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    Battery electrode substrate and process for producing the same
    6.
    发明授权
    Battery electrode substrate and process for producing the same 有权
    电池电极基板及其制造方法

    公开(公告)号：US6071650A

    公开(公告)日：2000-06-06

    申请号：US135956

    申请日：1998-08-18

    申请人： Keizo Harada ,  Kenichi Watanabe ,  Shosaku Yamanaka

    发明人： Keizo Harada ,  Kenichi Watanabe ,  Shosaku Yamanaka

    IPC分类号： B22F3/11 ,  H01M4/66 ,  H01M4/80 ,  H01M10/30

    CPC分类号： H01M4/801 ,  B22F3/1137 ,  B22F3/1143 ,  H01M4/667 ,  H01M4/80 ,  H01M4/808 ,  B22F2998/00 ,  B22F2998/10 ,  B22F2999/00 ,  H01M10/30 ,  H01M2300/0014 ,  H01M4/661

    摘要： A battery electrode substrate which is constituted of a porous metallic body structure having communicating pores at a porosity of at least 90% and an Fe/Ni multilayer structure wherein the skeletal portion of the porous metallic body is composed mainly of Fe and has an Ni covering layer on the surface thereof while pores communicating with the inside and outside of Fe skeletal portion exist in the Fe skeletal portion and the inside of the pores is covered with Ni. The electrode substrate is produced by applying an iron oxide powder of at most 20 .mu.m in an average particle size on a porous resin core body; heat treating the core to remove an organic resin component while simultaneously sintering Fe to obtain a porous Fe body; and then covering the Fe skeletal portion with Ni by electroplating. In this process, the iron oxide can be used in combination with carbon powder. Further, a nickel porous sintered body can also be produced using nickel oxide in place of iron oxide.

    摘要翻译： 一种电池用电极基板，其特征在于，具有孔隙率为90％以上的连通孔的多孔金属体结构体和Fe / Ni多层结构体，其中，所述多孔金属体的骨架部分主要由Fe构成，并具有Ni覆盖层 在Fe骨架部分中存在与Fe骨架部分的内部和外部连通的孔，并且用Ni覆盖孔的内部。 通过在多孔树脂芯体上涂布平均粒径为20μm以下的氧化铁粉末来制造电极基板， 热处理芯以除去有机树脂组分，同时同时烧结Fe以获得多孔Fe体; 然后通过电镀用Ni覆盖Fe骨架部分。 在该方法中，氧化铁可与碳粉末组合使用。 此外，也可以使用氧化镍代替氧化铁来制造镍多孔烧结体。

    Process for preparing metallic porous body, electrode substrate for battery and process for preparing the same
    8.
    发明授权
    Process for preparing metallic porous body, electrode substrate for battery and process for preparing the same 失效
    金属多孔体的制​​备方法，电池用电极基板及其制备方法

    公开(公告)号：US5640669A

    公开(公告)日：1997-06-17

    申请号：US567145

    申请日：1995-12-04

    申请人： Keizo Harada ,  Masayuki Ishii ,  Kenichi Watanabe ,  Shosaku Yamanaka

    发明人： Keizo Harada ,  Masayuki Ishii ,  Kenichi Watanabe ,  Shosaku Yamanaka

    IPC分类号： B22F3/11 ,  B22F1/00

    CPC分类号： B22F3/1137 ,  B22F2998/10 ,  B22F2999/00 ,  Y10T428/12056

    摘要： A process for preparing a metallic porous body, comprising: forming a layer comprising Cu, a Cu alloy, or a precursor thereof onto a skeleton composed of a porous resin body having a three-dimensional network, heat-treating the resin body with the layer formed thereon to remove a heat-decomposable organic component, thereby forming a porous metallic skeleton of Cu or a Cu alloy; and plating the surface of the Cu or Cu alloy skeleton with Ni or an Ni alloy. The heat treating may be carried out by direct induction heating. The metallic porous body is useful as electrodes for batteries, various filters, carriers for catalysts, etc. When the porous body is cut and used as the electrode substrate, the coating of an area, where Cu or its alloy has been exposed by cutting or the like, with a third metal having a lower ionization tendency than Cu or its alloy can provide an electrode substrate having better corrosion resistance and battery service life.

    摘要翻译： 一种制备金属多孔体的方法，包括：将由Cu，Cu合金或其前体构成的层形成在由具有三维网状结构的多孔树脂体构成的骨架上，将层与树脂体进行热处理 在其上形成以除去可热分解的有机组分，从而形成Cu或Cu合金的多孔金属骨架; 并用Ni或Ni合金电镀Cu或Cu合金骨架表面。 热处理可以通过直接感应加热进行。 金属多孔体可用作电池用电极，各种过滤器，催化剂用载体等。当多孔体被切割并用作电极基板时，通过切割Cu或其合金已暴露Cu或其合金的区域的涂层 类似物，具有比Cu或其合金低的电离倾向的第三金属可以提供具有更好的耐腐蚀性和电池使用寿命的电极基底。

    Electrode substrate for battery and process for preparing the same
    9.
    发明授权
    Electrode substrate for battery and process for preparing the same 失效
    电池用电极基板及其制备方法

    公开(公告)号：US5733684A

    公开(公告)日：1998-03-31

    申请号：US652090

    申请日：1996-05-23

    申请人： Keizo Harada ,  Kenichi Watanabe ,  Shosaku Yamanaka

    发明人： Keizo Harada ,  Kenichi Watanabe ,  Shosaku Yamanaka

    IPC分类号： H01M4/66 ,  H01M4/80 ,  H01M4/32

    CPC分类号： H01M4/80 ,  H01M4/808

    摘要： An electrode substrate, for a battery, as a support for an active material used in a collector for a battery, comprising a metallic porous structure possessing interconnecting pores with a porosity of not less than 90% and a number of pores per cm of not less than 10 and having an Fe/Ni two-layer structure wherein Fe constitutes the interior of a skeleton of a porous body constituting the porous structure with the surface portion of the skeleton coated with Ni. Preferably, Fe constituting the interior of the skeleton has a purity of not less than 98% by weight, and the thickness of the nickel coating layer having an Fe content of not more than 10% by weight is 0.1 to 10 .mu.m. The ratio of thickness of the Fe-diffused layer to the thickness of the Ni coating layer is regulated to not more than 0.65 by forming a metallic porous body of Fe using a porous resin as a substrate, plating the metallic porous body with Ni, heat treating the plated body.

    摘要翻译： 一种电池用电极基板，作为用于电池用集电体的活性物质的支持体，其特征在于，具有金属多孔结构体，该金属多孔结构体具有孔隙率不小于90％的孔隙率和不小于几厘米的孔隙数 并且具有Fe / Ni两层结构，其中Fe构成构成多孔结构的骨架的内部，其中骨架的表面部分涂覆有Ni。 优选构成骨架内部的Fe的纯度为98重量％以上，Fe含量为10重量％以下的镍被膜的厚度为0.1〜10μm。 通过使用多孔树脂作为基材形成Fe的金属多孔体，将Ni扩散层的厚度与Ni被覆层的厚度的比例调整为0.65以下，将金属多孔体镀Ni 处理电镀体。