    6.
    发明申请
    Ziegler-Natta catalyst for particle size control 失效
    齐格勒 - 纳塔催化剂用于粒度控制

    公开(公告)号:US20090163680A1

    公开(公告)日:2009-06-25

    申请号:US12004814

    申请日:2007-12-20

    IPC分类号: C08F4/76

    摘要: Catalyst components, methods of forming catalyst compositions, polymerization processes utilizing the catalyst compositions and polymers formed thereby are described herein. The methods generally include providing a magnesium dialkoxide compound, contacting the magnesium dialkoxide compound with a first agent to form a solution of a reaction product “A1”, contacting the solution of reaction product “A1” with a reducing agent to form a reduced reaction product “A2”, contacting reduced reaction product “A2” with a second agent to form a solid reaction product “A3”, contacting solid reaction product “A3” with a metal halide to form reaction product “B” and contacting reaction product “B” with an organoaluminum compound to form a catalyst component.

    摘要翻译: 本文描述了催化剂组分,形成催化剂组合物的方法,利用催化剂组合物的聚合方法和由此形成的聚合物。 所述方法通常包括提供二烷氧基镁化合物,使二烷氧基镁化合物与第一试剂接触以形成反应产物“A1”的溶液,使反应产物“A1”的溶液与还原剂接触以形成还原反应产物 “A2”,将还原的反应产物“A2”与第二试剂接触以形成固体反应产物“A3”,使固体反应产物“A3”与金属卤化物接触以形成反应产物“B”并使反应产物“B” 与有机铝化合物形成催化剂组分。

    Process for controlling morphology of Ziegler-Natta catalysts
    7.
    发明授权
    Process for controlling morphology of Ziegler-Natta catalysts 失效
    控制齐格勒 - 纳塔催化剂形态的方法

    公开(公告)号:US08063159B2

    公开(公告)日:2011-11-22

    申请号:US11778262

    申请日:2007-07-16

    IPC分类号: C08F4/00

    摘要: Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. It comprises altering the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor; or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent. Use of the invention enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties.

    摘要翻译: 公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。 其包括通过控制可溶性含镁催化剂前体的浓度来改变催化剂组分从包括可溶性镁的催化剂前体的催化剂合成溶液中的沉淀,其中催化剂组分的平均粒径增加,并且颗粒尺寸 分布增加,可溶性含镁催化剂前体的浓度降低; 或沉淀剂,其中催化剂组分的平均粒度增加,并且随着沉淀剂浓度的增加,粒度分布增加。 使用本发明能够改善催化剂的一致性,而不管生产规模如何,催化剂形态定制成所需的聚合物形态。 新颖的催化剂组分可用于制备聚合物及其最终用途制品,具有期望的性能。

    Process for Controlling Morphology of Ziegler-Natta Catalysts
    8.
    发明申请
    Process for Controlling Morphology of Ziegler-Natta Catalysts 审中-公开
    控制齐格勒 - 纳塔催化剂形态的方法

    公开(公告)号:US20120064268A1

    公开(公告)日:2012-03-15

    申请号:US13272279

    申请日:2011-10-13

    摘要: Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. The process enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

    摘要翻译: 公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。 该方法能够改善催化剂的一致性,而不管生产规模如何,催化剂形态定制成所需的聚合物形态。 新颖的催化剂组分可用于制备聚合物及其最终用途制品,具有期望的性能。 要强调的是,该摘要被提供以符合要求摘要的规则,这将允许搜索者或其他读者快速确定技术公开的主题。 提交它的理解是,它不会用于解释或限制权利要求的范围或含义。

    Ziegler-Natta catalyst
    9.
    发明授权
    Ziegler-Natta catalyst 有权
    齐格勒 - 纳塔催化剂

    公开(公告)号:US08003741B2

    公开(公告)日:2011-08-23

    申请号:US12069190

    申请日:2008-02-07

    IPC分类号: C08F4/50

    摘要: The present invention relates generally to catalysts, to methods of making catalysts, to methods of using catalysts, to methods of polymerizing, and to polymers made with such catalysts. More particularly, the present invention relates to polyolefin catalysts and to Ziegler-Natta catalysts, to methods of making such catalysts, to methods of using such catalysts, to polyolefin polymerization, and to polyolefins.

    摘要翻译: 本发明一般涉及催化剂,制备催化剂的方法,使用催化剂的方法,聚合方法以及用这种催化剂制备的聚合物。 更具体地,本发明涉及聚烯烃催化剂和齐格勒 - 纳塔催化剂,制备这种催化剂的方法,使用这种催化剂的方法,聚烯烃聚合和聚烯烃。

    Process for Controlling Morphology of Ziegler-Natta Catalysts
    10.
    发明申请
    Process for Controlling Morphology of Ziegler-Natta Catalysts 失效
    控制齐格勒 - 纳塔催化剂形态的方法

    公开(公告)号:US20090023875A1

    公开(公告)日:2009-01-22

    申请号:US11778262

    申请日:2007-07-16

    IPC分类号: B01J37/03 C08F4/12

    摘要: Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. It comprises altering the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor; or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent. Use of the invention enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

    摘要翻译: 公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。 其包括通过控制可溶性含镁催化剂前体的浓度来改变催化剂组分从包括可溶性镁的催化剂前体的催化剂合成溶液中的沉淀,其中催化剂组分的平均粒径增加,并且颗粒尺寸 分布增加,可溶性含镁催化剂前体的浓度降低; 或沉淀剂,其中催化剂组分的平均粒度增加,并且随着沉淀剂浓度的增加,粒度分布增加。 使用本发明能够改善催化剂的一致性,而不管生产规模如何,催化剂形态定制成所需的聚合物形态。 新颖的催化剂组分可用于制备聚合物及其最终用途制品,具有期望的性能。 要强调的是,该摘要被提供以符合要求摘要的规则,这将允许搜索者或其他读者快速确定技术公开的主题。 提交它的理解是,它不会用于解释或限制权利要求的范围或含义。