摘要:
A system comprising a fuel converter comprising a catalyst composition capable of converting a fuel into a selected one or both of a syngas reductant and a short chain hydrocarbon reductant, wherein the catalyst composition comprises: cracking sites that perform a cracking function when a temperature of an exhaust fluid is greater than a predetermined threshold temperature, wherein the cracking function converts long chain hydrocarbon molecules to short chain hydrocarbon molecules; and partial oxidation sites that perform a catalytic partial oxidation function when the temperature of the exhaust fluid is less than the predetermined threshold temperature, wherein the catalytic partial oxidation function oxidizes the fuel to produce the syngas reductant; and a selective catalytic reduction catalyst reactor in fluid communication with the fuel converter and the exhaust fluid.
摘要:
A system includes an exhaust conduit configured to conduct a stream of exhaust gas, wherein the exhaust conduit comprises a selective catalytic reduction catalyst reactor comprising a first catalyst composition; an fuel source configured to introduce a fuel into the exhaust gas stream within the exhaust conduit upstream of the selective catalytic reduction catalyst reactor; a catalytic partial oxidation reformer in fluid communication with the exhaust gas stream and upstream from the selective catalytic reduction catalyst reactor, wherein the catalytic partial oxidation reformer can introduce a hydrogen-rich syngas co-reductant into the exhaust gas stream, when a temperature of the exhaust fluid is less than a determined threshold temperature.
摘要:
A method is provided for operating a diesel engine with reduced emissions. The method comprises combusting a first biodiesel blend fuel in a diesel engine resulting in the production of diesel exhaust gases containing NOx. The diesel exhaust gases are admixed with a second biodiesel blend fuel, and the second biodiesel blend fuel is hydrolyzed to form reducing agents. The diesel exhaust gases containing NOx are passed through an NOx-reducing catalyst to reduce the NOx through a selective catalytic reduction reaction with the reducing agents. The invention further provides a method for operating a diesel engine with reduced emissions, comprising combusting a first biodiesel blend fuel in a diesel engine resulting in the production of diesel exhaust gases containing NOx. A second biodiesel blend fuel is converted in a fuel processor thereby forming reducing agents, and the diesel exhaust gases are admixed with the reducing agents. The diesel exhaust gases containing NOx are passed through an NOx-reducing catalyst to reduce the NOx through a selective catalytic reduction reaction with the reducing agents.
摘要:
A method is provided for operating a diesel engine with reduced emissions. The method comprises combusting a first biodiesel blend fuel in a diesel engine resulting in the production of diesel exhaust gases containing NOx. The diesel exhaust gases are admixed with a second biodiesel blend fuel, and the second biodiesel blend fuel is hydrolyzed to form reducing agents. The diesel exhaust gases containing NOx are passed through an NOx-reducing catalyst to reduce the NOx through a selective catalytic reduction reaction with the reducing agents. The invention further provides a method for operating a diesel engine with reduced emissions, comprising combusting a first biodiesel blend fuel in a diesel engine resulting in the production of diesel exhaust gases containing NOx. A second biodiesel blend fuel is converted in a fuel processor thereby forming reducing agents, and the diesel exhaust gases are admixed with the reducing agents. The diesel exhaust gases containing NOx are passed through an NOx-reducing catalyst to reduce the NOx through a selective catalytic reduction reaction with the reducing agents.
摘要:
A system includes a fuel converter comprising a catalyst composition, and the catalyst composition can convert fuel into a hydrocarbon reductant stream; a separation system that separates the hydrocarbon reductant stream into a first reductant sub-stream that comprises short chain hydrocarbon molecules, and a second reductant sub-stream that comprises long chain hydrocarbon molecules; a selective catalytic reduction catalyst reactor in fluid communication with the fuel converter, and the catalyst reactor has an inner surface that defines a first zone and a second zone, and the first zone is configured to receive the second reductant sub-stream, and the second zone is configured to receive the first reductant sub-stream; and an exhaust stream that flows into the first zone contacts the second reductant sub-stream before flowing into the second zone and contacting the first reductant sub-stream.
摘要:
According to various embodiments, an exhaust treatment system includes a catalyst that is in direct contact with an exhaust stream, at least one sensor that senses a system parameter and produces one or more signals corresponding to the system parameter, and a controller that is configured to receive the one or more signals and control catalyst performance based on the one or more signals by regenerating the catalyst. Regenerating the catalyst includes increasing a temperature of the exhaust stream flowing to the catalyst and directing a reductant injector to adjust a flow rate of reductant being injected into the exhaust stream flowing to the catalyst.
摘要:
The present invention details a process for producing a catalyst powder. The steps of the process include preparing catalyst slurry, drying, pyrolyzing, and calcining the catalyst slurry to obtain a calcined catalyst powder. The catalyst slurry comprises a catalyst, a liquid carrier, a templating agent, and a catalyst substrate. The catalyst slurry is dried to obtain a raw catalyst powder. The raw catalyst powder is heated in a first controlled atmosphere to obtain a pyrolyzed catalyst powder and the pyrolyzed catalyst powder is calcined in a second controlled atmosphere to obtain a calcined catalyst powder. A method of fabricating a catalyst surface and catalytic converter using the prepared catalyst powder is also illustrated.
摘要:
A catalyst composition is provided that includes a catalytic metal secured to a substrate, and the substrate is mesoporous and has pores that are templated. A catalyst composition includes a catalytic metal secured to a mesoporous substrate. The mesoporous substrate is a reaction product of a reactive solution, a solvent, a modifier, and a templating agent. A method for controlling nitrous oxide emissions including the catalyst composition comprising introducing a regeneration fuel into an exhaust stream upstream relative to the catalyst composition and heating the exhaust stream upstream relative to the catalyst composition. When the regeneration fuel is introduced the air/fuel ratio λ of an air/fuel mixture of a lean burn exhaust is greater than 1.
摘要:
Various methods and systems are provided for an exhaust gas treatment device for an exhaust gas treatment system. In one example, the exhaust gas treatment device includes a primary flow passage through which exhaust gas flows to the exhaust gas treatment device, a first sub-catalyst partially disposed in the primary flow passage splitting the exhaust gas into a first gas flow and a bypass flow, and a second sub-catalyst disposed downstream of the first sub-catalyst in the bypass flow forming a second gas flow, where the second gas flow is different from the first gas flow.
摘要:
An exhaust treatment system is provided. Method of increasing activation of NOx reduction catalyst using two or more reductant is discussed. The exhaust treatment system includes an exhaust source, a reductant source, a nitrogen oxide (NOx) reduction catalyst, a sensor, and a controller. The reductant source includes a first reductant and second reductant, and is disposed to inject a reductant stream into an exhaust stream from the exhaust source. The NOx catalyst is disposed to receive both the exhaust stream and reductant stream. The sensor is disposed to sense a system parameter related to carbon loading of the catalyst and produce a signal corresponding to the system parameter. The controller is disposed to receive the signal and to control dosing of the reductant stream based at least in part on the signal.